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5.
  • Aleksandrovskii, A. N., et al. (author)
  • Effect of argon on the thermal expansion of fullerite C60 at helium temperatures
  • 2001
  • In: Low temperature physics (Woodbury, N.Y., Print). - : American Institute of Physics. - 1063-777X .- 1090-6517. ; 27:3, s. 245-246
  • Journal article (peer-reviewed)abstract
    • The linear thermal expansion of compacted Ar-doped fullerite C60(ArxC60) is investigated at 2–12 K using a dilatometric method. The thermal expansion of ArxC60 is also studied after partial desaturation of argon from fullerite. It is revealed that argon doping resulted in a considerable change of the temperature dependence of the thermal expansion of fullerite. An explanation of the observed effects is proposed.
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6.
  • Aleksandrovskii, A. N., et al. (author)
  • Low-temperature thermal expansion of pure and inert gas-doped fullerite C60
  • 2003
  • In: Fizika Nizkikh Temperatur (Kharkov). - : AIP Publishing. - 0132-6414 .- 1816-0328. ; 29:4, s. 432-442
  • Journal article (peer-reviewed)abstract
    • The low temperature (2–24 K) thermal expansion of pure (single-crystal and polycrystalline) C60 and polycrystalline C60 intercalated with He, Ne, Ar, and Kr has been investigated using the high-resolution capacitance dilatometer. The investigation of the time dependence of the sample length variations deltaL(t) on heating by deltaT shows that the thermal expansion is determined by the sum of positive and negative contributions, which have different relaxation times. The negative thermal expansion usually prevails at helium temperatures. The positive expansion is connected with the phonon thermalization of the system. The negative expansion is caused by reorientation of the C60 molecules. It is assumed that the reorientation is of a quantum character. The inert gas impurities affect the reorientation of the C60 molecules very strongly, especially at liquid helium temperatures. A temperature hysteresis of the thermal expansion coefficient of Kr– and He–C60 solutions has been revealed. The hysteresis is attributed to orientational polyamorphous transformation in these systems.
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7.
  • Aleksandrovskii, A. N., et al. (author)
  • Negative thermal expansion of fullerite C60 at helium temperatures
  • 1997
  • In: Low temperature physics (Woodbury, N.Y., Print). - : AIP Publishing. - 1063-777X .- 1090-6517. ; 23:11, s. 943-946
  • Journal article (peer-reviewed)abstract
    • The thermal expansion of fullerite C60 has been measured in the temperature range 2–9 K. A compacted fullerite sample with a diameter of about 6 mm and height of 2.4 mm was used. It was found that at temperatures below ~ 3.4 K the linear thermal expansion coefficient becomes negative. At temperatures above 5 K our results are in good agreement with the available literature data. A qualitative explanation of the results is proposed
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8.
  • Aleksandrovskii, A.N., et al. (author)
  • Thermal expansion of fullerite C60 alloyed with argon and neon
  • 2001
  • In: Low temperature physics (Woodbury, N.Y., Print). - Woodbury : American Institute of Physics. - 1063-777X .- 1090-6517. ; 27:12, s. 1033-1036
  • Journal article (peer-reviewed)abstract
    • The linear thermal expansion of compacted fullerite C60 alloyed with argon (ArxC60) and neon (NexC60) are investigated by a dilatometric method. The experimental temperature is 2–12 K. In the same temperature interval the thermal expansion of ArxC60 and NexC60 are examined after partial desaturation of the gases from fullerite. It is found that Ar and Ne alloying affects the temperature dependence of the thermal expansion coefficient of C60 quite appreciably. The libration and translation contributions to the thermal expansion of pure C60 are separated. The experimental results on the thermal expansion are used to obtain the Debye temperature of pure C60. The effects observed are tentatively interpreted.
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9.
  • Aleksandrovskii, A. N., et al. (author)
  • Thermal expansion of single-crystal fullerite C60 at helium temperatures
  • 2000
  • In: Low temperature physics (Woodbury, N.Y., Print). - : AIP Publishing. - 1063-777X .- 1090-6517. ; 26:1, s. 75-80
  • Journal article (peer-reviewed)abstract
    • The thermal expansion of single-crystal fullerite C60 has been studied in the range of liquid-helium temperatures (2–10 K). At temperatures below ~4.5 K the thermal expansion of fullerite C60 becomes negative, in agreement with the previous results on polycrystalline materials. A qualitative explanation of the results is proposed.
