| 1. |
- Bergman, Jonas, et al.
(author)
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When the River Began—The Formation of River Motala Ström and Human Presence in the Early Holocene, Sweden
- 2020
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In: Quaternary. - : MDPI AG. - 2571-550X. ; 3:3
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Journal article (peer-reviewed)abstract
- In conjunction with the extensive archaeological projects conducted at the current outlet of Sweden’s second largest lake, Lake Vättern, macrofossil, pollen and diatom records have been studied from 14C-dated lake and river sediments from River Motala Ström in Motala and Lake Boren. These investigations have revealed sedimentary evidence of the Yoldia Sea regression, the Ancient Lake Vättern transgression, and the following stepwise river formation process. Around 9000 cal BC, two small kettlehole basins at Strandvägen and Kanaljorden became isolated from the Baltic basin. As the ice sheet retreated further north, the isostatic uplift isolated the Vättern basin from the Baltic basin. Due to the uneven isostatic uplift, the basin tilted toward the south, and the Ancient Lake Vättern transgression started in Motala. The threshold in Motala at 92.5 m a.s.l. was reached around 7200 cal BC, and River Motala Ström was formed. 14C-dated diatom records from Lake Boren, and shoreline deposits in Motala, confirm this event. The water level in Lake Vättern initially fell around 1.5 m, and around 5800 cal BC, a second erosional event cut down the threshold to modern day level. At this time, the Late Mesolithic settlements in Motala were established and expanded.
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| 2. |
- Helmens, Karin F., et al.
(author)
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Major cooling intersecting peak Eemian Interglacial warmth in northern Europe
- 2015
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In: Quaternary Science Reviews. - : Elsevier BV. - 0277-3791 .- 1873-457X. ; 122, s. 293-299
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Journal article (peer-reviewed)abstract
- The degree of climate instability on the continent during the warmer-than-present Eemian Interglacial (around ca. 123 kyr ago) remains unsolved. Recently published high-resolution proxy data from the North Atlantic Ocean suggest that the Eemian was punctuated by abrupt events with reductions in North Atlantic Deep Water formation accompanied by sea-surface temperature cooling. Here we present multiproxy data at an unprecedented resolution that reveals a major cooling event intersecting peak Eemian warmth on the North European continent. Two independent temperature reconstructions based on terrestrial plants and chironomids indicate a summer cooling of the order of 2-4 degrees C. The cooling event started abruptly, had a step-wise recovery, and lasted 500-1000 yr. Our results demonstrate that the common view of relatively stable interglacial climate conditions on the continent should be revised, and that perturbations in the North Atlantic oceanic circulation under warmer-than-present interglacial conditions may also lead to abrupt and dramatic changes on the adjacent continent.
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| 3. |
- Idris, Shaza Bushra, et al.
(author)
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Polyester copolymer scaffolds enhance expression of bone markers in osteoblast-like cells
- 2010
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In: J BIOMED MATER RES PART A. - : Wiley. - 1549-3296. ; 94A:2, s. 631-639
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Journal article (peer-reviewed)abstract
- In tissue engineering, the resorbable aliphatic polyester poly(L-lactide) (PLLA) is used as scaffolds in bone regeneration. Copolymers of poly(L-lactide)-co-(epsilon-caprolactone) [poly(LLA-co-CL)] and poly(L-lactide)-co-(1,5-dioxepan-2-one) [poly(LLA-co-DXO)], with superior mechanical properties to PLLA, have been developed to be used as scaffolds, but the influence on the osteogenic potential is unclear. This in vitro study of test scaffolds of poly(LLA-co-CL) and poly(LLA-co-DXO) using PLLA scaffolds as a control demonstrates the attachment and proliferation of human osteoblast-like cells (HOB) as measured by SEM and a methylthiazol tetrazolium (MTT) colorimetric assay, and the progression of HOB osteogenesis for up to 3 weeks; expressed as synthesis of the osteoblast differentiation markers: collagen type 1 (Col 1), alkaline phosphatase, bone sialoprotein, osteocalcin (OC), osteopontin and runt related gene 2 (Runx2). Surface analysis disclosed excellent surface attachment, spread and penetration of the cells into the pores of the test scaffolds compared to the PLLA. MTT results indicated that test scaffolds enhanced the proliferation of HOBs. Cells grown on the test scaffolds demonstrated higher synthesis of Col 1 and OC and also increased bone markers mRNA expression. Compared to scaffolds of PLLA, the poly(LLA-co-CL) and poly(LLA-co-DXO) scaffolds enhanced attachment, proliferation, and expression of osteogenic markers by HOBs in vitro. Therefore, these scaffolds might be appropriate carriers for bone engineering. (C) 2010 Wiley Periodicals, Inc. J Biomed Mater Res Part A: 94A: 631-639, 2010
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| 4. |
- Katrantsiotis, Christos, et al.
