| 1. |
- Thai, Nguyen Xuan, et al.
(author)
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Realization of a portable H2S sensing instrument based on SnO2 nanowires
- 2020
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In: Journal of Science: Advanced Materials and Devices. - : Elsevier BV. - 2468-2284 .- 2468-2179. ; 5:1, s. 40-47
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Journal article (peer-reviewed)abstract
- Monitoring of toxic gas in air is important because air pollution, especially in developing countries, has rapidly become severe. The high cost of installation and maintenance of a stationary analysis system by using methods such as gas chromatography limits its applications. Low-power, portable devices with relatively low-cost gas sensors are effective for mapping pollution levels in real-time in urban areas and in other living environmentts. Herein, the realization of a portable H2S sensing instrument based on SnO2 nanowires is reported. The sensor chip was prepared by the on-chip growth of SnO2 nanowires directly from the edges of Pt electrodes. The electronic system and software for signal acquisition, data processing, data storage, and output of the instrument were developed. A prototype for zero series of the instrument was also realized. The instrument is capable of monitoring H2S gas in air at ppm level and in biogas production with satisfation.
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| 2. |
- Chu Thi, Quy, et al.
(author)
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Ethanol-Sensing Characteristics of Nanostructured ZnO: Nanorods, Nanowires, and Porous Nanoparticles
- 2017
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In: Journal of Electronic Materials. - : Springer Science and Business Media LLC. - 0361-5235 .- 1543-186X. ; , s. 1-6
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Journal article (peer-reviewed)abstract
- The morphology and crystalline size of metal oxide-sensing materials arebelieved to have a strong influence on the performance of gas sensors. In thispaper, we report a comparative study on the ethanol-sensing characteristics ofZnO nanorods, nanowires, and porous nanoparticles. The porous ZnOnanoparticles were prepared using a simple thermal decomposition of a sheetlikehydrozincite, whereas the nanorods and nanowires were grown byhydrothermal and chemical vapor deposition methods, respectively. Themorphology and crystal structure of the synthesized materials were characterizedby field-emission scanning electron microscopy and x-ray diffraction.Ethanol gas-sensing characteristics were systematically studied at differenttemperatures. Our findings show that for ethanol gas-sensing applications,ZnO porous nanoparticles exhibited the best sensitivity, followed by thenanowires and nanorods. Gas-sensing properties were also examined withrespect to the role of crystal growth orientation, crystal size, and porosity.
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| 3. |
- Duoc, Vo Thanh, et al.
(author)
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Hydrogen gas sensor based on self-heating effect of SnO2/Pt thin film with ultralow power consumption
- 2024
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In: International journal of hydrogen energy. - : Elsevier. - 0360-3199 .- 1879-3487. ; 61, s. 774-782
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Journal article (peer-reviewed)abstract
- Self-heating of sensing elements on gas sensors is an effective solution to avoid using external heaters. In this paper, a self-heated hydrogen gas sensor is presented. The sensor was created using the DC sputtering method, which involved fabricating it on a thermal-insulating Kapton flexible substrate. This process utilized a thin film of SnO2 with thick 50 nm that was modified with nanoclusters of Pt, serving as the sensing material. The SnO2/Pt material film was analyzed for microstructure and composition by SEM, XRD, and XPS analysis. Infrared images show that the self-heating effect is mainly concentrated in the strip of gas-sensitive material. It showed many good performances, such as high sensitivity (able to detect down to 50 ppm of H2), good selectivity (poor response to CO, NH3, H2S, and NO2), the sensor's performance is little changed by environmental humidity, and low power consumption (89 μW at 5V). The sensor is also stable and low-cost, suitable for portable H2 detection devices due to its low generated heat and small size.
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| 4. |
- Nguyet, To Thi, et al.