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  • Metcalfe, Daniel B., et al. (author)
  • Patchy field sampling biases understanding of climate change impacts across the Arctic
  • 2018
  • In: Nature Ecology and Evolution. - : Springer Science and Business Media LLC. - 2397-334X. ; 2:9, s. 1443-1448
  • Journal article (peer-reviewed)abstract
    • Effective societal responses to rapid climate change in the Arctic rely on an accurate representation of region-specific ecosystem properties and processes. However, this is limited by the scarcity and patchy distribution of field measurements. Here, we use a comprehensive, geo-referenced database of primary field measurements in 1,840 published studies across the Arctic to identify statistically significant spatial biases in field sampling and study citation across this globally important region. We find that 31% of all study citations are derived from sites located within 50 km of just two research sites: Toolik Lake in the USA and Abisko in Sweden. Furthermore, relatively colder, more rapidly warming and sparsely vegetated sites are under-sampled and under-recognized in terms of citations, particularly among microbiology-related studies. The poorly sampled and cited areas, mainly in the Canadian high-Arctic archipelago and the Arctic coastline of Russia, constitute a large fraction of the Arctic ice-free land area. Our results suggest that the current pattern of sampling and citation may bias the scientific consensuses that underpin attempts to accurately predict and effectively mitigate climate change in the region. Further work is required to increase both the quality and quantity of sampling, and incorporate existing literature from poorly cited areas to generate a more representative picture of Arctic climate change and its environmental impacts.
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  • Siefert, Andrew, et al. (author)
  • A global meta-analysis of the relative extent of intraspecific trait variation in plant communities
  • 2015
  • In: Ecology Letters. - : Wiley. - 1461-023X .- 1461-0248. ; 18:12, s. 1406-1419
  • Research review (peer-reviewed)abstract
    • Recent studies have shown that accounting for intraspecific trait variation (ITV) may better address major questions in community ecology. However, a general picture of the relative extent of ITV compared to interspecific trait variation in plant communities is still missing. Here, we conducted a meta-analysis of the relative extent of ITV within and among plant communities worldwide, using a data set encompassing 629 communities (plots) and 36 functional traits. Overall, ITV accounted for 25% of the total trait variation within communities and 32% of the total trait variation among communities on average. The relative extent of ITV tended to be greater for whole-plant (e.g. plant height) vs. organ-level traits and for leaf chemical (e.g. leaf N and P concentration) vs. leaf morphological (e.g. leaf area and thickness) traits. The relative amount of ITV decreased with increasing species richness and spatial extent, but did not vary with plant growth form or climate. These results highlight global patterns in the relative importance of ITV in plant communities, providing practical guidelines for when researchers should include ITV in trait-based community and ecosystem studies.
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  • Wade, G. A., et al. (author)
  • The MiMeS survey of magnetism in massive stars : introduction and overview
  • 2016
  • In: Monthly notices of the Royal Astronomical Society. - : Oxford University Press (OUP). - 0035-8711 .- 1365-2966. ; 456:1, s. 2-22
  • Journal article (other academic/artistic)abstract
    • The MiMeS (Magnetism in Massive Stars) project is a large-scale, high-resolution, sensitive spectropolarimetric investigation of the magnetic properties of O- and early B-type stars. Initiated in 2008 and completed in 2013, the project was supported by three Large Program allocations, as well as various programmes initiated by independent principal investigators, and archival resources. Ultimately, over 4800 circularly polarized spectra of 560 O and B stars were collected with the instruments ESPaDOnS (Echelle SpectroPolarimetric Device for the Observation of Stars) at the Canada-France-Hawaii Telescope, Narval at the Telescope Bernard Lyot and HARPSpol at the European Southern Observatory La Silla 3.6 m telescope, making MiMeS by far the largest systematic investigation of massive star magnetism ever undertaken. In this paper, the first in a series reporting the general results of the survey, we introduce the scientific motivation and goals, describe the sample of targets, review the instrumentation and observational techniques used, explain the exposure time calculation designed to provide sensitivity to surface dipole fields above approximately 100 G, discuss the polarimetric performance, stability and uncertainty of the instrumentation, and summarize the previous and forthcoming publications.
