| 1. |
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| 2. |
- Klionsky, Daniel J., et al.
(author)
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Guidelines for the use and interpretation of assays for monitoring autophagy
- 2012
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In: Autophagy. - : Informa UK Limited. - 1554-8635 .- 1554-8627. ; 8:4, s. 445-544
-
Research review (peer-reviewed)abstract
- In 2008 we published the first set of guidelines for standardizing research in autophagy. Since then, research on this topic has continued to accelerate, and many new scientists have entered the field. Our knowledge base and relevant new technologies have also been expanding. Accordingly, it is important to update these guidelines for monitoring autophagy in different organisms. Various reviews have described the range of assays that have been used for this purpose. Nevertheless, there continues to be confusion regarding acceptable methods to measure autophagy, especially in multicellular eukaryotes. A key point that needs to be emphasized is that there is a difference between measurements that monitor the numbers or volume of autophagic elements (e.g., autophagosomes or autolysosomes) at any stage of the autophagic process vs. those that measure flux through the autophagy pathway (i.e., the complete process); thus, a block in macroautophagy that results in autophagosome accumulation needs to be differentiated from stimuli that result in increased autophagic activity, defined as increased autophagy induction coupled with increased delivery to, and degradation within, lysosomes (in most higher eukaryotes and some protists such as Dictyostelium) or the vacuole (in plants and fungi). In other words, it is especially important that investigators new to the field understand that the appearance of more autophagosomes does not necessarily equate with more autophagy. In fact, in many cases, autophagosomes accumulate because of a block in trafficking to lysosomes without a concomitant change in autophagosome biogenesis, whereas an increase in autolysosomes may reflect a reduction in degradative activity. Here, we present a set of guidelines for the selection and interpretation of methods for use by investigators who aim to examine macroautophagy and related processes, as well as for reviewers who need to provide realistic and reasonable critiques of papers that are focused on these processes. These guidelines are not meant to be a formulaic set of rules, because the appropriate assays depend in part on the question being asked and the system being used. In addition, we emphasize that no individual assay is guaranteed to be the most appropriate one in every situation, and we strongly recommend the use of multiple assays to monitor autophagy. In these guidelines, we consider these various methods of assessing autophagy and what information can, or cannot, be obtained from them. Finally, by discussing the merits and limits of particular autophagy assays, we hope to encourage technical innovation in the field.
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| 3. |
- Kristanl, Matej, et al.
(author)
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The Seventh Visual Object Tracking VOT2019 Challenge Results
- 2019
-
In: 2019 IEEE/CVF INTERNATIONAL CONFERENCE ON COMPUTER VISION WORKSHOPS (ICCVW). - : IEEE COMPUTER SOC. - 9781728150239 ; , s. 2206-2241
-
Conference paper (peer-reviewed)abstract
- The Visual Object Tracking challenge VOT2019 is the seventh annual tracker benchmarking activity organized by the VOT initiative. Results of 81 trackers are presented; many are state-of-the-art trackers published at major computer vision conferences or in journals in the recent years. The evaluation included the standard VOT and other popular methodologies for short-term tracking analysis as well as the standard VOT methodology for long-term tracking analysis. The VOT2019 challenge was composed of five challenges focusing on different tracking domains: (i) VOT-ST2019 challenge focused on short-term tracking in RGB, (ii) VOT-RT2019 challenge focused on "real-time" short-term tracking in RGB, (iii) VOT-LT2019 focused on long-term tracking namely coping with target disappearance and reappearance. Two new challenges have been introduced: (iv) VOT-RGBT2019 challenge focused on short-term tracking in RGB and thermal imagery and (v) VOT-RGBD2019 challenge focused on long-term tracking in RGB and depth imagery. The VOT-ST2019, VOT-RT2019 and VOT-LT2019 datasets were refreshed while new datasets were introduced for VOT-RGBT2019 and VOT-RGBD2019. The VOT toolkit has been updated to support both standard short-term, long-term tracking and tracking with multi-channel imagery. Performance of the tested trackers typically by far exceeds standard baselines. The source code for most of the trackers is publicly available from the VOT page. The dataset, the evaluation kit and the results are publicly available at the challenge website(1).
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| 4. |
- Tang, Ting-Ting, et al.
(author)
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Impaired thymic export and apoptosis contribute to regulatory T-cell defects in patients with chronic heart failure.
- 2011
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In: PLoS ONE. - : Public Library of Science (PLoS). - 1932-6203 .- 1932-6203. ; 6:9, s. e24272-
-
Journal article (peer-reviewed)abstract
- Animal studies suggest that regulatory T (T(reg)) cells play a beneficial role in ventricular remodeling and our previous data have demonstrated defects of T(reg) cells in patients with chronic heart failure (CHF). However, the mechanisms behind T(reg-)cell defects remained unknown. We here sought to elucidate the mechanism of T(reg-)cell defects in CHF patients.
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| 5. |
- Ariyawansa, Hiran A., et al.
(author)
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Fungal diversity notes 111–252—taxonomic and phylogenetic contributions to fungal taxa
- 2015
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In: Fungal diversity. - : Springer Science and Business Media LLC. - 1560-2745 .- 1878-9129. ; 75, s. 27-274
-
Journal article (peer-reviewed)abstract
- This paper is a compilation of notes on 142 fungal taxa, including five new families, 20 new genera, and 100 new species, representing a wide taxonomic and geographic range. The new families, Ascocylindricaceae, Caryosporaceae and Wicklowiaceae (Ascomycota) are introduced based on their distinct lineages and unique morphology. The new Dothideomycete genera Pseudomassariosphaeria (Amniculicolaceae), Heracleicola, Neodidymella and P s e u d o m i c ros p h a e r i o p s i s ( D id y m e l l a c e a e ) , P s e u d o p i t h o m y c e s ( D i d y m o s p h a e r i a c e a e ) , Brunneoclavispora, Neolophiostoma and Sulcosporium (Halotthiaceae), Lophiohelichrysum (Lophiostomataceae), G a l l i i c o l a , Popul o c re s c e n t i a a nd Va g i c o l a (Phaeosphaeriaceae), Ascocylindrica (Ascocylindricaceae), E l o n g a t o p e d i c e l l a t a ( R o u s s o e l l a c e a e ) , Pseudoasteromassaria (Latoruaceae) and Pseudomonodictys (Macrodiplodiopsidaceae) are introduced. The newly described species of Dothideomycetes (Ascomycota) are Pseudomassariosphaeria bromicola (Amniculicolaceae), Flammeascoma lignicola (Anteagloniaceae), Ascocylindrica marina (Ascocylindricaceae) , Lembosia xyliae (Asterinaceae), Diplodia crataegicola and Diplodia galiicola ( B o t r yosphae r i a cea e ) , Caryospor a aquat i c a (Caryosporaceae), Heracleicola premilcurensis and Neodi dymell a thai landi cum (Didymellaceae) , Pseudopithomyces palmicola (Didymosphaeriaceae), Floricola viticola (Floricolaceae), Brunneoclavispora bambusae, Neolophiostoma pigmentatum and Sulcosporium thailandica (Halotthiaceae), Pseudoasteromassaria fagi (Latoruaceae), Keissleriella dactylidicola (Lentitheciaceae), Lophiohelichrysum helichrysi (Lophiostomataceae), Aquasubmersa japonica (Lophiotremataceae) , Pseudomonodictys tectonae (Macrodiplodiopsidaceae), Microthyrium buxicola and Tumidispora shoreae (Microthyriaceae), Alloleptosphaeria clematidis, Allophaeosphaer i a c y t i s i , Allophaeosphae r i a subcylindrospora, Dematiopleospora luzulae, Entodesmium artemisiae, Galiicola pseudophaeosphaeria, Loratospora(Basidiomycota) are introduced together with a new genus Neoantrodiella (Neoantrodiellaceae), here based on both morphology coupled with molecular data. In the class Agaricomycetes, Agaricus pseudolangei, Agaricus haematinus, Agaricus atrodiscus and Agaricus exilissimus (Agaricaceae) , Amanita m e l l e i a l b a , Amanita pseudosychnopyramis and Amanita subparvipantherina (Amanitaceae), Entoloma calabrum, Cora barbulata, Dictyonema gomezianum and Inocybe granulosa (Inocybaceae), Xerocomellus sarnarii (Boletaceae), Cantharellus eucalyptorum, Cantharellus nigrescens, Cantharellus tricolor and Cantharellus variabilicolor (Cantharellaceae), Cortinarius alboamarescens, Cortinarius brunneoalbus, Cortinarius ochroamarus, Cortinarius putorius and Cortinarius seidlii (Cortinariaceae), Hymenochaete micropora and Hymenochaete subporioides (Hymenochaetaceae), Xylodon ramicida (Schizoporaceae), Colospora andalasii (Polyporaceae), Russula guangxiensis and Russula hakkae (Russulaceae), Tremella dirinariae, Tremella graphidis and Tremella pyrenulae (Tremellaceae) are introduced. Four new combinations Neoantrodiella gypsea, Neoantrodiella thujae (Neoantrodiellaceae), Punctulariopsis cremeoalbida, Punctulariopsis efibulata (Punctulariaceae) are also introduced here for the division Basidiomycota. Furthermore Absidia caatinguensis, Absidia koreana and Gongronella koreana (Cunninghamellaceae), Mortierella pisiformis and Mortierella formosana (Mortierellaceae) are newly introduced in the Zygomycota, while Neocallimastix cameroonii and Piromyces irregularis (Neocallimastigaceae) ar e i n t roduced i n the Neocallimastigomycota. Reference specimens or changes in classification and notes are provided for Alternaria ethzedia, Cucurbitaria ephedricola, Austropleospora, Austropleospora archidendri, Byssosphaeria rhodomphala, Lophiostoma caulium, Pseudopithomyces maydicus, Massariosphaeria, Neomassariosphaeria and Pestalotiopsis montellica.