(author)
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Seasonal variability in temperature trends and atmospheric circulation systems during the Eemian (Last Interglacial) based on n-alkanes hydrogen isotopes from Northern Finland
- 2021
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In: Quaternary Science Reviews. - Amsterdam : Elsevier. - 0277-3791 .- 1873-457X. ; 273, s. 107250-107250
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Journal article (peer-reviewed)abstract
- The Last Interglacial warm period, the Eemian (ca. 130-116 thousand years ago), serves as a reference for projected future climate in a warmer world. However, there is a limited understanding of the seasonal characteristics of interglacial climate dynamics, especially in high latitude regions. In this study, we aimto provide new insights into seasonal trends in temperature and moisture source location, linked to shifts in atmospheric circulation patterns, for northern Fennoscandia during the Eemian. Our study is based on the distribution and stable hydrogen isotope composition (dD) of n-alkanes in a lake sediment sequence from the Sokli paleolake in NE Finland, placed in a multi-proxy framework. The dD values of predominantly macrophyte-derived mid-chain n-alkanes are interpreted to reflect lake water dD variability influenced by winter precipitation dD (dDprec), ice cover duration and deuterium (D)-depleted meltwater. The dD values of terrestrial plant-derived long-chain n-alkanes primarily reflect soil water dD variability modulated by summer dDprec and by the evaporative enrichment of soil and leaf water. The dDprec variability in our study area is mostly attributed to the temperature effect and the moisture source location linked to the relative dominance between D-depleted continental and polar air masses and Denriched North Atlantic air masses. The biomarker signal further corroborates earlier diatom-based studies and pollen-inferred January and July temperature reconstructions from the same sediment sequence. Three phases of climatic changes can be identified that generally follow the secular variationsin seasonal insolation: (i) an early warming trend succeeded by a period of strong seasonality (ii) a midoptimum phase with gradually decreased seasonality and cooler summers, and (iii) a late climatic instability with a cooling trend. Superimposed on this trend, two abrupt cooling events occur in the early and late Eemian. The Sokli dD variability is generally in good agreement with other North Atlantic and Siberian records, reflecting major changes in the atmospheric circulation patterns during the Eemian as a response to orbital and oceanic forcings.
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| 5. |
- Kylander, Malin E., et al.
(author)
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New insights from XRF core scanning data into boreal lake ontogeny during the Eemian (Marine Isotope Stage 5e) at Sokli, northeast Finland
- 2018
-
In: Quaternary Research. - : Cambridge University Press (CUP). - 0033-5894 .- 1096-0287. ; 89:1, s. 352-364
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Journal article (peer-reviewed)abstract
- Biological proxies from the Sokli Eemian (Marine Isotope Stage 5e) paleolake sequence from northeast Finland have previously shown that, unlike many postglacial records from boreal sites, the lake becomes increasingly eutrophic over time. Here, principal components (PC) were extracted from a high resolution multi-element XRF core scanning dataset to describe minerogenic input from the wider catchment (PC1), the input of S, Fe, Mn, and Ca-rich detrital material from the surrounding Sokli Carbonatite Massif (PC2), and chemical weathering (PC3). Minerogenic inputs to the lake were elevated early in the record and during two abrupt cooling events when soils and vegetation in the catchment were poor. Chemical weathering in the catchment generally increased over time, coinciding with higher air temperatures, catchment productivity, and the presence of acidic conifer species. Abiotic edaphic processes play a key role in lake ontogeny at this site stemming from the base cation- and nutrient-rich bedrock, which supports lake alkalinity and productivity. The climate history at this site, and its integrated effects on the lake system, appear to override development processes and alters its long-term trajectory.
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| 6. |
- Målberg, Sofia, et al.