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  • Abdelkader, Amal F., 1969, et al. (author)
  • High salt stress induces swollen prothylakoids in dark-grown wheat and alters both prolamellar body transformation and reformation after irradiation
  • 2007
  • In: Journal of Experimental Botany. - : Oxford University Press (OUP). - 0022-0957 .- 1460-2431. ; 58:10, s. 2553-2564
  • Journal article (peer-reviewed)abstract
    • High salinity causes ion imbalance and osmotic stress in plants. Leaf sections from 8-d-old dark-grown wheat (Triticum aestivum cv. Giza 168) were exposed to high salt stress (600 mM) and the native arrangements of plastid pigments together with the ultrastructure of the plastids were studied using low-temperature fluorescence spectroscopy and transmission electron microscopy. Although plastids from salt-treated leaves had highly swollen prothylakoids (PTs) the prolamellar bodies (PLBs) were regular. Accordingly, a slight intensity decrease of the short-wavelength protochlorophyllide (Pchlide) form was observed, but no change was found in the long-wavelength Pchlide form emitting at 656 nm. After irradiation, newly formed swollen thylakoids showed traversing stromal strands. The PLB dispersal was partly inhibited and remnants of the PLBs formed an electron-dense structure, which remained after prolonged (8 h) irradiation. The difference in fluorescence emission maximum of the main chlorophyll form in salt-stressed leaves (681 nm) and in control leaves (683 nm) indicated a restrained formation of the photosynthetic apparatus. Overall chlorophyll accumulation during prolonged irradiation was inhibited. Salt-stressed leaves returned to darkness after 3 h of irradiation had, compared with the control, a reduced amount of Pchlide and reduced reformation of regular net-like PLBs. Instead, the size of the electron-dense structures increased. This study reports, for the first time, the salt-induced swelling of PTs and reveals traversing stromal strands in newly formed thylakoids. Although the PLBs were intact and the Pchlide fluorescence emission spectra appeared normal after salt stress in darkness, plastid development to chloroplasts was highly restricted during irradiation.
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  • Ahvenniemi, Esko, et al. (author)
  • Recommended reading list of early publications on atomic layer deposition-Outcome of the "Virtual Project on the History of ALD"
  • 2017
  • In: Journal of Vacuum Science & Technology. A. Vacuum, Surfaces, and Films. - : American Vacuum Society. - 0734-2101 .- 1520-8559. ; 35:1
  • Research review (peer-reviewed)abstract
    • Atomic layer deposition (ALD), a gas-phase thin film deposition technique based on repeated, self-terminating gas-solid reactions, has become the method of choice in semiconductor manufacturing and many other technological areas for depositing thin conformal inorganic material layers for various applications. ALD has been discovered and developed independently, at least twice, under different names: atomic layer epitaxy (ALE) and molecular layering. ALE, dating back to 1974 in Finland, has been commonly known as the origin of ALD, while work done since the 1960s in the Soviet Union under the name "molecular layering" (and sometimes other names) has remained much less known. The virtual project on the history of ALD (VPHA) is a volunteer-based effort with open participation, set up to make the early days of ALD more transparent. In VPHA, started in July 2013, the target is to list, read and comment on all early ALD academic and patent literature up to 1986. VPHA has resulted in two essays and several presentations at international conferences. This paper, based on a poster presentation at the 16th International Conference on Atomic Layer Deposition in Dublin, Ireland, 2016, presents a recommended reading list of early ALD publications, created collectively by the VPHA participants through voting. The list contains 22 publications from Finland, Japan, Soviet Union, United Kingdom, and United States. Up to now, a balanced overview regarding the early history of ALD has been missing; the current list is an attempt to remedy this deficiency.
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  • Aleksandrovskii, A.N., et al. (author)
  • On the polyamorphism of fullerite-based orientational glasses.
  • 2005
  • In: Low Temperature Physics. - : AIP Publishing. - 1063-777X .- 1090-6517. ; 31:5, s. 429-444
  • Journal article (peer-reviewed)abstract
    • The dilatometric investigation in the temperature range of 2–28 K shows that a first-orderpolyamorphous transition occurs in the orientational glasses based on C60 doped with H2, D2 andXe. A polyamorphous transition was also detected in C60 doped with Kr and He. It is observed thatthe hysteresis of thermal expansion caused by the polyamorphous transition (and, hence, the transitiontemperature) is essentially dependent on the type of doping gas. Both positive and negativecontributions to the thermal expansion were observed in the low-temperature phase of the glasses.The relaxation time of the negative contribution occurs to be much longer than that of the positivecontribution. The positive contribution is found to be due to phonon and libron modes, whilst thenegative contribution is attributed to tunneling states of the C60 molecules. The characteristictime of the phase transformation from the low-T phase to the high-T phase has been found for theC60–H2 system at 12 K. A theoretical model is proposed to interpret these observed phenomena.The theoretical model proposed, includes a consideration of the nature of polyamorphism inglasses, as well as the thermodynamics and kinetics of the transition. A model of noninteractingtunneling states is used to explain the negative contribution to the thermal expansion. The experimentaldata obtained is considered within the framework of the theoretical model. From the theoreticalmodel the order of magnitude of the polyamorphous transition temperature has been estimated.It is found that the late stage of the polyamorphous transformation is described well by theKolmogorov law with an exponent of n = 1. At this stage of the transformation, the two-dimensionalphase boundary moves along the normal, and the nucleation is not important.
