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  • Adbo, Karina, et al. (author)
  • Study of the kinetics of enantioselective solid-phase extraction on Tröger’s base molecularly imprinted polymers
  • 2001
  • In: Analytica Chimica Acta. - : Elsevier. - 0003-2670 .- 1873-4324. ; 435:1, s. 115-120
  • Journal article (peer-reviewed)abstract
    • Molecularly imprinted polymers (MIPs) selective for Tröger’s base were designed and synthesised, and HPLC-chromatographic evaluation of polymer recognition characteristics was undertaken. Baseline separation of racemic Tröger’s base was readily achieved, and enantioseparation factors (α) of up to 4.8±0.2 were obtained. The high enantioselectivity demonstrated by these materials prompted their use to examine the kinetics and thermodynamics of individual enantiomers in a solid-phase extraction (SPE) process. Enantiomer-dependent differences in the rates and extent of adsorption were observed. Furthermore, the enantiomeric enrichment of racemates was demonstrated in batch studies.
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  • Hedin-Dahlström, Jimmy, et al. (author)
  • A class II aldolase mimic
  • 2006
  • In: Journal of organic chemistry. - Cardiff, Wales, September 10-14. ; 71:13, s. 4845-4853
  • Journal article (peer-reviewed)
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