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| 6. |
- Beal, Jacob, et al.
(author)
-
Robust estimation of bacterial cell count from optical density
- 2020
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In: Communications Biology. - : Springer Science and Business Media LLC. - 2399-3642. ; 3:1
-
Journal article (peer-reviewed)abstract
- Optical density (OD) is widely used to estimate the density of cells in liquid culture, but cannot be compared between instruments without a standardized calibration protocol and is challenging to relate to actual cell count. We address this with an interlaboratory study comparing three simple, low-cost, and highly accessible OD calibration protocols across 244 laboratories, applied to eight strains of constitutive GFP-expressing E. coli. Based on our results, we recommend calibrating OD to estimated cell count using serial dilution of silica microspheres, which produces highly precise calibration (95.5% of residuals <1.2-fold), is easily assessed for quality control, also assesses instrument effective linear range, and can be combined with fluorescence calibration to obtain units of Molecules of Equivalent Fluorescein (MEFL) per cell, allowing direct comparison and data fusion with flow cytometry measurements: in our study, fluorescence per cell measurements showed only a 1.07-fold mean difference between plate reader and flow cytometry data.
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| 7. |
- Feng, Ruizhi, et al.
(author)
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Mutations in TUBB8 and Human Oocyte Meiotic Arrest.
- 2016
-
In: The New England journal of medicine. - 1533-4406. ; 374:3, s. 223-232
-
Journal article (peer-reviewed)abstract
- Background Human reproduction depends on the fusion of a mature oocyte with a sperm cell to form a fertilized egg. The genetic events that lead to the arrest of human oocyte maturation are unknown. Methods We sequenced the exomes of five members of a four-generation family, three of whom had infertility due to oocyte meiosis I arrest. We performed Sanger sequencing of a candidate gene, TUBB8, in DNA samples from these members, additional family members, and members of 23 other affected families. The expression of TUBB8 and all other β-tubulin isotypes was assessed in human oocytes, early embryos, sperm cells, and several somatic tissues by means of a quantitative reverse-transcriptase-polymerase-chain-reaction assay. We evaluated the effect of the TUBB8 mutations on the assembly of the heterodimer consisting of one α-tubulin polypeptide and one β-tubulin polypeptide (α/β-tubulin heterodimer) in vitro, on microtubule architecture in HeLa cells, on microtubule dynamics in yeast cells, and on spindle assembly in mouse and human oocytes. Results We identified seven mutations in the primate-specific gene TUBB8 that were responsible for oocyte meiosis I arrest in 7 of the 24 families. TUBB8 expression is unique to oocytes and the early embryo, in which this gene accounts for almost all the expressed β-tubulin. The mutations affect chaperone-dependent folding and assembly of the α/β-tubulin heterodimer, disrupt microtubule behavior on expression in cultured cells, alter microtubule dynamics in vivo, and cause catastrophic spindle-assembly defects and maturation arrest on expression in mouse and human oocytes. Conclusions TUBB8 mutations have dominant-negative effects that disrupt microtubule behavior and oocyte meiotic spindle assembly and maturation, causing female infertility. (Funded by the National Basic Research Program of China and others.).
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| 8. |
- Luo, Yifei, et al.
(author)
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Technology Roadmap for Flexible Sensors
- 2023
-
In: ACS Nano. - : American Chemical Society. - 1936-0851 .- 1936-086X. ; 17:6, s. 5211-5295
-
Research review (peer-reviewed)abstract
- Humans rely increasingly on sensors to address grand challenges and to improve quality of life in the era of digitalization and big data. For ubiquitous sensing, flexible sensors are developed to overcome the limitations of conventional rigid counterparts. Despite rapid advancement in bench-side research over the last decade, the market adoption of flexible sensors remains limited. To ease and to expedite their deployment, here, we identify bottlenecks hindering the maturation of flexible sensors and propose promising solutions. We first analyze challenges in achieving satisfactory sensing performance for real-world applications and then summarize issues in compatible sensor-biology interfaces, followed by brief discussions on powering and connecting sensor networks. Issues en route to commercialization and for sustainable growth of the sector are also analyzed, highlighting environmental concerns and emphasizing nontechnical issues such as business, regulatory, and ethical considerations. Additionally, we look at future intelligent flexible sensors. In proposing a comprehensive roadmap, we hope to steer research efforts towards common goals and to guide coordinated development strategies from disparate communities. Through such collaborative efforts, scientific breakthroughs can be made sooner and capitalized for the betterment of humanity.
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| 9. |
- Meng, Jingxiang, et al.
(author)
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Adaptive Differentiation in Seedling Traits in a Hybrid Pine Species Complex, Pinus densata and Its Parental Species, on the Tibetan Plateau
- 2015
-
In: PLOS ONE. - : Public Library of Science (PLoS). - 1932-6203. ; 10:3
-
Journal article (peer-reviewed)abstract
- Evidence from molecular genetics demonstrates that Pinus densata is a natural homoploid hybrid originating from the parent species Pinus tabuliformis and Pinus yunnanensis, and ecological selection may have played a role in the speciation of Pinus densata. However, data on differentiation in adaptive traits in the species complex are scarce. In this study, we performed a common garden test on 16 seedling traits to examine the differences between Pinus densata and its parental species in a high altitude environment. We found that among the 16 analyzed traits, 15 were significantly different among the species. Pinus tabuliformis had much earlier bud set and a relatively higher bud set ratio but poorer seedling growth, and Pinus yunnanensis had opposite responses for the same traits. Pinus densata had the greatest fitness with higher viability and growth rates than the parents. The relatively high genetic contribution of seedling traits among populations suggested that within each species the evolutionary background is complex. The correlations between the seedling traits of a population within a species and the environmental factors indicated different impacts of the environment on species evolution. The winter temperature is among the most important climate factors that affected the fitness of the three pine species. Our investigation provides empirical evidence on adaptive differentiation among this pine species complex at seedling stages.
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| 10. |
- Xing, Fangqian, et al.