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  • Andersson, O., et al. (author)
  • Thermal conductivity of C60 under high pressure
  • 1995
  • In: Science and technology of fullerene materials. - Pittsburgh, Pa : Materials Research Society. - 155899260X ; , s. 549-554
  • Conference paper (peer-reviewed)
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  • Andreasson, A., et al. (author)
  • Fosfomycin versus Ciprofloxacin as transrectal prostatebiopsy antibiotic prophylaxis an open randomized controlled multicenter drug trial
  • 2023
  • In: European Urology. - : Elsevier. - 0302-2838 .- 1873-7560. ; 83:Suppl. 1, s. S180-S180
  • Journal article (other academic/artistic)abstract
    • Introduction & Objectives: Antibiotic prophylaxis are administered as a routine to decrease the risk for septic complications following transrectal prostate biopsy. Fosfomycin administered 1 h or more prior to biopsy has equal or better infectious complication rates as compared to Ciprofloxacin in both prospective and retrospective studies from countries with high rates of antibiotic resistance. The aim of this study was to investigate if Fosfomycin administered immediately prior to prostate biopsy was as effective as Ciprofloxacin in Sweden, a country with low rates of antibiotic resistance.Materials & Methods: A randomized, controlled, open, multicenter, non-inferiority-study including men of all ages undergoing transrectal prostate biopsy was performed in the urology departments of three Swedish hospitals. The total number of patients were planned for 3448, divided into low and high infection risk groups. The low-risk group was randomized to either one dose of Fosfomycin 3g or Ciprofloxacin 750mg before biopsy. The high-risk group was randomized to either two doses of Fosfomycin 3g prior to biopsy and one more 24 h after biopsy or Ciprofloxacin 500mg once prior to biopsy and then twice daily for three days. The drugs were administered orally. All patients had a rectal swab for culture before and after biopsy. The endpoint was hospitalisation due to urinary tract infection within 14 days from biopsy, follow-up was performed with a phone interview.Results: The safety board prematurely interrupted the study after 42 included patients due to an unusual high number of hospitalisations. Four out of 20 patients (20%), three in the low-risk group and one in the high-risk group, had been hospitalised due to urosepsis in the Fosfomycin group. One further patient described fever symptoms but did not seek health care. No patient in the Ciprofloxacin group (n=21) described symptoms of infection from the urinary tract. One patient was lost to follow-up. A one-sided binomial test showed a p-value of <0.001. Two of the four hospitalised patients had a positive blood culture for Pseudomonas Aeruginosa and one had a positive rectal swab culture for Pseudomonas species both before and after biopsy.Conclusions: The study does not support the use of Fosfomycin administered immediately prior to prostate biopsy. The results may have been affected by the unexpected high number of Pseudomonas infections, a bacteria where Fosfomycin often lack effect. If Fosfomycin is to be used it should be with caution if Pseudomonas has been seen in earlier cultures
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  • Berkolaiko, G., et al. (author)
  • Computing Nodal Deficiency with a Refined Dirichlet-to-Neumann Map
  • 2022
  • In: Journal of Geometric Analysis. - : Springer Science and Business Media LLC. - 1050-6926 .- 1559-002X. ; 32:10
  • Journal article (peer-reviewed)abstract
    • Recent work of the authors and their collaborators has uncovered fundamental connections between the Dirichlet-to-Neumann map, the spectral flow of a certain family of self-adjoint operators, and the nodal deficiency of a Laplacian eigenfunction (or an analogous deficiency associated to a non-bipartite equipartition). Using a refined construction of the Dirichlet-to-Neumann map, we strengthen all of these results, in particular getting improved bounds on the nodal deficiency of degenerate eigenfunctions. Our framework is very general, allowing for non-bipartite partitions, non-simple eigenvalues, and non-smooth nodal sets. Consequently, the results can be used in the general study of spectral minimal partitions, not just nodal partitions of generic Laplacian eigenfunctions.
