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  • Baraldi, A., et al. (author)
  • Thermal stability of the Rh(110) missing-row reconstruction: Combination of real-time core-level spectroscopy and ab initio modeling
  • 2005
  • In: Physical Review B. Condensed Matter and Materials Physics. ; 72
  • Journal article (peer-reviewed)abstract
    • The thermal stability of the (1×2) missing-row phase of Rh(110), whose first layer is an ordered array of one-dimensional atomic chains, is investigated using high-resolution core-level spectroscopy and density functional calculations. The time evolution of the spectra indicates that this phase is metastable towards deconstruction into a (1×1) phase. Our calculations unveil the mechanism of this process, which is shown to be ignited by surface defects, and provide a value for the activation energy in good agreement with experimental findings.
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