(author)
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Needle morphological evidence of the homoploid hybrid origin of Pinus densata based on analysis of artificial hybrids and the putative parents, Pinus tabuliformis and Pinus yunnanensis
- 2014
-
In: Ecology and Evolution. - : Wiley. - 2045-7758. ; 4:10, s. 1890-1902
-
Journal article (peer-reviewed)abstract
- Genetic analyses indicate that Pinus densata is a natural homoploid hybrid originating from Pinus tabuliformis and Pinus yunnanensis. Needle morphological and anatomical features show relative species stability and can be used to identify coniferous species. Comparative analyses of these needle characteristics and phenotypic differences between the artificial hybrids, P.densata, and parental species can be used to determine the genetic and phenotypic evolutionary consequences of natural hybridization. Twelve artificial hybrid families, the two parental species, and P.densata were seeded in a high-altitude habitat in Linzhi, Tibet. The needles of artificial hybrids and the three pine species were collected, and 24 needle morphological and anatomical traits were analyzed. Based on these results, variations in 10 needle traits among artificial hybrid families and 22 traits among species and artificial hybrids were predicted and found to be under moderate genetic control. Nineteen needle traits in artificial hybrids were similar to those in P.densata and between the two parental species, P.tabuliformis and P.yunnanensis. The ratio of plants with three needle clusters in artificial hybrids was 22.92%, which was very similar to P.densata. The eight needle traits (needle length, the mean number of stomata in sections 2mm in length of the convex and flat sides of the needle, mean stomatal density, mesophyll/vascular bundle area ratio, mesophyll/resin canal area ratio, mesophyll/(resin canals and vascular bundles) area ratio, vascular bundle/resin canal area ratio) relative to physiological adaptability were similar to the artificial hybrids and P.densata. The similar needle features between the artificial hybrids and P.densata could be used to verify the homoploid hybrid origin of P.densata and helps to better understand of the hybridization roles in adaptation and speciation in plants.
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| 11. |
- Chang, J. F., et al.
(author)
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Ni2P Makes Application of the PtRu Catalyst Much Stronger in Direct Methanol Fuel Cells
- 2015
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In: ChemSusChem. - : Wiley. - 1864-5631 .- 1864-564X. ; 8:19, s. 3340-3346
-
Journal article (peer-reviewed)abstract
- PtRu is regarded as the best catalyst for direct methanol fuel cells, but the performance decay resulting from the loss of Ru seriously hinders commercial applications. Herein, we demonstrated that the presence of Ni2P largely reduces Ru loss, which thus makes the application of PtRu much stronger in direct methanol fuel cells. Outstanding catalytic activity and stability were observed by cyclic voltammetry. Upon integrating the catalyst material into a practical direct methanol fuel cell, the highest maximum power density was achieved on the PtRu-Ni2P/C catalyst among the reference catalysts at different temperatures. A maximum power density of 69.9mWcm-2 at 30°C was obtained on PtRu-Ni2P/C, which is even higher than the power density of the state-of-the-art commercial PtRu catalyst at 70°C (63.1mWcm-2). Moreover, decay in the performance resulting from Ru loss was greatly reduced owing to the presence of Ni2P, which is indicative of very promising applications.
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| 12. |
- Chen, DS, et al.
(author)
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Single cell atlas for 11 non-model mammals, reptiles and birds
- 2021
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In: Nature communications. - : Springer Science and Business Media LLC. - 2041-1723. ; 12:1, s. 7083-
-
Journal article (peer-reviewed)abstract
- The availability of viral entry factors is a prerequisite for the cross-species transmission of severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2). Large-scale single-cell screening of animal cells could reveal the expression patterns of viral entry genes in different hosts. However, such exploration for SARS-CoV-2 remains limited. Here, we perform single-nucleus RNA sequencing for 11 non-model species, including pets (cat, dog, hamster, and lizard), livestock (goat and rabbit), poultry (duck and pigeon), and wildlife (pangolin, tiger, and deer), and investigated the co-expression of ACE2 and TMPRSS2. Furthermore, cross-species analysis of the lung cell atlas of the studied mammals, reptiles, and birds reveals core developmental programs, critical connectomes, and conserved regulatory circuits among these evolutionarily distant species. Overall, our work provides a compendium of gene expression profiles for non-model animals, which could be employed to identify potential SARS-CoV-2 target cells and putative zoonotic reservoirs.
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| 13. |
- Chen, Xing, et al.
(author)
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Chronic stability of a neuroprosthesis comprising multiple adjacent Utah arrays in monkeys
- 2023
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In: Journal of Neural Engineering. - 1741-2560 .- 1741-2552. ; 20:3
-
Journal article (peer-reviewed)abstract
- Objective. Electrical stimulation of visual cortex via a neuroprosthesis induces the perception of dots of light ('phosphenes'), potentially allowing recognition of simple shapes even after decades of blindness. However, restoration of functional vision requires large numbers of electrodes, and chronic, clinical implantation of intracortical electrodes in the visual cortex has only been achieved using devices of up to 96 channels. We evaluated the efficacy and stability of a 1024-channel neuroprosthesis system in non-human primates (NHPs) over more than 3 years to assess its suitability for long-term vision restoration. Approach. We implanted 16 microelectrode arrays (Utah arrays) consisting of 8 x 8 electrodes with iridium oxide tips in the primary visual cortex (V1) and visual area 4 (V4) of two sighted macaques. We monitored the animals' health and measured electrode impedances and neuronal signal quality by calculating signal-to-noise ratios of visually driven neuronal activity, peak-to-peak voltages of the waveforms of action potentials, and the number of channels with high-amplitude signals. We delivered cortical microstimulation and determined the minimum current that could be perceived, monitoring the number of channels that successfully yielded phosphenes. We also examined the influence of the implant on a visual task after 2-3 years of implantation and determined the integrity of the brain tissue with a histological analysis 3-3.5 years post-implantation. Main results. The monkeys remained healthy throughout the implantation period and the device retained its mechanical integrity and electrical conductivity. However, we observed decreasing signal quality with time, declining numbers of phosphene-evoking electrodes, decreases in electrode impedances, and impaired performance on a visual task at visual field locations corresponding to implanted cortical regions. Current thresholds increased with time in one of the two animals. The histological analysis revealed encapsulation of arrays and cortical degeneration. Scanning electron microscopy on one array revealed degradation of IrOx coating and higher impedances for electrodes with broken tips. Significance. Long-term implantation of a high-channel-count device in NHP visual cortex was accompanied by deformation of cortical tissue and decreased stimulation efficacy and signal quality over time. We conclude that improvements in device biocompatibility and/or refinement of implantation techniques are needed before future clinical use is feasible.
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| 14. |
- Feng, C., et al.
(author)
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Addressing transient and permanent faults in NoC with efficient fault-tolerant deflection router
- 2013
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In: IEEE Transactions on Very Large Scale Integration (vlsi) Systems. - 1063-8210 .- 1557-9999. ; 21:6, s. 1053-1066
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Journal article (peer-reviewed)abstract
- Continuing decrease in the feature size of integrated circuits leads to increases in susceptibility to transient and permanent faults. This paper proposes a fault-tolerant solution for a bufferless network-on-chip, including an on-line fault-diagnosis mechanism to detect both transient and permanent faults, a hybrid automatic repeat request, and forward error correction link-level error control scheme to handle transient faults and a reinforcement-learning-based fault-tolerant deflection routing (FTDR) algorithm to tolerate permanent faults without deadlock and livelock. A hierarchical-routing-table-based algorithm (FTDR-H) is also presented to reduce the area overhead of the FTDR router. Synthesized results show that, compared with the FTDR router, the FTDR-H router can reduce the area by 27% in an 8×8 network. Simulation results demonstrate that under synthetic workloads, in the presence of permanent link faults, the throughput of an 8×8 network with FTDR and FTDR-H algorithms are 14% and 23% higher on average than that with the fault-on-neighbor (FoN) aware deflection routing algorithm and the cost-based deflection routing algorithm, respectively. Under real application workloads, the FTDR-H algorithm achieves 20% less hop counts on average than that of the FoN algorithm. For transient faults, the performance of the FTDR router can achieve graceful degradation even at a high fault rate. We also implement the fault-tolerant deflection router which can achieve 400 MHz in TSMC 65-nm technology.
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| 15. |
- Feng, Ligang, 1983, et al.
(author)
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Nanostructured PtRu/C catalyst promoted by CoP as an efficient and robust anode catalyst in direct methanol fuel cells
- 2015
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In: Nano Energy. - : Elsevier BV. - 2211-2855. ; 15, s. 462-469
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Journal article (peer-reviewed)abstract
- Nanostructured PtRu material is considered as the best catalyst for direct methanol fuel cells (DMFCs), but the performance decay resulting from Ru loss seriously hinders the commercial application. Here we demonstrated that the performance of nanostructured PtRu catalyst for methanol oxidation could be significantly improved by CoP material; the presence of CoP could largely slow down the loss of Ru and Pt in PtRu catalyst system, thus promising a highly active and durable performance in DMFCs. Cyclic Voltammetry results showed the peak current is 2.89 times higher than that of state-of-the-art commercial PtRu/C-JM (231.9mAmg-1PtRu) and 3.86 times higher than that of the home-made reference (PtRu/C-H) catalyst (173.6mAmg-1PtRu); kinetics study probed by electrochemical impedance spectroscopy showed a large reduced charge transfer resistance in the rate determining step. The highest maximum power density was achieved on this novel PtRu-CoP/C catalyst among all the evaluated catalysts at different temperatures. Specifically, a maximum power density of 85.7mWcm-2 achieved at 30°C is much higher than that of state-of-the-art commercial PtRu/C catalyst at 70°C (63.1mWcm-2). Outstanding catalytic activity and stability observed on this novel PtRu-CoP/C catalyst should be attributed to a synergistic effect between the nanostructured PtRu and CoP, in which the presence of CoP increases PtRu physical stability and anti-CO poisoning ability. The present work is a significant step that opens an avenue in the development of highly active and durable catalysts for fuel cells technology, and makes PtRu catalyst system much closer for commercial application in DMFCs.