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  • Buga, Sergei G., et al. (author)
  • Semimetallic and semiconductor properties of some superhard and ultrahard fullerites in the range 300-2 K
  • 2000
  • In: Proceedings of the 5th IUMRS International Conference on Advanced Materials, Beijing 1999. - : Elsevier B.V.. ; , s. 1009-1015
  • Conference paper (peer-reviewed)abstract
    • Electrical resistivity and magnetoresistance were measured on samples with disordered structures synthesized from pure C60 and C70 at pressures in the range 8–12.5 GPa and temperatures of 900–1500 K. Different types of behaviour were observed: semimetallic, VRH and semiconducting, depending on the degree of disorder and the particular short-range order of the samples. A negative magnetoresistance was observed at T<10 K on samples with a semimetallic type of conductivity synthesized at 8 GPa pressure. The temperature dependence of resistivity in the sample with a disordered crystalline structure based on 3D-polymerized C60 molecules fits Mott's law for hopping conductivity. T3/2, T2 and T4 dependencies of conductivity are observed for samples with densities of 2.8 and 3.05 g/cm3 synthesized at a pressure of 12.5 GPa. The effect of hydrostatic pressure on the resistivity of cross-linked layered carbon structures obtained from C60 at P=8 GPa, T=1600 K was investigated up to 0.6 GPa at room temperature. An approximately linear decrease of resistivity was observed with a very small value of the derivative d ln ρ/dp=0.06 /GPa, which correlates with a very low compressibility of the material.
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29.
  • Cameron, Erin K., et al. (author)
  • Uneven global distribution of food web studies under climate change
  • 2019
  • In: Ecosphere. - : Wiley. - 2150-8925 .- 2150-8925. ; 10:3
  • Journal article (peer-reviewed)abstract
    • Trophic interactions within food webs affect species distributions, coexistence, and provision of ecosystem services but can be strongly impacted by climatic changes. Understanding these impacts is therefore essential for managing ecosystems and sustaining human well-being. Here, we conducted a global synthesis of terrestrial, marine, and freshwater studies to identify key gaps in our knowledge of climate change impacts on food webs and determine whether the areas currently studied are those most likely to be impacted by climate change. We found research suffers from a strong geographic bias, with only 3.5% of studies occurring in the tropics. Importantly, the distribution of sites sampled under projected climate changes was biased-areas with decreases or large increases in precipitation and areas with low magnitudes of temperature change were under-represented. Our results suggest that understanding of climate change impacts on food webs could be broadened by considering more than two trophic levels, responses in addition to species abundance and biomass, impacts of a wider suite of climatic variables, and tropical ecosystems. Most importantly, to enable better forecasts of biodiversity responses to dimate change, we identify critically under-represented geographic regions and climatic conditions which should be prioritized in future research.
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  • Cho, C. R., et al. (author)
  • Na0.5K0.5NbO3 thin films for MFIS_FET type non-volatile memory applications
  • 2002
  • In: Integrated Ferroelectrics. - 1058-4587 .- 1607-8489. ; 49, s. 21-30
  • Journal article (peer-reviewed)abstract
    • Na0.5K0.5NbO3(NKN) thin films have been prepared on Pt80Ir20, SiO2/Si, and Ta2O5/Si substrates for ferroelectric non-volatile memory applications. Ferroelectric hysteresis loops for Au/NKN/Pt80Ir20 vertical capacitor yielded remnant polarization of 12 muC/cm(2) and coercive field similar to20 kV/cm. Significant flat-band voltage V-FB shifts with buffer layer thickness in Au/NKN/SiO2/Si structures have been attributed to the intermixing between Na and K alkali ions and SiO2 layer. On the other hand, Au/NKN/Ta2O5/Si structure exhibited wide memory window without significant V-FB deviations, low leakage currents, and rather long retention time at zero bias.
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  • Dolbin, Alexander Vitoldovich, et al. (author)
  • Influence of dissolved oxygen on the thermal expansion and polyamorphism of fullerite C60
  • 2007
  • In: Low temperature physics (Woodbury, N.Y., Print). - : AIP Publishing. - 1063-777X .- 1090-6517. ; 33:5, s. 465-471
  • Journal article (peer-reviewed)abstract
    • The temperature dependence of the coefficient of linear thermal expansion alpha of O-2-C-60 solutions with 20% and 80% filling of the octahedral cavities with oxygen is investigated in the temperature interval 2.2-24 K. Hysteresis of alpha(T) is observed, attesting to the coexistence of two orientational glasses in these solutions. A comparison of the behavior of these glasses is made. The characteristic times for reorientation of the C-60 molecules and for the phase transformations in the solutions are determined. When the temperature of the O-2-C-60 solution with 20 mol.% oxygen is increased to 450 degrees C, a chemical interaction of the oxygen with the C-60 molecules is manifested. It proves possible to separate the influences of the chemical and physical sorption of oxygen on the thermal expansion of polycrystalline fullerite C-60.