(author)
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Design of Elastomeric Homo- and Copolymer Networks of Functional Aliphatic Polyester for Use in Biomedical Applications
- 2010
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In: Chemistry of Materials. - : American Chemical Society (ACS). - 0897-4756 .- 1520-5002. ; 22:9, s. 3009-3014
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Journal article (peer-reviewed)abstract
- An unsaturated aliphatic polyester was synthesized by condensation polymerization to yield the pre-polymer, poly(but-2-ene-1,4-diyl malonate) (PBM), which is applicable as an elastomeric network and as a macroinitiator for the polymerization of cyclic ester monomers. The method of preparation was simple and straightforward with no need to purify the monomers or add a potentially harmful catalyst. The number average molecular weight of the pre-polymer could easily be increased from 5000 to 12000 by extending the reaction time. The pre-polymer PBM was successfully cross-linked with UV-radiation to form a clear, transparent, colorless, flexible, and strong film. PBM as a macroinitiator for L-lactide (LLA) and epsilon-caprolactone (CL) polymerizations highly increased the ductility of the LLA-polymer, while maintaining the strength, compared to PLLA polymerized with common initiators. The tensile properties of PCL were also improved. The linear PCL-PBM and PLLA-PBM polymers were easily cross-linked to give polymers with greater strength and higher modulus as the result.
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| 7. |
- Plikk, Anna, 1982-, et al.
(author)
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Chironomid-based temperature reconstruction for the Eemian Interglacial (MIS 5e) at Sokli, northeast Finland
- 2019
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In: Journal of Paleolimnology. - : Springer Science and Business Media LLC. - 0921-2728 .- 1573-0417. ; 61:3, s. 355-371
-
Journal article (peer-reviewed)abstract
- The Last Interglacial (Eemian, MIS 5e) can be considered a test-bed for climate dynamics under a warmer-than-present climate. In this study we present a chironomid record from the high latitude Sokli site (N Finland), where a long continuous sediment sequence from the Last Interglacial has been preserved from glacial erosion. The chironomid-analysis shows a diverse fauna, with dominance of warm-water indicators and shifts in assemblage composition that can be attributed to temperature, lake depth, productivity and habitat availability. Quantitative mean July paleotemperature estimates based on the chironomid data indicate overall mean July temperatures up to 1°C warmer than present. Two cooling events can be discerned, the Tunturi event, dated to about 127 ka BP, in the lower part of the sequence, and the Värriö event, dated to about 119 ka BP, associated with the beginning of a cooling trend in the upper part of the record. Warm conditions already at the onset of the interglacial contrast with a recent chironomid-based Last Interglacial temperature reconstruction from Denmark which suggests a late onset of Eemian warming. The relatively small increase in inferred temperatures compared to present day temperatures differs from other high latitude Eemian sites, and likely reflects the influence of the Atlantic Meridional Overturning Circulation in maintaining already elevated temperatures in Fennoscandia during interglacials.
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| 8. |
- Plikk, Anna, et al.
(author)
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Development of an Eemian (MIS 5e) Interglacial palaeolake at Sokli (N Finland) inferred using multiple proxies
- 2016
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In: Palaeogeography, Palaeoclimatology, Palaeoecology. - : Elsevier BV. - 0031-0182 .- 1872-616X. ; 463, s. 11-26
-
Journal article (peer-reviewed)abstract
- A 12 m long lacustrine record from Sokli, N Finland, was analyzed for diatoms, non-pollen palynomorphs, macrofossils, pollen and geochemistry in order to reconstruct the development of a high-latitude Eemian lake and investigate the influence of climatic and environmental changes on the lake ecosystem. Based on this multi-proxy dataset we distinguished five major lake phases in the lake's evolution. An initial minerogenic, glacio-lacustrine phase was followed by an organic-rich early Eemian lake phase characterized by anoxic bottom waters, high seasonality and rising nutrient levels. A long open water season, pronounced summer stratification and high productivity characterized the following early mid-Eemian lake phase, corresponding to the Eemian thermal maximum. During the late mid-Eemian lake phase decreasing water depths due to infilling and extensive mixing of the water column resulted in less stable summer stratification and decreased anoxia. The late-Eemian lake phase was characterized by shallow and dynamic conditions and a cooling climate. Superimposed on these general trends are two events characterized by colder and more arid conditions, that possibly match cold and arid events registered in palaeolimnological records on the European continent. In general, the multi-proxy record reflects a nutrient rich lake, where changes in mixing regime associated with climatic forcing and lake level changes asserted a major impact on the aquatic assemblages. The changes in the aquatic assemblages reflect the major patterns of climate change that took place during the Eemian in northern Europe; i.e. a rapid warming and high seasonality during the early Eemian, decreased seasonality during the mid Eemian and a cooling late Eemian with increased seasonality. The high latitude Sokli Eemian palaeolake record lengthens the latitudinal extent of Eemian terrestrial records across Europe, adding to the understanding of climatic gradients and drivers over Europe.
