1. |
- Buvailo, Halyna, et al.
(author)
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Facile one-pot synthesis of hybrid compounds based on decavanadate showing water oxidation activity
- 2020
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In: Inorganic Chemistry Communications. - : Elsevier BV. - 1387-7003 .- 1879-0259. ; 119
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Journal article (peer-reviewed)abstract
- Herein, we report the synthesis of two hybrid compounds based on decavanadate anion, namely, [Cu(dien)(Hdien)]2[V10O28]·2H2O (1) and (H3dien)2[V10O28]·4H2O (2), where dien = diethylenetriamine, obtained under mild conditions. Both compounds were characterized by elemental, TG/DTA, single crystal and powder X-ray diffraction analyses, IR and EPR spectroscopies. The compound 1 was found to be active as homogeneous photochemical oxidation catalyst of water to dioxygen.
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2. |
- Shevchenko, Denys, et al.
(author)
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Synthesis, crystal structure, mass spectrometry, electrochemistry and magnetism of a Mn-III-substituted trilacunary Keggin tungstosilicate
- 2013
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In: Dalton Transactions. - : Royal Society of Chemistry (RSC). - 1477-9226 .- 1477-9234. ; 42:14, s. 5130-5139
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Journal article (peer-reviewed)abstract
- A rare example of a "monomeric" triple transition-metal substituted Keggin anion has been synthesized and characterized by various methods including X-ray crystallography, ESI and MALDI mass spectrometry, electrochemistry, EPR, and SQUID.
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