(author)
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Enhanced response characteristics of NO2 gas sensor based on ultrathin SnS2 nanoplates : Experimental and DFT study
- 2024
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In: Sensors and Actuators A-Physical. - : Elsevier. - 0924-4247 .- 1873-3069. ; 373
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Journal article (peer-reviewed)abstract
- Layered-metal dichalcogenides with extraordinary characteristics of vast surface area, tunable bandgap and superior adsorption capability enable the potential for application in gas sensors. However, the synthesis of effective material for enhanced response performance remains a challenge. Herein, we exploited a fascinating sensitivity and selectivity towards NO2 gas detection using SnS2 nanoflakes prepared via the hydrothermal method. SnS2 nanoflakes with a thickness of 25 nm and an average diameter of approximately 500 nm show the potential for the detection of NO2 gas at low concentrations of ppb levels. The sensing properties of the SnS2 sensors were investigated for different concentrations of NO2 at various operating temperatures. The sensor exhibits the highest gas-sensing response of 161 at 250 οC upon exposure to 5 ppm of NO2 gas with fast response and recovery times. In addition, the sensor shows excellent selectivity with a low detection limit of ppb level. The electronic structure and gas-sensing mechanism are elucidated via finding density of states, charge density, and band structure based on DFT study which is calculated by the Vienna ab-initio simulation package (VASP). The considerable small adsorption energy reveals a physisorption of the NO2 molecules on the SnS2 surface (-0.174 eV), indicating the SnS2 nanoflakes are intriguing candidates for the speedy detection of NO2 gas.
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| 5. |
- Son, Dang Ngoc, et al.
(author)
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A novel design and fabrication of self-heated In2O3 nanowire gas sensor on for ethanol detection
- 2022
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In: Sensors and Actuators A-Physical. - : Elsevier. - 0924-4247 .- 1873-3069. ; 345
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Journal article (peer-reviewed)abstract
- Many attempts have been made on the design and fabrication of low-power consumption gas sensor for application on the Internet of Things and portable devices. The performance of gas sensors includes sensitivity, selectivity, and power consumption, which are strongly dependent on the configuration of the device such as the gap size between two electrodes, the sensing material, and operation principle. Here, self-heated In2O3 nanowire-based gas sensors were designed and fabricated by on-chip growth technique via thermal evaporation to work at room temperature. The effect of electrode gap (10-40 mu m) on the power consumption and gas sensing performance of the In2O3 nanowire sensors was studied. With the large gap of 40 mu m, the sensor exhibited excellent sensing characteristics of low power consumption (1.06 mW) with ability to detect ethanol gas down to 20 ppm effectively. We also examined the role of nanowire conductivity in the performance of the self-heated sensor in the detection of reducing gas. The sensor demonstrated rapid response and recovery times of less than a minute, exceptional stability, and remarkable recovery.
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| 6. |
- Chu Manh, Hung, et al.
(author)
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ZnO coral-like nanoplates decorated with Pd nanoparticles for enhanced VOC gas sensing
- 2021
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In: Journal of Science: Advanced Materials and Devices. - Hanoi, Vietnam : Elsevier. - 2468-2284 .- 2468-2179. ; 6:3, s. 453-461
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Journal article (peer-reviewed)abstract
- A high working temperature of the ZnO nanomaterial-based gas sensor could shorten the lifetime of the sensor and increase its power consumption. Enhancing the volatile organic compound (VOC) sensing performance of ZnO nanomaterial-based gas sensors in terms of gas response and temperature is vital for their practical application. Decoration of noble metals onto nanostructures is an effective approach for improving their sensing characteristics. Herein, hydrothermally synthesized ZnO coral-like nanoplates decorated with Pd nanoparticles are introduced to achieve the improved VOC sensing performance. The morphology, crystal structure, composition, atomic structure, and gas sensing properties of the synthesized pristine and Pd–ZnO coral-like nanoplates were investigated. The results showed a remarkable reduction of optimal working temperature from 450 °C for the pristine ZnO based sensor to 350 °C for the Pd–ZnO based sensor. The sensor response to acetone at the optimal operating temperature of 350 °C was improved three times by surface decoration with Pd nanoparticles. The response time and recovery time of the Pd–ZnO sensor were about three times faster than that of the pristine ZnO sensor. The Pd–ZnO sensor reached a theoretical detection limit of 17 ppt and a sensitivity of 3.5–2.5 ppm acetone at 350 °C. The sensor transient stability after several on/off switching cycles from air to gas revealed the effective reusability of the fabricated devices. A plausible mechanism for the VOC sensing of the porous Pd–ZnO coral-like nanoplate-based sensor is also discussed.