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35.
  • Dolbin, Alexander V., et al. (author)
  • Low-temperature radial thermal expansion of single-walled carbon nanotube bundles saturated with nitrogen
  • 2010
  • In: Low temperature physics (Woodbury, N.Y., Print). - : AIP Publishing. - 1063-777X .- 1090-6517. ; 36:5, s. 365-369
  • Journal article (peer-reviewed)abstract
    • The effect of a N2 impurity on the radial thermal expansion coefficient αr of single-walled carbon nanotube bundles has been investigated in the temperature interval 2.2–43 K by the dilatometric method. Saturation of nanotube bundles with N2 caused a sharp increase in the positive magnitudes of αr in the whole temperature range used and a very high and wide maximum in the thermal expansion coefficient αr(T) at T ~ 28 K. The low temperature desorption of the impurity from the N2-saturated powder of bundles of single-walled carbon nanotubes with open and closed ends has been investigated.
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  • Dolbin, Alexander V., et al. (author)
  • Quantum effects in the radial thermal expansion of bundles of single-walled carbon nanotubes doped with 4He
  • 2010
  • In: Low temperature physics (Woodbury, N.Y., Print). - Woodbury, N.Y. : American Institute of Physics. - 1063-777X .- 1090-6517. ; 36:7, s. 635-637
  • Journal article (peer-reviewed)abstract
    • The radial thermal expansion αr of bundles of single-walled carbon nanotubes saturated with 4He impurities to the molar concentration 9.4% has been investigated in the interval 2.5–9.5 K using the dilatometric method. In the interval 2.1–3.7 K αr is negative and is several times higher than the negative αr for pure nanotube bundles. This most likely points to 4He atom tunneling between different positions in the nanotube bundle system. The excess expansion was reduced with decreasing 4He concentration.
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37.
  • Dolbin, Alexander V., et al. (author)
  • Quantum phenomena in the radial thermal expansion of bundles of single-walled carbon nanotubes doped with 3He. A giant isotope effect
  • 2011
  • In: Low temperature physics (Woodbury, N.Y., Print). - : American Institute of Physics (AIP). - 1063-777X .- 1090-6517. ; 37:6, s. 544-546
  • Journal article (peer-reviewed)abstract
    • The radial thermal expansion αr of bundles of single-walled carbon nanotubes saturated with 3He up to the molar concentration 9.4% has been investigated in the temperature interval 2.1–9.5 K by high-sensitivity capacitance dilatometry. In the interval 2.1–7 K a negative αr was observed, with a magnitude which exceeded the largest negative αr values of pure and 4He-saturated nanotubes by three and two orders of magnitude, respectively. The contributions of the two He isotope impurities to the negative thermal expansion of the nanotube bundles are most likely connected with the spatial redistribution of 4He and 3He atoms by tunneling at the surface and inside nanotube bundles. The isotope effect turned out to be huge, probably owing to the higher tunneling probability of 3He atoms.
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38.
  • Dolbin, Alexander V., et al. (author)
  • Radial thermal expansion of pure and Xe-saturated bundles of single-walled carbon nanotubes at low temperatures
  • 2009
  • In: Low temperature physics (Woodbury, N.Y., Print). - : AIP Publishing. - 1063-777X .- 1090-6517. ; 35:6, s. 484-490
  • Journal article (peer-reviewed)abstract
    • The radial thermal expansion coefficient alphar of pure and Xe-saturated bundles of single-walled carbon nanotubes (CNTs) is measured in the interval 2.2–120 K. The coefficient is positive above T=5.5 K and negative at lower temperatures. The experiment was done using a low-temperature capacitance dilatometer with a sensitivity of 2×10−9 cm, and the sample was prepared by compacting a CNT powder in such a way that the pressure applied oriented the nanotube axes perpendicular to the axis of the cylindrical sample. The data show that individual nanotubes have a negative thermal expansion, while the solid compacted material has a positive expansion coefficient due to expansion of the intertube volume in the bundles. Doping the nanotubes with Xe caused a sharp increase in the magnitude of alphar in the whole range of temperatures used and gave rise to a peak in the dependence alphar(T) in the interval 50–65 K. A subsequent decrease in the Xe concentration lowered the peak considerably but had little effect on the thermal expansion coefficient of the sample outside the region of the peak. The features revealed are explained qualitatively.