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| 16. |
- Gao, Mingming, et al.
(author)
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Engineered 2D MXene-based materials for advanced supercapacitors and micro-supercapacitors
- 2024
-
In: Materials Today. - 1369-7021 .- 1873-4103. ; 72, s. 318-358
-
Research review (peer-reviewed)abstract
- The class of two-dimensional transition metal carbides/nitrides/oxycarbides (known as MXenes) has shown great potential in energy storage applications due to their intrinsic layered structure, outstanding electrical conductivity, tunable surface chemistry, and unique physicochemical properties. This review summarizes the latest progresses of MXene-based materials for supercapacitors and micro-supercapacitors. First, state-of-the-art structural engineering strategies for the construction of novel MXene-based electrodes are highlighted, as the electrochemical performance of MXenes is influenced by their structure, such as interlayer spacing and surface functional group density. Furthermore, the charge storage mechanisms of MXene-based electrodes in different electrolytes are discussed to stimulate further design and development of tailored materials for high-performance devices. Moreover, different device fabrication technologies are summarized and the achievements of specific device geometries (e.g., fiber-shape, planar-type, and three-dimensional devices) containing MXene-based materials are critically reviewed. Finally, perspectives and outlook for the development of high-performance MXene-based electrodes in terms of material engineering, performance improvement and device innovation are provided, clearly indicating research directions for next-generation advanced energy storage devices.
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| 17. |
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| 18. |
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| 19. |
- Huang, Liangliang, et al.
(author)
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Study on continuous cold-pressing technology of engineered wood flooring with EPI adhesive
- 2018
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In: Wood research. - : Statny Drevarsky Vyskumny Ustav. - 1336-4561. ; 63:2, s. 335-342
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Journal article (peer-reviewed)abstract
- The effects of process parameters (adhesive spread, press time, and applied pressure) on the gluing performance of engineered wood flooring bonded with emulsion-polymer-isocyanate (EPI) adhesive were studied. The results showed (shear strength and aging test) that the major factors were adhesive spread and press time. The optimized parameters for best gluing performance of engineered wood flooring were 160 g.m-2, 14 s, and 60 s for adhesive spread, heat time, and press time, respectively, within certain ranges
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| 20. |
- Huang, Xing, et al.
(author)
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Semiconducting Conjugated Coordination Polymer with High Charge Mobility Enabled by "4+2" Phenyl Ligands
- 2023
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In: Journal of the American Chemical Society. - : AMER CHEMICAL SOC. - 0002-7863 .- 1520-5126. ; 145:4, s. 2430-2438
-
Journal article (peer-reviewed)abstract
- Electrically conductive coordination polymers and metal-organic frameworks are attractive emerging electroactive materials for (opto-)electronics. However, developing semiconducting coordination polymers with high charge carrier mobility for devices remains a major challenge, urgently requiring the rational design of ligands and topological networks with desired electronic structures. Herein, we demonstrate a strategy for synthesizing high-mobility semiconducting conjugated coordination polymers (c-CPs) utilizing novel conjugated ligands with D2h symmetry, namely, "4 + 2" phenyl ligands. Compared with the conventional phenyl ligands with C6h symmetry, the reduced symmetry of the "4 + 2" ligands leads to anisotropic coordination in the formation of c-CPs. Consequently, we successfully achieve a single-crystalline three-dimensional (3D) c-CP Cu4DHTTB (DHTTB = 2,5-dihydroxy-1,3,4,6-tetrathiolbenzene), containing orthogonal ribbon-like pi-d conjugated chains rather than 2D conjugated layers. DFT calculation suggests that the resulting Cu4DHTTB exhibits a small band gap (similar to 0.2 eV), strongly dispersive energy bands near the Fermi level with a low electron-hole reduced effective mass (similar to 0.2m0*). Furthermore, the four-probe method reveals a semiconducting behavior with a decent conductivity of 0.2 S/cm. Thermopower measurement suggests that it is a p-type semiconductor. Ultrafast terahertz photoconductivity measurements confirm Cu4DHTTB's semiconducting nature and demonstrate the Drude-type transport with high charge carrier mobilities up to 88 +/- 15 cm2 V-1 s-1, outperforming the conductive 3D coordination polymers reported till date. This molecular design strategy for constructing high-mobility semiconducting c-CPs lays the foundation for achieving high-performance c-CP-based (opto-)electronics.
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| 21. |
- Hudson, Thomas J., et al.
(author)
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International network of cancer genome projects
- 2010
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In: Nature. - : Springer Science and Business Media LLC. - 0028-0836 .- 1476-4687. ; 464:7291, s. 993-998
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Journal article (peer-reviewed)abstract
- The International Cancer Genome Consortium (ICGC) was launched to coordinate large-scale cancer genome studies in tumours from 50 different cancer types and/or subtypes that are of clinical and societal importance across the globe. Systematic studies of more than 25,000 cancer genomes at the genomic, epigenomic and transcriptomic levels will reveal the repertoire of oncogenic mutations, uncover traces of the mutagenic influences, define clinically relevant subtypes for prognosis and therapeutic management, and enable the development of new cancer therapies.
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| 22. |
- Jia, Xue, et al.
(author)
-
CsPb(IxBr1-x)(3) solar cells
- 2019
-
In: Science Bulletin. - : ELSEVIER. - 2095-9273. ; 64:20, s. 1532-1539
-
Journal article (peer-reviewed)abstract
- Owing to its nice performance, low cost, and simple solution-processing, organic-inorganic hybrid perovskite solar cell (PSC) becomes a promising candidate for next-generation high-efficiency solar cells. The power conversion efficiency (PCE) has boosted from 3.8% to 25.2% over the past ten years. Despite the rapid progress in PCE, the device stability is a key issue that impedes the commercialization of PSCs. Recently, all-inorganic cesium lead halide perovskites have attracted much attention due to their better stability compared with their organic-inorganic counterpart. In this progress report, we summarize the properties of CsPb(IxBr1-x)(3) and their applications in solar cells. The current challenges and corresponding solutions are discussed. Finally, we share our perspectives on CsPb(IxBr1-x)(3) solar cells and outline possible directions to further improve the device performance. (C) 2019 Science China Press. Published by Elsevier B.V. and Science China Press. All rights reserved.
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| 23. |
- Kanoni, Stavroula, et al.
(author)
-
Implicating genes, pleiotropy, and sexual dimorphism at blood lipid loci through multi-ancestry meta-analysis.
- 2022
-
In: Genome biology. - : Springer Science and Business Media LLC. - 1474-760X .- 1465-6906 .- 1474-7596. ; 23:1
-
Journal article (peer-reviewed)abstract
- Genetic variants within nearly 1000 loci are known to contribute to modulation of blood lipid levels. However, the biological pathways underlying these associations are frequently unknown, limiting understanding of these findings and hindering downstream translational efforts such as drug target discovery.To expand our understanding of the underlying biological pathways and mechanisms controlling blood lipid levels, we leverage a large multi-ancestry meta-analysis (N=1,654,960) of blood lipids to prioritize putative causal genes for 2286 lipid associations using six gene prediction approaches. Using phenome-wide association (PheWAS) scans, we identify relationships of genetically predicted lipid levels to other diseases and conditions. We confirm known pleiotropic associations with cardiovascular phenotypes and determine novel associations, notably with cholelithiasis risk. We perform sex-stratified GWAS meta-analysis of lipid levels and show that 3-5% of autosomal lipid-associated loci demonstrate sex-biased effects. Finally, we report 21 novel lipid loci identified on the X chromosome. Many of the sex-biased autosomal and X chromosome lipid loci show pleiotropic associations with sex hormones, emphasizing the role of hormone regulation in lipid metabolism.Taken together, our findings provide insights into the biological mechanisms through which associated variants lead to altered lipid levels and potentially cardiovascular disease risk.