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| 7. |
- Duoc, Vo Thanh, et al.
(author)
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New Design of ZnO Nanorod- and Nanowire-Based NO2 Room-Temperature Sensors Prepared by Hydrothermal Method
- 2019
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In: Journal of Nanomaterials. - : HINDAWI LTD. - 1687-4110 .- 1687-4129.
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Journal article (peer-reviewed)abstract
- Room-temperature gas sensors are attracting attention because of their low power consumption, safe operation, and long-term stability. Herein, ZnO nanorods (NRs) and nanowires (NWs) were on-chip grown via a facile hydrothermal method and used for room-temperature NO2 gas sensor applications. The ZnO NRs were obtained by a one-step hydrothermal process, whereas the NWs were obtained by a two-step hydrothermal process. To obtain ZnO NW sensor, the length of NRs was controlled short enough so that none of the nanorod-nanorod junction was made. Thereafter, the NWs were grown from the tips of no-contact NRs to form nanowire-nanowire junctions. The gas-sensing characteristics of ZnO NRs and NWs were tested against NO2 gas at room temperature for comparison. The gas-sensing characteristics of the sensors were also tested at different applied voltages to evaluate the effect of the self-activated gas-sensing performance. Results show that the diameter of ZnO NRs and NWs is the dominant parameter of their NO2 gas-sensing performance at room temperature. In addition, self-activation by local heating occurred for both sensors, but because the NWs were smaller and sparser than the NRs, local heating thus required a lower applied voltage with maximal response compared with the NRs.
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| 8. |
- Duoc, Vo Thanh, et al.
(author)
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Room temperature highly toxic NO2 gas sensors based on rootstock/scion nanowires of SnO2/ZnO, ZnO/SnO2, SnO2/SnO2 and, ZnO/ZnO
- 2021
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In: Sensors and actuators. B, Chemical. - : Elsevier. - 0925-4005 .- 1873-3077. ; 348
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Journal article (peer-reviewed)abstract
- Grafted structures between SnO2 and ZnO nanowires were realized in a two-step process of growth. First, the rootstocks of SnO2 or ZnO nanowires were synthesized by thermal evaporation technique. Second, a thin Au layer was sputter deposited on the sample and synthesis of nanowire scions of ZnO or SnO2, respectively, on the rootstocks was realized by thermal evaporation technique again. In both growth steps, SnO2 powder or a mixture of ZnO and carbon powders was use as source materials for the synthesis. Different rootstock/scion combinations of SnO2/ZnO, ZnO/SnO2 nanowires (called heterostructures) and ZnO/ZnO, SnO2/SnO2 nanowires (called homostructures) were synthesised. The fabricated grafted nanowires were examined by field-emission scanning electron microscope and their compositions were analyzed by energy dispersive spectroscopy and X-ray diffraction analysis. The test results indicate that this type of nanostructure material is very promising for NO2 gas sensing at ppt level at room temperature. Among the fabricated structures the SnO2/ZnO nanowires showed the best sensing performance with the high sensitivity and fast response and recovery time. We also discussed the gas sensing mechanism of the fabricated sensors based on the band diagram.
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| 9. |
- Duy, Nguyen Van, et al.