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| 9. |
- Plikk, Anna, 1982-, et al.
(author)
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Diatom assemblages from an Eemian palaeolake in northern Europe with morphological observations of rare Aulacoseira sp. resting spores
-
Other publication (other academic/artistic)abstract
- An overview of the diatom flora of the last interglacial (Eemian) lacustrine gyttja deposit at Sokli, northeastern Finland is presented together with detailed descriptions including photomicrographs of resting spores similar to the Aulacoseira islandica-skvortzowii group, not found in recent material from Europe. Comparisons are made with literature data on similar taxa. The morphology of the resting spores (e.g. the number of striae and areolae in 10 µm) attributes them to the A. islandica-skvortzowii group but the lack of vegetative cells in the Sokli record makes declaration of true synonymy difficult. The presence of spores similar/related to the A. islandica-skvortzowii group in the Sokli Eemian palaeolake may reflect a more widespread distribution of this group in the past.
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| 10. |
- Plikk, Anna, 1982-, et al.
(author)
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Diatom assemblages from an Eemian palaeolake in Northern Europe with morphological observations of rare Aulacoseira sp. resting spores
- 2021
-
In: Diatom Research. - 0269-249X .- 2159-8347. ; 36:4, s. 313-321
-
Journal article (peer-reviewed)abstract
- An overview of the diatom flora of the last interglacial (Eemian) lacustrine gyttja deposit at Sokli, northeastern Finland is presented together with descriptions including photomicrographs of resting spores similar to the Aulacoseira islandica-skvortzowii group, not found in recent material from Europe. Comparisons are made with literature data on similar taxa. The morphology of the resting spores (e.g., the number of striae and areolae in 10 mu m) links them to the A. islandica-skvortzowii group, but the lack of vegetative cells in the Sokli record makes the determination of true synonymy difficult. The presence of spores similar/related to the A. islandica-skvortzowii group in the Sokli Eemian palaeolake may reflect a more widespread distribution of this group in the past.
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| 11. |
- Plikk, Anna, 1982-
(author)
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The Eemian Interglacial at Sokli, northern Finland : A multi-proxy environmental and climatic reconstruction based on a 9 m long lacustrine sediment sequence
- 2018
-
Doctoral thesis (other academic/artistic)abstract
- Understanding the fundamentals of the Earth’s climate system during the Quaternary Period (the past ca 2.6 million years) is of imminent interest in light of the reported recent climatic changes. The Eemian Interglacial (ca 129,000-116,000 years ago) is the last period before the present interglacial (the Holocene, the last ca 11,700 years) when temperatures were as warm as or warmer than today and may serve as an analogue to future climatic warming. The Eemian is a relatively well-studied period, but many aspects of the interglacial climatic dynamics still remain unresolved. One reason for this is the chronological uncertainties of many records from this time period; another is the relatively uneven distribution of palaeoarchives. Especially from high latitude areas, terrestrial records from the Eemian are few due to the impact of glacial erosion during the Weichselian Glacial (ca 116,000-11,700 years ago).This thesis is based on data from Sokli, N Finland, where cold-based conditions of the Weichselian ice sheets and non-typical bedrock conditions have allowed preservation of an unusually thick Eemian lacustrine deposit in stratigraphic sequence with overlying Weichselian and Holocene deposits. The main purpose of this thesis is to contribute to the knowledge of climate variability in Fennoscandia and the North Atlantic region during the Eemian, and it involves a qualitative multi-proxy reconstruction of the Eemian lake and its development as well as a quantitative reconstruction of the regional Eemian July temperature evolution using subfossil chironomids. Attention is paid also to the identification and characterization of short-term climatic events in the Sokli record.The main contribution of this study is to increase the spatial coverage of Eemian palaeoclimatological data. Specific results include the description of the lake development, identifying phases where non-climatic variables likely affect the quantitative chironomid-based temperature reconstruction, as well as qualitative and quantitative reconstructions of climatic features such as changes in seasonality and temperature. Five major lake phases are distinguished. A glaciolacustrine phase is followed by an early Eemian lake phase characterized by short mixing periods and rising nutrient levels. The following early mid-Eemian lake phase