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| 24. |
- Kong, P. P., et al.
(author)
-
Superconductivity in Strong Spin Orbital Coupling Compound Sb2Se3
- 2014
-
In: Scientific Reports. - : Springer Science and Business Media LLC. - 2045-2322. ; 4, s. 6679-
-
Journal article (peer-reviewed)abstract
- Recently, A(2)B(3) type strong spin orbital coupling compounds such as Bi2Te3, Bi2Se3 and Sb2Te3 were theoretically predicated to be topological insulators and demonstrated through experimental efforts. The counterpart compound Sb2Se3 on the other hand was found to be topological trivial, but further theoretical studies indicated that the pressure might induce Sb2Se3 into a topological nontrivial state. Here, we report on the discovery of superconductivity in Sb2Se3 single crystal induced via pressure. Our experiments indicated that Sb2Se3 became superconductive at high pressures above 10 GPa proceeded by a pressure induced insulator to metal like transition at similar to 3 GPa which should be related to the topological quantum transition. The superconducting transition temperature (T-C) increased to around 8.0 K with pressure up to 40 GPa while it keeps ambient structure. High pressure Raman revealed that new modes appeared around 10 GPa and 20 GPa, respectively, which correspond to occurrence of superconductivity and to the change of T-C slop as the function of high pressure in conjunction with the evolutions of structural parameters at high pressures.
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| 25. |
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| 26. |
- Kristan, Matej, et al.
(author)
-
The Visual Object Tracking VOT2015 challenge results
- 2015
-
In: Proceedings 2015 IEEE International Conference on Computer Vision Workshops ICCVW 2015. - : IEEE. - 9780769557205 ; , s. 564-586
-
Conference paper (peer-reviewed)abstract
- The Visual Object Tracking challenge 2015, VOT2015, aims at comparing short-term single-object visual trackers that do not apply pre-learned models of object appearance. Results of 62 trackers are presented. The number of tested trackers makes VOT 2015 the largest benchmark on short-term tracking to date. For each participating tracker, a short description is provided in the appendix. Features of the VOT2015 challenge that go beyond its VOT2014 predecessor are: (i) a new VOT2015 dataset twice as large as in VOT2014 with full annotation of targets by rotated bounding boxes and per-frame attribute, (ii) extensions of the VOT2014 evaluation methodology by introduction of a new performance measure. The dataset, the evaluation kit as well as the results are publicly available at the challenge website(1).
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| 27. |
- Kristan, Matej, et al.
(author)
-
The Visual Object Tracking VOT2016 Challenge Results
- 2016
-
In: COMPUTER VISION - ECCV 2016 WORKSHOPS, PT II. - Cham : SPRINGER INT PUBLISHING AG. - 9783319488813 - 9783319488806 ; , s. 777-823
-
Conference paper (peer-reviewed)abstract
- The Visual Object Tracking challenge VOT2016 aims at comparing short-term single-object visual trackers that do not apply pre-learned models of object appearance. Results of 70 trackers are presented, with a large number of trackers being published at major computer vision conferences and journals in the recent years. The number of tested state-of-the-art trackers makes the VOT 2016 the largest and most challenging benchmark on short-term tracking to date. For each participating tracker, a short description is provided in the Appendix. The VOT2016 goes beyond its predecessors by (i) introducing a new semi-automatic ground truth bounding box annotation methodology and (ii) extending the evaluation system with the no-reset experiment.
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| 28. |
- Langer, Judith, et al.
(author)
-
Present and Future of Surface-Enhanced Raman Scattering
- 2020
-
In: ACS Nano. - : American Chemical Society (ACS). - 1936-086X .- 1936-0851. ; 14:1, s. 28-117
-
Research review (peer-reviewed)abstract
- The discovery of the enhancement of Raman scattering by molecules adsorbed on nanostructured metal surfaces is a landmark in the history of spectroscopic and analytical techniques. Significant experimental and theoretical effort has been directed toward understanding the surface-enhanced Raman scattering (SERS) effect and demonstrating its potential in various types of ultrasensitive sensing applications in a wide variety of fields. In the 45 years since its discovery, SERS has blossomed into a rich area of research and technology, but additional efforts are still needed before it can be routinely used analytically and in commercial products. In this Review, prominent authors from around the world joined together to summarize the state of the art in understanding and using SERS and to predict what can be expected in the near future in terms of research, applications, and technological development. This Review is dedicated to SERS pioneer and our coauthor, the late Prof. Richard Van Duyne, whom we lost during the preparation of this article. ©
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| 29. |
- Li, Guoqiang, et al.
(author)
-
Activity of Platinum/Carbon and Palladium/Carbon Catalysts Promoted by Ni2P in Direct Ethanol Fuel Cells
- 2014
-
In: ChemSusChem. - : Wiley. - 1864-5631 .- 1864-564X. ; 7:12, s. 3374-3381
-
Journal article (peer-reviewed)abstract
- Ethanol is an alternative fuel for direct alcohol fuel cells, inwhich the electrode materials are commonly based on Pt orPd. Owing to the excellent promotion effect of Ni2P that wasfound in methanol oxidation, we extended the catalyst systemof Pt or Pd modified by Ni2P in direct ethanol fuel cells. TheNi2P-promoted catalysts were compared to commercial catalystsas well as to reference catalysts promoted with only Ni oronly P. Among the studied catalysts, Pt/C and Pd/C modifiedby Ni2P (30 wt%) showed both the highest activity and stability.Upon integration into the anode of a homemade direct ethanolfuel cell, the Pt-Ni2P/C-30% catalyst showed a maximumpower density of 21 mWcm-2, which is approximately twotimes higher than that of a commercial Pt/C catalyst. The Pd-Ni2P/C-30% catalyst exhibited a maximum power density of90 mWcm-2. This is approximately 1.5 times higher than thatof a commercial Pd/C catalyst. The discharge stability on bothtwo catalysts was also greatly improved over a 12 h dischargeoperation.
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| 30. |
- Li, Yongqiang, 1992, et al.
(author)
-
Assessment of compositional changes of carbonated cement pastes subjected to high temperatures using in-situ Raman mapping and XPS
- 2022
-
In: Journal of Building Engineering. - : Elsevier BV. - 2352-7102. ; 45
-
Journal article (peer-reviewed)abstract
- This paper presents a new method for assessing the compositional changes of carbonated cement pastes subjected to high temperatures. In this new method, in-situ Raman mapping combined with X-ray photoelectron spectroscopy (XPS) was used to monitor the phase transformation in carbonated cement pastes subjected to various high temperatures from 30 to 950 degrees C. Two kinds of carbonated areas, i.e., vaterite dominated and calcite dominated, were found in the in-situ Raman measurements. With the elevation in temperature, most of the vaterite was converted to calcite at 500 degrees C and completely decomposed at 600 degrees C, while the decomposition of calcite started at 600 degrees C and finished at 720 degrees C. Meanwhile, the depolymerization of the calcium modified silica gel to the silicate phases with a lower degree of polymerization was initiated at 500 degrees C, which led to the crystallization of beta-C2S at 600 degrees C. The generation of beta-C2S was found to increase with the elevation in temperature and became the dominant phase at 950 degrees C. In conclusion, the high temperature could affect the stability of carbonated cement pastes at 500 degrees C and above. The in-situ Raman mapping measurement has provided an extraordinary view of the spatial distribution of interesting phases subjected to high temperatures in a nondestructive way, which should be more consistent with the true condition in the material.
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| 31. |
- Li, Yongqiang, 1992, et al.
