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  • Klein, T., et al. (author)
  • Metal-insulator transition and superconductivity in boron-doped diamond
  • 2007
  • In: Physical Review B. Condensed Matter and Materials Physics. - 1098-0121 .- 1550-235X. ; 75:165313
  • Journal article (peer-reviewed)abstract
    • We report on a detailed analysis of the transport properties and superconducting critical temperatures of boron-doped diamond films grown along the {100} direction. The system presents a metal-insulator transition (MIT) for a boron concentration (nB) on the order of nc~4.5×1020  cm−3, in excellent agreement with numerical calculations. The temperature dependence of the conductivity and Hall effect can be well described by variable range hopping for nB<nc with a characteristic hopping temperature T0 strongly reduced due to the proximity of the MIT. All metallic samples (i.e., for nB>nc) present a superconducting transition at low temperature. The zero-temperature conductivity 0 deduced from fits to the data above the critical temperature (Tc) using a classical quantum interference formula scales as 0(nB/nc−1) with ~1. Large Tc values (0.4  K) have been obtained for boron concentration down to nB/nc~1.1 and Tc surprisingly mimics a (nB/nc−1)1/2 law. Those high Tc values can be explained by a slow decrease of the electron-phonon coupling parameter and a corresponding drop of the Coulomb pseudopotential µ* as nBnc.
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