(author)
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Design and fabrication of effective gradient temperature sensor array based on bilayer SnO2/Pt for gas classification
- 2022
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In: Sensors and actuators. B, Chemical. - : Elsevier. - 0925-4005 .- 1873-3077. ; 351
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Journal article (peer-reviewed)abstract
- Classification of different gases is important, and it is possible to use different gas sensors for this purpose. Electronic noses, for example, combine separated gas sensors into an array for detecting different gases. However, the use of separated sensors in an array suffers from being bulky, high-energy consumption and complex fabrication processes. Generally, gas sensing properties, including gas selectivity, of semiconductor gas sensors are strongly dependent on their working temperature. It is therefore feasible to use a single device composed of identical sensors arranged in a temperature gradient for classification of multiple gases. Herein, we introduce a design for simple fabrication of gas sensor array based on bilayer Pt/SnO2 for real-time monitoring and classification of multiple gases. The study includes design simulation of the sensor array to find an effective gradient temperature, fabrication of the sensors and test of their performance. The array, composed of five sensors, was fabricated on a glass substrate without the need of backside etching to reduce heat loss. A SnO2 thin film sensitized with Pt on top deposited by sputtering was used as sensing material. The sensor array was tested against different gases including ethanol, methanol, isopropanol, acetone, ammonia, and hydrogen. Radar plots and principal component analysis were used to visualize the distinction of the tested gases and to enable effective classification.
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| 10. |
- Duy, Nguyen Van, et al.
(author)
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Enhancement of NH3 gas sensing with Ag-Pt co-catalyst on SnO2 nanofilm towards medical diagnosis
- 2023
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In: Thin Solid Films. - : Elsevier. - 0040-6090 .- 1879-2731. ; 767
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Journal article (peer-reviewed)abstract
- Exhaled breath analysis is a noninvasive diagnostic method for fatal disease monitoring and screening, which is recently gained extensive interest of researchers worldwide emphasizing on the development of effective chemiresistive gas sensor for practical application. Here, the Ag-Pt bimetallic nanoparticles were used to deco-rate nanofilms of SnO2 making different gas sensors with high performance. We found that the bimetal alloy improved the sensor performance significantly with super sensitivity as compared with the separate Ag and Pt catalyst. The right ratio of the bimetal made the sensor very sensitive to NH3, so that it was able to quickly (12 s) detect 1 parts-per-million of NH3 with a response of 4.31 at a temperature of 250 degrees C. The sensor limit of detection for NH3 was less than 10 parts-per-billion. The response of the sensor was negligibly affected by humidity and interfering gases. The results showed that the tiny, robust, and inexpensive sensor developed in this work can be used in breath analysis for early diagnosis via NH3 monitoring.
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| 11. |
- Ngoc, Trinh Minh, 1978-, et al.
(author)
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H2S Sensing Characteristics of Self-heated Ag-coated SnO2 nanowires
- 2017
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In: Proceeding of the 12th Asian Conference on Chemical Sensors (ACCS2017). - Hanoi. ; , s. 350-353
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Conference paper (other academic/artistic)abstract
- The H2S gas sensing characterization of gas sensors based on the SnO2 nanowires network has been reported by several research groups. However, the self-heated gas sensor using Ag-coated SnO2 nanowires network for sensing H2S was investigated the first times. In this study, we will report on the effected of density SnO2 nanowires network on H2S sensitivity. The SnO2 nanowires network density can be controlled bythe distance between sensor electrodes. After SnO2 nanowires decorated with Ag, the results showt hat the H2S gas sensing properties depend on the density of the SnO2 nanowires network. Asthe density of SnO2 nanowires network increases, the response of sensors decreases. Thesensor can operate at as low power as 2 mW to H2S gas concentration of 0.25 ppm. The responseand recovery times of sensor are about 200 s. Moreover, working at low operating power gives us the benefit of energy saving as well as the elongation of lifetime.
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| 12. |
- Ngoc, Trinh Minh, et al.