(author)
-
Evolution of Microstructural Characteristics of Carbonated Cement Pastes Subjected to High Temperatures Evaluated by MIP and SEM
- 2022
-
In: Materials. - : MDPI AG. - 1996-1944. ; 15:17
-
Journal article (peer-reviewed)abstract
- The microstructural evolutions of both uncarbonated and carbonated cement pastes subjected to various high temperatures (30 degrees C, 200 degrees C, 400 degrees C, 500 degrees C, 600 degrees C, 720 degrees C, and 950 degrees C) are presented in this study by the means of mercury intrusion porosimetry (MIP) and scanning electron microscopy (SEM). It was found that the thermal stabilities of uncarbonated cement pastes were significantly changed from 400 to 500 degrees C due to the decomposition of portlandite at this temperature range. More large pores and microcracks were generated from 600 to 720 degrees C, with the depolymerization of C-S-H. After carbonation, the microstructures of carbonated cement pastes remained unchanged below 500 degrees C and started to degrade at 600 degrees C, due to the decompositions of calcium carbonates and calcium modified silica gel. At 950 degrees C, both uncarbonated and carbonated cement pastes showed a loosely honeycombed microstructure, composed mainly of beta-C2S and lime. It can be concluded that carbonation improves the high-temperature resistance of cement pastes up to 500 degrees C, but this advantage is lost at temperatures over 600 degrees C.
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| 32. |
- Li, Yong Qiang, et al.
(author)
-
Carbonation of the synthetic calcium silicate hydrate (C-S-H) under different concentrations of CO2: Chemical phases analysis and kinetics
- 2020
-
In: Journal of CO2 Utilization. - : Elsevier BV. - 2212-9820. ; 35, s. 303-313
-
Journal article (peer-reviewed)abstract
- In this study, the chemical phases analysis and the kinetics of synthetic calcium silicate hydrate (C-S-H) under differentCO2concentrations (natural (0.03%), 3%, 10%, 20%, 50%, 100%) were investigated. For this aim, the scanning electron microscope (SEM) and transmission electron microscope (TEM) were employed for microstructure characterisation. The 29Si magic angle spinning nuclear magnetic resonance (29Si MAS NMR), X-ray diffraction (XRD) and thermogravimetric analysis (TGA) coupled with mass spectrometer (MS) were used for characterising the chemical phases before and after carbonation. From the NMR results, it was found that C-S-H would be partly decalcified under the natural condition but completely under the accelerated conditions. Two equations related to the carbonation kinetics under natural and accelerated conditions were proposed respectively. The compositions in decalcified C-S-H were not affected by the CO2 concentration. The XRD analysis showed that vaterite, aragonite and calcite were coexistent after carbonation, which would be transformed to aragonite and calcite with further carbonation. The preferential formation of the allotropic calcium carbonate was not impacted by the concentration of CO2 either. Based on the TGA-MS test, the stoichiometric formula of synthetic C-S-H was determined with CaOâ'™SiO2â'™0.87H2O or Câ Sâ H0.87. In addition, a carbonation kinetics model was proposed to learn the carbonation kinetics of C-S-H carbonated in different CO2 concentrations. The experimental data fitted well with the model. The carbonation kinetics between 3% and 20% CO2 are similar, but different from that under 50% and 100% CO2
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| 33. |
- Li, Zhenlin, et al.
(author)
-
Research on the durability and Sustainability of an artificial lightweight aggregate concrete made from municipal solid waste incinerator bottom ash (MSWIBA)
- 2023
-
In: Construction and Building Materials. - : Elsevier BV. - 0950-0618. ; 365
-
Journal article (peer-reviewed)abstract
- This study chooses to use three common cementing materials, Portland cement (OPC), ground granulated blast furnace slag (GGBFS) and fly ash (FA), as the binder for the production of three artificial lightweight coarse aggregates (ALCAs) through cold bonding with municipal solid waste incineration bottom ash (MSWIBA) in which MSWIBA accounts for 70% of the total content by volume. In this study, three ALCAs were used to replace 0%, 30%, 60%, and 100% of natural aggregates used in the production of concrete. Through capillary water absorption and rapid migration of chloride ions, the effect of the replacement amount of ALCAs on the durability of concrete was explored. Additionally, in accordance with the Material Sustainability Index (MSI), a statistical analysis of the CO2 emissions, energy consumption and cost of the concrete made of the three ALCAs was carried out. Studies have shown that ALCAs can improve the Interfacial Transition Zone (ITZ) and pore structure of concrete, thereby improving the ability of concrete to resist chloride ion penetration. In addition, the use of ALCAs can reduce the cost of concrete. Among the ALCAs used in this study, those which use GGBFS and FA as adhesives (without OPC) can improve the durability of concrete the most and reduce CO2 emissions.
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| 34. |
- Lian, Ke-yan, et al.
(author)
-
Stable High-Energy Density Super-Atom Clusters of Aluminum Hydride
- 2012
-
In: Chinese Journal of Chemical Physics. - : AIP Publishing. - 1674-0068 .- 2327-2244. ; 25:2, s. 147-152
-
Journal article (peer-reviewed)abstract
- With the concept of super-atom, first principles calculations propose a new type of super stable cage clusters AlnH3n that are much more energetic stable than the well established clusters, AlnHn+2. In the new clusters, the aluminum core-frame acts as a super-atom with n vertexes and 2n Al-Al edges, which allow to adsorb n hydrogen atoms at the top-site and 2n at the bridge-site. Using Al12H36 as the basic unit, stable chain structures, (Al12H36)(m), have been constructed following the same connection mechanism as for (AlH3)(n) linear polymeric structures. Apart from high hydrogen percentage per molecule, calculations have shown that these new clusters possess large heat of formation values and their combustion heat is about 4.8 times of the methane, making them a promising high energy density material.
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| 35. |
- Liu, Jun, et al.
(author)
-
Alkali-activated binders based on incinerator bottom ash combined with limestone-calcined clay or fly ash
- 2022
-
In: Construction and Building Materials. - : Elsevier BV. - 0950-0618. ; 320
-
Journal article (peer-reviewed)abstract
- This study investigates the feasibility of improving the properties of alkali-activated bottom ash (AABA) binders by incorporating limestone-calcined clay (LC2) or fly ash (FA) with the aim of treating and utilising bottom ash in a large-scale as a potential resource for construction materials. Experimental results revealed that increasing the substitution with LC2 or FA in the AABA binders increased both the compressive strength and the immobilization capacity of heavy metal when compared to the pure AABA binders. Given a Na2O content of 5%, the compressive strength of the AABA binder with 30% bottom ash substituted by FA was almost 200% higher than that of the pure AABA binder. However, further increase in the Na2O dosage did not necessarily lead to higher compressive strength, which was found to be controlled by the volume fraction of air voids and large pores. When greater Na2O dosages were employed, i.e., 6 % and 7 %, LC2 was found to be more useful in improving the properties of AABA binders than FA. Furthermore, the substitution of bottom ash with FA resulted in the formation of N-A-S-H gels, whereas the substitution with LC2 led to the formation of more C-A-S-H gels. Finally, the immobilization capacity appeared to be influenced by many factors, such as hydration products, capillary pores and different types of heavy metals.
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| 36. |
- Liu, Jun, et al.
(author)
-
Exploring the carbon capture and sequestration performance of biochar-artificial aggregate using a new method
- 2023
-
In: Science of the Total Environment. - : Elsevier BV. - 0048-9697 .- 1879-1026. ; 859
-
Journal article (peer-reviewed)abstract
- To achieve the ambitious goal of carbon neutrality, more carbon sequestration channels need to be developed. In this study, we tried to combine biochar with cold-bonded artificial lightweight coarse aggregate (ALCA) which is made from municipal solid household waste incineration bottom ash (MSWIBA).The strong carbon capture ability of biochar was used to attract external CO2 into the interior of ALCAs, which combined with CaO in MSWIBA to form CaCO3 to achieve the effect of chemical carbon sequestration. The total carbon sequestration and carbon sequestration rate of biochar-ALCAs were quantified by a self-designed CO2 concentration change test box, the physical and mechanical properties of biochar-ALCAs were investigated, as well as the changes before and after carbonization. The results showed that biochar and ALCAs had good synergistic carbon sequestration ability. The total carbon sequestration of biochar-ALCAs could reach 30.58–33.06 kg/ton. The carbon sequestration efficiency could reach 70.2 % and 84.9 % at 28 d/56 d in a low CO2 concentration environment (0.05 % VOL). In addition, the water absorption of biochar-ALCAs decreased by 4.3 %–13.9 %, the apparent density increased by 0.9 %–2.8 %, and the strength increased by 4.3 %–7.0 % after carbon sequestration, and the physical and mechanical properties were significantly improved. The purpose of this paper is to investigate the synergistic carbon sequestration of biochar in combination with ALCAs and to quantitatively assess its ability to solidify low concentrations of CO2 in the natural environment. A new test apparatus and test method were designed for this purpose. This paper may contribute for an important advance on the preparation of recyclable cement-type composites able to capture and solidify CO2 from the natural environment.