is characterized by a prolonged open water season and high productivity and possibly corresponds to the Eemian climatic optimum. The late mid-Eemian lake phase is characterized by infilling and eutrophic conditions while the late Eemian lake phase reflects shallow, dynamic and cooling conditions.The qualitative study suggests a shift from a higher seasonality in the early Eemian towards more oceanic conditions during the mid-Eemian, while chironomid-inferred July temperatures indicate that near present-day temperatures prevailed at Sokli already from the beginning of the interglacial and that optimum temperatures were only moderately (ca + 1°C) higher than at present. These results suggest that the climatic development at Sokli followed that of central Europe during the Eemian. Two events characterized by colder and more arid conditions are identified, and can be tentatively correlated to meltwater events registered in marine records from the Nordic seas and subpolar north Atlantic, possibly reflecting the effect that meltwater pulses and related disruptions in the thermohaline circulation had on adjacent continental areas.
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| 12. |
- Plikk, Peter, et al.
(author)
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Mapping the Characteristics of the Radical Ring-Opening Polymerization of a Cyclic Ketene Acetal Towards the Creation of a Functionalized Polyester
- 2009
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In: Journal of Polymer Science Part A. - : Wiley. - 0887-624X .- 1099-0518. ; 47:18, s. 4587-4601
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Journal article (peer-reviewed)abstract
- Radical ring-opening polymerization of cyclic ketene acetals is a means to achieve novel types of aliphatic polyesters. 2-methylene-1,3-dioxe-5-pene is a seven-membered cyclic ketene acetal containing an unsaturation in the 5-position in the ring structure. The double bond functionality enables further reactions subsequent to polymerization. The monomer 2-methylene-1,3-dioxe-5-pene was synthesized and polymerized in bulk by free radical polymerization at different temperatures, to determine the structure of the products and propose a reaction mechanism. The reaction mechanism is dependent on the reaction temperature. At higher temperatures, ring-opening takes place to a great extent followed by a new cyclization process to form the stable five-membered cyclic ester 3-vinyl-1,4-butyrolactone as the main reaction product. Thereby, propagation is suppressed and only small amounts of other oligomeric products are formed. At lower temperatures, the cyclic ester formation is reduced and oligomeric products containing both ring-opened and ring-retained repeating units are produced at higher yield.
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| 13. |
- Rosenberg, Thomas M., et al.
(author)
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Middle and Late Pleistocene humid periods recorded in palaeolake deposits of the Nafud desert, Saudi Arabia
- 2013
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In: Quaternary Science Reviews. - : Elsevier BV. - 0277-3791 .- 1873-457X. ; 70, s. 109-123
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Journal article (peer-reviewed)abstract
- Present climate in the Nafud desert of northern Saudi Arabia is hyper-arid and moisture brought by north-westerly winds scarcely reaches the region. The existence of abundant palaeolake sediments provides evidence for a considerably wetter climate in the past. However, the existing chronological framework of these deposits is solely based on radiocarbon dating of questionable reliability, due to potential post-depositional contamination with younger C-14. By using luminescence dating, we show that the lake deposits were not formed between 40 and 20 ka as suggested previously, but approximately ca 410 ka, 320 ka, 200 ka, 125 ka, and 100 ka ago. All of these humid phases are in good agreement with those recorded in lake sediments and speleothems from southern Arabia. Surprisingly, no Holocene lake deposits were identified. Geological characteristics of the deposits and diatom analysis suggest that a single, perennial lake covered the entire south-western Nafud ca 320 ka ago. In contrast, lakes of the 200 ka, 125 ka, and 100 ka humid intervals were smaller and restricted to interdune depressions of a preexisting dune relief. The concurrent occurrence of humid phases in the Nafud, southern Arabia and the eastern Mediterranean suggests that moisture in northern Arabia originated either from the Mediterranean due to more frequent frontal depression systems or from stronger Indian monsoon circulation, respectively. However, based on previously published climate model simulations and palaecolimate evidence from central Arabia and the Negev desert, we argue that humid climate conditions in the Nafud were probably caused by a stronger African monsoon and a distinct change in zonal atmospheric circulation.