(author)
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Ultralow power consumption gas sensor based on a self- heated nanojunction of SnO2 nanowires
- 2018
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In: RSC Advances. - : ROYAL SOC CHEMISTRY. - 2046-2069. ; 8:63, s. 36323-36330
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Journal article (peer-reviewed)abstract
- The long duration of a working device with a limited battery capacity requires gas sensors with low power consumption. A self-heated gas sensor is a highly promising candidate to satisfy this requirement. In this study, two gas sensors with sparse and dense SnO2 nanowire (NW) networks were investigated under the Joule heating effect at the nanojunction. Results showed that the local heating nanojunction was effective for NO2 sensing but generally not for reduction gases. At 1 W, the sparse NW sensor showed a good sensing performance to the NO2 gas. The dense SnO2 NW network required a high-power supply for gas-sensitive activation, but was suitable for reduction gases. A power of approximately 500 W was also needed for a fast recovery time. Notably, the dense NW sensor can response to ethanol and H2S gases. Results also showed that the self-heated sensors were simple in design and reproducible in terms of the fabrication process.
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| 13. |
- Nguyen, Xuan Thai, et al.
(author)
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Gas sensor array based on tin oxide nano structure for volatile organic compounds detection
- 2020
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In: Vietnam Journal of Science and Technology. - : Vietnam Academy of Science and Technology. - 2525-2518. ; 58:2, s. 189-196
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Journal article (peer-reviewed)abstract
- The detection of volatile organic compounds (VOCs) is essential in practicalapplication in breath analysis. Thus, gas sensors based on metal oxide have been fabricated, butthey lacked selectivity. One approach to resolve this task is to use an array of highly sensitiveand selective sensors as an electronic nose. Here a gas sensor array based on Tin oxide nanostructurewith temperature modulation techniques was presented. A Platinum micro-heater isaccompanied with the array gas sensor. The gas sensor array was composed of five singlesensors, and that single sensor is located at different site from the micro heater and works atdifferent temperatures. The gas sensing properties of the gas array sensors were investigatedwith VOC gases such as Ethanol, Methanol, Iso-propanol, and Acetone as well as NH3, H2, andH2S. We also confirm the good selectivity of the array sensor for Ethanol, Methanol, Isopropanol,Acetone, NH3, H2, and H2S by using radar graphic method.
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| 14. |
- Tan, Ha Minh, 1989-, et al.
(author)
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Novel Self-Heated Gas Sensors Using on-Chip Networked Nanowires with Ultralow Power Consumption
- 2017
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In: ACS Applied Materials and Interfaces. - : American Chemical Society (ACS). - 1944-8244 .- 1944-8252. ; 9, s. 6153-6162
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Journal article (peer-reviewed)abstract
- The length of single crystalline nanowires (NWs) offers aperfect pathway for electron transfer, while the small diameter of the NWshampers thermal losses to tje environment, substrate, and metal electrodes.Therefore, Joule self-heating effect is nearly ideal for operating NW gassensors at ultralow power consumption, without additional heaters. Therealization of the self-heated NW sensors using the “pick and place”approach is complex, hardly reproducible, low yield, and not applicable formass production. Here, we present the sensing capability of the self-heatednetworked SnO2 NWs effectively prepared by on-chip growth. Ourdeveloped self-heated sensors exhibit a good response of 25.6 to 2.5 ppmNO2 gas, while the response to 500 ppm H2, 100 ppm NH3, 100 ppm H2S,and 500 ppm C2H5OH is very low, indicating the good selectivity of thesensors to NO2 gas. Furthermore, the detection limit is very low, down to 82parts-per-trillion. As-obtained sensing performance under self-heating modeis nearly identical to that under external heating mode. While the power consumption under self-heating mode is extremely low,around hundreds of microwatts, as scaled-down the size of the electrode is below 10 μm. The selectivity of the sensors can becontrolled simply by tuning the loading power that enables simple detection of NO2 in mixed gases. Remarkable performancetogether with a significantly facile fabrication process of the present sensors enhances the potential application of NW sensors innext generation technologies such as electronic noses, the Internet of Things, and smartphone sensing.
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| 15. |
- Thai, Nguyen Xuan, et al.