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| 37. |
- Liu, Jun, et al.
(author)
-
Resource utilization of municipal solid waste incineration fly ash - cement and alkali-activated cementitious materials: A review
- 2022
-
In: Science of the Total Environment. - : Elsevier BV. - 0048-9697 .- 1879-1026. ; 852
-
Research review (peer-reviewed)abstract
- The increase in municipal solid waste (MSW) production has led to an increase in MSW incineration fly ash (MSWIFA) production. MSWIFA contains toxic and harmful substances such as heavy metals and dioxins, which can cause harm to the environment if not treated properly. Only a few MSWIFAs will be landfilled directly, and the rest will need to be treated by other methods. The treatment of MSWIFA can be divided into three types: separation, stabilization/solidification (S/S), and thermal treatment, which are either not fully developed or too costly. Resource utilization is a sustainable means of treating MSWIFA. MSWIFA is used in the production of cement and alkali-activated cementitious materials as a means of resource utilization with significant advantages. This can alleviate the consumption of nature and reduce greenhouse gas emissions in conventional cement production. Compared with MSWIFA cement, MSWIFA alkali-activated cementitious material can be achieved with almost no consumption of natural resources, which is worthy of further research to realize the large-scale application of MSWIFA. At the end of the paper, the perspective of separation of dioxins from MSWIFA, co-processing of MSWI ash, and production of “MSWIFA green materials” is presented.
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| 38. |
- Liu, Jun, et al.
(author)
-
Synthesis of geopolymer using municipal solid waste incineration fly ash and steel slag: Hydration properties and immobilization of heavy metals
- 2023
-
In: Journal of Environmental Management. - 0301-4797 .- 1095-8630. ; 341
-
Journal article (peer-reviewed)abstract
- In this study, a novel method for the disposal of municipal solid waste incineration fly ash (MSWIFA) was proposed. By applying geopolymer technology, steel slag (SS) and MSWIFA were used together as precursors to synthesize a cementitious material with sufficient strength that is useable in construction. The effects of the dosages of SS and alkaline activator on the properties of the geopolymer were investigated. Compressive testing was used to characterize the mechanical properties of the geopolymer. X-ray diffraction (XRD), thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) were used for microscopic analysis. Leaching tests were performed to assess the immobilization effect of the geopolymer on heavy metals. The results showed that the compressive strength of the geopolymer reached 23.03 MPa at 56 d with 20% SS and 11% Na2O admixture. Highly polymerized hydration products, such as C-(A)-S-H gels and N-A-S-H gels, contributed to the compact microstructure, which provided mechanical strength and limited the migration and leaching of heavy metals in the geopolymer matrix. In terms of the results, this work is significant for the development of MSWIFA management.
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| 39. |
- Liu, Jun, et al.
(author)
-
Valorization of municipal solid waste incineration bottom ash (MSWIBA) into cold-bonded aggregates (CBAs): Feasibility and influence of curing methods
- 2022
-
In: Science of the Total Environment. - : Elsevier BV. - 0048-9697 .- 1879-1026. ; 843
-
Journal article (peer-reviewed)abstract
- The municipal solid waste incineration bottom ash (MSWIBA) contains amounts of hazardous elements or composition, and its disposal to landfills may pose a serious threat to the ground water and soil. To reduce the environmental impact of MSWIBA, a novelty application into the utilization of MSWIBA for the manufacture of cold-bonded aggregates (CBAs) was investigated in this study. This study explored the impacts of curing systems on the comprehensive properties of CBAs. Furthermore, the hydrating phases of the designed CBAs were studied by X-ray diffractometer, and the micro characteristics of CBAs was analyzed by Scanning Electron Microscopy. The results show that CBAs produced from the MSWIBA had good properties with density of 1.75–1.98 g/cm3, moisture content of 0.78–16.48 %, water absorption of 3.99–14.02 % and compressive behavior of 1.6–4.8 MPa. Moreover, the heating water curing environment can significantly improve the comprehensive properties of CBAs. Specifically, the compressive strength of the CBAs under the 80 °C curing condition was increased by 74 %–113 %, and the water absorption rate was reduced by 3.4 %–8 %, compared with other curing regimes. Additionally, the XRD analysis showed that there are spinel phases in the CBAs compounds, which is beneficial to solidify the hazardous metals. Also, low-carbon CBAs also greatly reduce the amount of Cu and Pb leaching, which meets the limit requirements in the Chinese standards. Overall, application of MSWIBA as admixture in CBAs is an effective approach to recycle waste and replace natural aggregates. Meanwhile, this work can provide an insight for the production of eco-friendly LWAs.
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| 40. |
- Liu, Tao, et al.
(author)
-
16% efficiency all-polymer organic solar cells enabled by a finely tuned morphology via the design of ternary blend
- 2021
-
In: Joule. - : CELL PRESS. - 2542-4351. ; 5:4, s. 914-930
-
Journal article (peer-reviewed)abstract
- A SUMMARY There is an urgent demand for all-polymer organic solar cells (AP-OSCs) to gain higher efficiency. Here, we successfully improve the performance to 16.09% by introducing a small amount of BN-T, a B <- N-type polymer acceptor, into the PM6:PY-IT blend. It has been found that BN-T makes the active layer, based on the PM6:PY-IT:BN-T ternary blend, more crystalline but meanwhile slightly reduces the phase separation, leading to enhancement of both exciton harvesting and charge transport. From a thermodynamic viewpoint, BN-T prefers to reside between PM6 and PY-IT, and the fraction of this fine-tunes the morphology. Besides, a significantly reduced nonradiative energy loss occurs in the ternary blend, along with the coexistence of energy and charge transfer between the two acceptors. The progressive performance facilitated by these improved properties demonstrates that AP-OSCs can possibly comparably efficient with those based on small molecule acceptors, further enhancing the competitiveness of this device type.
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| 41. |
- Liu, W., et al.
(author)
-
Changes in chemical phases and microscopic characteristics of fly ash blended cement pastes in different CO 2 concentrations
- 2020
-
In: Construction and Building Materials. - : Elsevier BV. - 0950-0618. ; 257
-
Journal article (peer-reviewed)abstract
- The effects of CO2 concentration on changes in chemical phases and microscopic characteristics for fly ash (FA) blended cement pastes were investigated in this study. Several microscopic test methods, including X-ray diffraction (XRD), thermo-gravimetric analysis (TGA), 29Si nuclear magnetic resonance (29Si NMR) and scanning electron microscope (SEM), were used to characterize the chemical compositions and microscopic features. The XRD results showed that the precipitation of allotropic calcium carbonate (CC̅) includes calcite (c), aragonite (a) and vaterite (v). The ratio of c/(a + v) was around 0.6 under 3% and 20% CO2, while more percentage of calcite was generated under 100% CO2 (c/(a + v) = 0.79). The precipitation of more calcite than vaterite and aragonite happened with the CO2 concentration elevated to 100%. TGA analysis indicated that the total content of CC̅ was similar under all accelerated conditions and higher than that under natural carbonation. Additionally, in the 29Si NMR spectra, more C-S-H (about 70%) was decalcified after accelerated carbonation compared with natural carbonation (54.1%). The decalcification degree was the same for 3% and 20% CO2 and showed the highest value under 100% CO2. The microstructure changes characterized by SEM observation exhibited denser microstructure after carbonation with the formation of CC̅ but no apparent difference was observed with different CO2 concentrations based on the SEM pictures. Compared with the carbonation of ordinary Portland cement (OPC) paste, the carbonation of FA blended cement paste was more inclined to precipitate as calcite than vaterite and aragonite and caused a lower decalcification degree of C-S-H. Overall, similar to OPC paste, the carbonation results obtained in natural and accelerated conditions for FA blended cement pastes were different and the conditions between 3% and 20% CO2 were similar while 100% CO2 showed different results.
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| 42. |
- Liu, Yihong, et al.