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| 14. |
- Salonen, J. Sakari, et al.
(author)
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Abrupt high-latitude climate events and decoupled seasonal trends during the Eemian
- 2018
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In: Nature Communications. - : Springer Science and Business Media LLC. - 2041-1723. ; 9
-
Journal article (peer-reviewed)abstract
- The Eemian (the Last Interglacial; ca. 129-116 thousand years ago) presents a testbed for assessing environmental responses and climate feedbacks under warmer-than-present boundary conditions. However, climate syntheses for the Eemian remain hampered by lack of data from the high-latitude land areas, masking the climate response and feedbacks in the Arctic. Here we present a high-resolution (sub-centennial) record of Eemian palaeoclimate from northern Finland, with multi-model reconstructions for July and January air temperature. In contrast with the mid-latitudes of Europe, our data show decoupled seasonal trends with falling July and rising January temperatures over the Eemian, due to orbital and oceanic forcings. This leads to an oceanic Late-Eemian climate, consistent with an earlier hypothesis of glacial inception in Europe. The interglacial is further intersected by two strong cooling and drying events. These abrupt events parallel shifts in marine proxy data, linked to disturbances in the North Atlantic oceanic circulation regime.
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| 15. |
- Undin, Jenny, et al.
(author)
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Synthesis of Amorphous Aliphatic Polyester-Ether Homo- and Copolymers by Radical Polymerization of Ketene Acetals
- 2010
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In: Journal of Polymer Science Part A. - : Wiley. - 0887-624X .- 1099-0518. ; 48:22, s. 4965-4973
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Journal article (peer-reviewed)abstract
- Radical ring-opening polymerization has been efficiently used to copolymerize 2-methylene-1,3,6-trioxocane (MTC) and 2-methylene-1,3-dioxepane (MDO). The cyclic ketene acetal MTC was first synthesized and homopolymerized at different temperatures using either 2,2-azobisisobutyronitrile or dicumyl peroxide as initiator. The polymerization mechanism was not temperature-dependent, and the polymerization proceeded with 100% ring-opening at all the temperatures evaluated. The structures of MTC and PMTC were verified by H-1-nuclear magnetic resonance (NMR) and C-13-NMR spectroscopies. A number-average molecular weight of 6500 was obtained after 2 days at 70 degrees C in bulk, which was somewhat higher than the theoretical molecular weight. A significant amount of branching was detected from the high polydispersity index as well as the glass-transition temperatures. The polyester-ether was then successfully obtained by copolymerization of MTC with MDO. Different feed ratios and temperatures were used to map the reaction, and the copolymers were characterized by NMR, size exclusion chromatography, and differential scanning calorimetry. The amount of MTC within the polymer was independent of the feed ratio and always higher than the amount of MDO.
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| 16. |
- Widgren, Mats, 1948-, et al.
(author)
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Precolonial agricultural terracing in Bokoni, South Africa : Typology and an exploratory excavation
- 2016
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In: Journal of African Archaeology. - : Brill. - 1612-1651 .- 2191-5784. ; 14:1, s. 33-53
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Journal article (peer-reviewed)abstract
- Earlier work on the terraced settlements of the Bokoni area (16th to 19th century, Mpumalanga province, South Africa) focussed on the homesteads, their contents, layout and chronology. This paper suggests a terminology and typology of agrarian structures in Bokoni in order to improve comparative approaches in Africa and beyond. The typology and an excavation of the terracing have made possible preliminary conclusions relevant for the further analysis of the terracing and stone-walling in Bokoni. The terracing developed incrementally, whereby cultivation, stone-clearing and terracing were intermixed processes. This is supported both by the organic content in a section of a terrace and by a phytolith analysis. The phytolith analysis furthermore indicated that maize was cultivated on the terraces, but this should be seen as a pilot study only, and presence of maize in Bokoni must be tested with other archaeobotanical methods.
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