(author)
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Prototype edge-grown nanowire sensor array for the real-time monitoring and classification of multiple gases
- 2020
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In: JOURNAL OF SCIENCE-ADVANCED MATERIALS AND DEVICES. - : VIETNAM NATL UNIV. - 2468-2284 .- 2468-2179. ; 5:3, s. 409-416
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Journal article (peer-reviewed)abstract
- The monitoring and classification of different gases using a single resistive semiconductor sensor are challenging because of the similar response characteristics. An array of separated sensors can be used as an electronic nose, but such arrays have a bulky structure and complex fabrication processes. Herein, we easily fabricated a gas-sensor array based on edge-grown SnO2 nanowires for the real-time monitoring and classification of multiple gases. The array comprised four sensors and was designed on a glass substrate. SnO2 nanowires were grown on-chip from the edge of electrodes, made contact together, and acted as sensing elements. This method was advantageous over the post-synthesis technique because the SnO2 nanowires were directly grown from the edge of the electrodes rather than on the surface. Accordingly, damage to the electrode was avoided by alloying Sn with Pt at a high growth temperature. The sensing characteristics of the sensor array were further examined for different gases, including methanol, isopropanol, ethanol, ammonia, hydrogen sulphide and hydrogen. Radar plots were used to improve the selective detection of different gases and enable effective classification. (C) 2020 The Authors. Publishing services by Elsevier B.V. on behalf of Vietnam National University, Hanoi.
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| 16. |
- Trinh, Minh Ngoc, 1978-, et al.
(author)
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Effective design and fabrication of low-power-consumption self-heated SnO2 nanowire sensors for reducing gases
- 2019
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In: Sensors and actuators. B, Chemical. - : Elsevier BV. - 0925-4005 .- 1873-3077. ; 295, s. 144-152
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Journal article (peer-reviewed)abstract
- Developing metal oxide gas sensors for internet-of-things (IoT) and portable applications require low-power consumption because of the limited battery in devices. This requirement is challenging because metal oxide sensors generally need high working temperatures, especially for reducing gases. Herein, we present an effective design and fabrication method of a SnO2 nanowire (NW) sensor for reducing gases by using the Joule heating effect at NW nanojunctions without needing an external or integrated heater. The sensor’s low-power consumption at around 4 mW was controlled by the size and nanojunction density of the device. The sensor has a simple design and is easy to fabricate. A proof-of-concept of a portable gas sensor module can be realised for monitoring highly toxic reducing gases, such as H 2S, NH3 and C2H5OH, by using the developed self-heated NWs.
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| 17. |
- Trinh, Minh Ngoc, 1978-, et al.
(author)
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Self-heated Ag-decorated SnO2 nanowires with low power consumption used as a predictive virtual multisensor for H2S-selective sensing
- 2019
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In: Analytica Chimica Acta. - : Elsevier BV. - 0003-2670 .- 1873-4324. ; 1069, s. 108-116
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Journal article (peer-reviewed)abstract
- Multisensor systems with low-power consumption are emerging for the Internet of Things. In this work, we demonstrate the use of self-heated networked Ag-decorated SnO2 NW sensors integrated into a portable module for selective detection of H2S gas at low power consumption, and the integrated system is simulated as a virtual multisensor under varying heating powers for identifying and quantifying different reducing gases. The H2S gas-sensing characterisations at the different self-heating powers of 2–10 mW showed that the gas response significantly increased with the increase in Ag density decoration and the heated power strongly affected the gas-sensing performance and sensor stability. Excellent response of 21.2 to 0.5 ppm H2S gas was obtained at a low heating power of 2 mW with an acceptable response/recovery time of 18/980 s. The increase of the heating power over 20 mW can destroy the devices. The integrated system could selectively detect H2S at the heating power below 4 mW and H2, C2H5OH and NH3gases at the heating power upon 4 mW. The virtual multisensor could discriminate qualitatively (with an accuracy of 100%) and quantitatively H2S, H2, NH3, C2H5OH (Ethanol) and CH3COCH3 (Aceton) gases with average errors of 13.5%, 14.7%, 16.8%, 16.9%, and 14.8%, respectively. The proposed sensing platform is a promising candidate for selective detection of H2S gas and virtual multisensor with low power consumption for mobile or wireless network devices.
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