(author)
-
Fracture and interfacial delamination origins of bilayer ceramic composites for dental restorations
- 2010
-
In: Journal of the European Ceramic Society. - : Elsevier BV. - 0955-2219 .- 1873-619X. ; 30:6, s. 1297-1305
-
Journal article (peer-reviewed)abstract
- Alumina and zirconia (Y-TZP) based bilayer ceramic dental composites with core to veneer thickness ratio (R-value) of 1: 1 and 2:1 were fabricated through an established dental laboratory multi-steps-firing procedure. Their flexural strengths were determined by three-point bending test. A combinational approach of numerical simulations by finite element analysis associated with direct fractography investigation was applied to elucidate the origins of fracture and interfacial delamination and the influence of physical properties mismatch between core ceramic and veneer porcelain. A newly developed argon ion beam cross-section polishing technique was used to conduct fine polishing required for close investigating of the core-veneer interface under scanning electron microscope. For the same core ceramic no significant difference was observed in determined flexural strength of two groups of bilayer composites. The flexural strength of the bilayer composites is similar to 55% and similar to 35% of the core ceramics and achieved similar to 90% and 70-77% of the predicated value respectively in case of Y-TZP and alumina based composites. Numerical simulations by finite element analysis indicate that the often observed interfacial delamination in Y-TZP based bilayer composites has a clear origin of the severe physical properties mismatch between veneer porcelain and core ceramics, particularly the flexural strength, which may be prevented by increasing the flexural strength of veneer porcelain to above 300 MPa. The observation of the formation of microcracks in alumina core immediately one grain-thick under the veneer-core interface warns the possible thermal damages initiated during the veneering operation.
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| 43. |
- Liu, Y. H., et al.
(author)
-
Bilayered ceramic dental composites with adhesive or reactive bonded interfaces
- 2013
-
In: Advances in Applied Ceramics. - 1743-6753 .- 1743-6761. ; 112:4, s. 227-234
-
Journal article (peer-reviewed)abstract
- By close inspection of the well polished cross-sections, two categories of interfaces were classified, namely, adhesive bonding between veneering porcelains and zirconia or alumina cores versus reactive bonding between veneering porcelains and cores of glass infiltrated alumina or lithium disilicate based glass ceramics. Argon ion beam cross-section polishing technique was applied to achieve gentle and fine polishing required for high resolution interfacial characterisation by scanning electron microscopy. The observations suggest that it is desirable to enhance the interfacial reactive bonding in order to avoid delamination in alumina and zirconia based composites.
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| 44. |
- Lu, Yang, et al.
(author)
-
Precise tuning of interlayer electronic coupling in layered conductive metal-organic frameworks
- 2022
-
In: Nature Communications. - : Nature Portfolio. - 2041-1723. ; 13:1
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Journal article (peer-reviewed)abstract
- Layered metal-organic frameworks attract interests for optoelectronics and spintronics. Here, the authors report a strategy to tune interlayer charge transport and thermoelectric properties via side-chain induced control of the layer spacing. Two-dimensional conjugated metal-organic frameworks (2D c-MOFs) have attracted increasing interests for (opto)-electronics and spintronics. They generally consist of van der Waals stacked layers and exhibit layer-depended electronic properties. While considerable efforts have been made to regulate the charge transport within a layer, precise control of electronic coupling between layers has not yet been achieved. Herein, we report a strategy to precisely tune interlayer charge transport in 2D c-MOFs via side-chain induced control of the layer spacing. We design hexaiminotriindole ligands allowing programmed functionalization with tailored alkyl chains (HATI_CX, X = 1,3,4; X refers to the carbon numbers of the alkyl chains) for the synthesis of semiconducting Ni-3(HATI_CX)(2). The layer spacing of these MOFs can be precisely varied from 3.40 to 3.70 angstrom, leading to widened band gap, suppressed carrier mobilities, and significant improvement of the Seebeck coefficient. With this demonstration, we further achieve a record-high thermoelectric power factor of 68 +/- 3 nW m(-1) K-2 in Ni-3(HATI_C3)(2), superior to the reported holes-dominated MOFs.
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| 45. |
- Luo, Xuhao, et al.
(author)
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Intrinsic polarization-sensitive organic photodetector with self-assembled all-polymer heterojunction
- 2022
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In: Applied Physics Letters. - : AIP Publishing. - 0003-6951 .- 1077-3118. ; 121:23
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Journal article (peer-reviewed)abstract
- Intrinsic polarization-sensitive photodetectors (IPPDs) have attracted considerable attention in recent years due to their simplicity in configuration, making them ideal candidates for compact and integrated polarization-sensitive sensing and imaging systems. Photoactive films with intrinsic optical anisotropy are necessary for IPPDs. This study reports an achievement of photoactive films based on all-polymer heterojunction films with in-plane optical anisotropy using a simple bottom-up self-assembly method. Both the donor (TQ1) and acceptor (N2200) polymers have the same spatial orientation with distinct anisotropy, approaching a dichroic ratio (DR) of 8. Polarization-sensitive light absorption is due to the uniaxially oriented polymer chains, which are dominated by lamellar packing with edge-on orientation. For IPPDs based on this anisotropic all-polymer heterojunction film, a photocurrent anisotropy was found with a polarized photocurrent ratio of 2.6. The detectivity of these IPPDs was found to be 1.9 × 1011 Jones (@ ∼600 nm, 0 V bias). Our work shows that oriented polymer donor-acceptor films fabricated using bottom-up self-assembly have great potential in applications, such as polarization detection.
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| 46. |
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| 47. |
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| 48. |
- Morii, Kaho, et al.
(author)
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The ALMA Survey of 70 mu m Dark High-mass Clumps in Early Stages (ASHES). IV. Star Formation Signatures in G023.477
- 2021
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In: Astrophysical Journal. - : American Astronomical Society. - 1538-4357 .- 0004-637X. ; 923:2
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Journal article (peer-reviewed)abstract
- With a mass of similar to 1000 M (circle dot) and a surface density of similar to 0.5 g cm(-2), G023.477+0.114, also known as IRDC 18310-4, is an infrared dark cloud (IRDC) that has the potential to form high-mass stars and has been recognized as a promising prestellar clump candidate. To characterize the early stages of high-mass star formation, we have observed G023.477+0.114 as part of the Atacama Large Millimeter/submillimeter Array (ALMA) Survey of 70 mu m Dark High-mass Clumps in Early Stages. We have conducted similar to 1.'' 2 resolution observations with ALMA at 1.3 mm in dust continuum and molecular line emission. We have identified 11 cores, whose masses range from 1.1 to 19.0 M (circle dot). Ignoring magnetic fields, the virial parameters of the cores are below unity, implying that the cores are gravitationally bound. However, when magnetic fields are included, the prestellar cores are close to virial equilibrium, while the protostellar cores remain sub-virialized. Star formation activity has already started in this clump. Four collimated outflows are detected in CO and SiO. H2CO and CH3OH emission coincide with the high-velocity components seen in the CO and SiO emission. The outflows are randomly oriented for the natal filament and the magnetic field. The position-velocity diagrams suggest that episodic mass ejection has already begun even in this very early phase of protostellar formation. The masses of the identified cores are comparable to the expected maximum stellar mass that this IRDC could form (8-19 M (circle dot)). We explore two possibilities on how IRDC G023.477+0.114 could eventually form high-mass stars in the context of theoretical scenarios.
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| 49. |
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| 50. |
- Phukhamsakda, Chayanard, et al.
(author)
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The numbers of fungi: contributions from traditional taxonomic studies and challenges of metabarcoding
- 2022
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In: Fungal diversity. - : Springer Science and Business Media LLC. - 1560-2745 .- 1878-9129. ; 114:1, s. 327-386
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Journal article (peer-reviewed)abstract
- The global diversity of fungi has been estimated using several different approaches. There is somewhere between 2–11 million estimated species, but the number of formally described taxa is around 150,000, a tiny fraction of the total. In this paper, we examine 12 ascomycete genera as case studies to establish trends in fungal species descriptions, and introduce new species in each genus. To highlight the importance of traditional morpho-molecular methods in publishing new species, we introduce novel taxa in 12 genera that are considered to have low species discovery. We discuss whether the species are likely to be rare or due to a lack of extensive sampling and classification. The genera are Apiospora, Bambusicola, Beltrania, Capronia, Distoseptispora, Endocalyx, Neocatenulostroma, Neodeightonia, Paraconiothyrium, Peroneutypa, Phaeoacremonium and Vanakripa. We discuss host-specificity in selected genera and compare the number of species epithets in each genus with the number of ITS (barcode) sequences deposited in GenBank and UNITE. We furthermore discuss the relationship between the divergence times of these genera with those of their hosts. We hypothesize whether there might be more species in these genera and discuss hosts and habitats that should be investigated for novel species discovery.
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