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  • Dolbin, Alexander V, et al. (author)
  • Radial thermal expansion of single-walled carbon nanotube bundles at low temperatures.
  • 2008
  • In: Fizika Nizkikh Temperatur. - : AIP Publishing. - 0132-6414. ; 34:8, s. 860-862
  • Journal article (peer-reviewed)abstract
    • For the first time, the linear coefficient of radial thermal expansion is measured on a system of carbon single-walled nanotube (SWNT) bundles at low temperatures (2.2–120 K). The measurements are performed using a dilatometer with a sensitivity of 2×10−9 cm. A cylindrical sample 7 mm high and 10 mm in diameter was obtained by compressing powder. The resulting bundles of nanotubes are oriented perpendicular to the sample axis. The starting powder consisted of over 90% SWNTs with outer diameter 1.1 nm, the length varying in the range 5–30 µm. A change of sign of the radial thermal expansion coefficient at 5.5 K is observed.
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  • Dolbin, Alexander V., et al. (author)
  • Specific features of thermal expansion and polyamorphism in CH4 – C60 solutions at low temperatures
  • 2007
  • In: Low Temperature Physics. - : AIP Publishing. - 1063-777X .- 1090-6517. ; 33:12, s. 1068-1072
  • Journal article (peer-reviewed)abstract
    • The temperature dependence of the linear thermal expansion coefficient alpha(T) is investigated in the temperature range of 2.5 to 23 K for two different CH4-C-60 solutions in which CH4 molecules occupy 24 and 50% of the octahedral interstitial sites of the C-60 lattice. In both cases, alpha(T) exhibits hysteresis, suggesting the existence of two types of orientational glass associated with these solutions. The temperature of the first-order phase transition between these two glasses is estimated, and the behavior of these two glasses is compared. The characteristic times of thermalization tau(1), reorientation of the C-60 molecules tau(2), and of the phase transformation between the glasses tau('), are estimated for these solutions. Both the temperature dependence of alpha(T) and the characteristic thermalization time tau(1) are found to have features near the phase transition temperature, and an explanation is put forward to explain these observed features.
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41.
  • Dolbin, Alexander V., et al. (author)
  • The effect of sorbed hydrogen on low-temperature radial thermal expansion of single-walled carbon nanotube bundles
  • 2009
  • In: Low temperature physics (Woodbury, N.Y., Print). - : AIP Publishing. - 1063-777X .- 1090-6517. ; 35:12, s. 939-943
  • Journal article (peer-reviewed)abstract
    • The effect of a normal H2 impurity upon the radial thermal expansion ar of single-walled carbon nanotube (SWNT) bundles has been investigated in the interval T = 2.2–27 K using the dilatometric method. It is found that H2 saturation of SWNT bundles causes a shift of the temperature interval of the negative thermal expansion towards lower (as compared to pure carbon nanotubes) temperatures and a sharp increase in the magnitude of ar in the whole range of temperatures investigated. The low temperature desorption of H2 from a powder consisting of bundles of SWNTs, open and closed at the ends, has been investigated.
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42.
  • Dolbin, Alexander V., et al. (author)
  • The effect of the noncentral impurity-matrix interaction upon the thermal expansion and polyamorphism of solid CO-C60 solutions at low temperatures
  • 2008
  • In: Fizika Nizkikh Temperatur. - : AIP Publishing. - 0132-6414. ; 34:6, s. 592-598
  • Journal article (peer-reviewed)abstract
    • Orientational glasses with CO molecules occupying 26 and 90% of the octahedral interstitial sites in the C60 lattice have been investigated by the dilatometric method in a temperature interval of 2.5–22 K. At temperatures 4–6 K the glasses undergo a first-order phase transition which is evident from the hysteresis of the thermal expansion and the maxima in the temperature dependences of the linear thermal expansion coefficients a(T), and the thermalization times t1(T) of the samples. The effect of the noncentral CO–C60 interaction upon the thermal expansion and the phase transition in these glasses was clarified by comparing the behavior of the properties of the CO–C60 and N2–C60 solutions.
  •  
43.
  • Dolbin, Alexander V., et al. (author)
  • Thermal expansion of solutions of deuteromethane in fullerite C60 at low temperature : Isotopic effect
  • 2009
  • In: Low temperature physics (Woodbury, N.Y., Print). - : American Institute of Physics. - 1063-777X .- 1090-6517. ; 35:3, s. 226-231
  • Journal article (peer-reviewed)abstract
    • The thermal expansion of CD4 solutions in the orientational glass C60 with molar concentration of deuteromethane 20 and 50% has been investigated in the temperature range 2.5–23 K. The orientational glass CD4–C60 undergoes a first-order phase transition in the temperature interval 4.5–55 K. This transition is manifested as hysteresis of the linear thermal expansion coefficient alpha as well as maxima in the temperature dependences alpha(T) and tau1(T), where tau1 is the characteristic thermalization time of the experimental samples. The characteristic re-orientation times of the C60 molecules and the characteristic phase transformations occurring in the experimental solutions are determined. The results of the present study are compared with the results of a similar study of the solution CH4–C60. It is concluded that tunneling rotation of the CH4 and CD4 molecules occupying interstitial positions in the fullerite C60 lattice occurs.
  •  
44.
  • EDEVAG, G, et al. (author)
  • Enzyme-linked immunosorbent assay-based inhibition test for neutralizing antibodies to polioviruses as an alternative to the neutralization test in tissue culture
  • 1995
  • In: Journal of clinical microbiology. - : American Society for Microbiology. - 0095-1137 .- 1098-660X. ; 33:11, s. 2927-2930
  • Journal article (peer-reviewed)abstract
    • A poliovirus-binding inhibition test (PoBI test) was established for the quantitative determination of antibodies to polioviruses and was evaluated in comparison with the conventional neutralization test (NT). The first step of the PoBI test is an incubation of serial dilutions of test samples with inactivated poliovirus followed by the detection of free viral epitopes by a double antibody sandwich enzyme-linked immunosorbent assay with type-specific capture polyclonal antisera and type-specific neutralizing monoclonal indicator antibodies. A comparison of the PoBI test with the conventional NT for antibodies to all three types in 100 human serum samples showed excellent correlations (r > 0.95) over a wide range of antibody concentrations. The PoBI test, not necessitating live virus and tissue culture facilities, could be a simple alternative to the NT, and the principle of the assay is potentially applicable to other microbial systems.
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45.
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46.
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47.
  • Elling, Devy L., et al. (author)
  • Workplace alcohol prevention : are managers' individual characteristics associated with organisational alcohol policy knowledge and inclination to initiate early alcohol interventions?
  • 2020
  • In: International Journal of Workplace Health Management. - 1753-8351 .- 1753-836X. ; 13:5, s. 543-560
  • Journal article (peer-reviewed)abstract
    • Purpose - Individual factors associated with managers' organisational alcohol policy knowledge and inclination to initiate early alcohol interventions have been understudied. This study aims to examine differences in managers' policy knowledge and inclination across a range of socio-demographic, work-related and health characteristics, and it aims to examine the association between policy knowledge and inclination to intervene, net of these characteristics.Design/methodology/approach - Questionnaire data were collected from 430 managers. Organisational alcohol policy knowledge and inclination to intervene were measured using a 5-point Likert scale ranging from 1 (very low) to 5 (very high). Socio-demographic, work-related and health characteristics included gender, age, education, managerial responsibility, years in current position, self-rated health and alcohol consumption. Associations were examined using multilevel ordinal regression analysis.Findings - Managers with a greater number of employees demonstrated the highest level of organisational alcohol policy knowledge and were more inclined to initiate early alcohol interventions. Alcohol policy knowledge was associated with inclination to intervene, net of individual characteristics.Practical implications - Considering how managers' characteristics might influence efforts to decrease hazardous alcohol consumption is potentially important when designing future workplace alcohol prevention programmes.Originality/value - Several individual factors related to managers' organisational alcohol policy knowledge and inclination to initiate early alcohol interventions were identified, particularly managerial responsibility. However, the association between policy knowledge and inclination to intervene remained strong after accounting for these individual factors. Future studies should explore alternative explanations at the individual and organisational levels.
  •  
48.
  • Ellison, A, et al. (author)
  • SiC crystal growth by HTCVD
  • 2004
  • In: Materials Science Forum, Vols. 457-460. ; , s. 9-
  • Conference paper (peer-reviewed)abstract
    • Advances in the development of the HTCVD technique for growth of bulk 2-inch diameter 4H SiC crystals are reviewed with demonstration of micropipe density down to 0.3 cm(-2), low crystal bending and X-ray rocking curve widths of 12". High Al doping in p-type substrates enables resistivities down to 0.5 Omega cm without increased micropipe density, while too high N doping causes spontaneous stacking faults formation in annealed n-type substrates. High purity semi-insulating wafers, grown under conditions reducing the incorporation of Si-vacancies, exhibit lower density of vacancy clusters and better properties for microwave device applications.
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49.
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50.
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