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Search: WFRF:(Elek Zoltan) > (2023)

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  • Chowdhury, Rajdip, 1993-, et al. (author)
  • Modular Synthesis of (Borylmethyl)silanes through Orthogonal Functionalization of a Carbon Atom
  • 2023
  • In: Organic Letters. - : American Chemical Society (ACS). - 1523-7060 .- 1523-7052. ; 25:11, s. 1935-1940
  • Journal article (peer-reviewed)abstract
    • (Borylmethyl)trimethylsilanes are important building blocks in organic synthesis displaying a unique reactivity. Yet, the synthesis of more advanced derivatives is limited by the advanced silicon intermediates required for their preparation. Herein, a one-pot synthesis of (borylmethyl)silanes is developed, sourced on available alkyl-, aryl-, alkoxy-, aryloxy-, and silyl-hydrosilane materials. The privileged reactivity of N-hydroxyphthalimidyl diazoacetate (NHPI-DA) in Si–H insertion and α-silyl redox-active esters in different decarboxylative borylation reactions are scrutinized.
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Type of publication
journal article (1)
Type of content
peer-reviewed (1)
Author/Editor
Mendoza, Abraham (1)
Chowdhury, Rajdip, 1 ... (1)
Elek, Gábor Zoltán (1)
Meana-Baamonde, Beat ... (1)
University
Stockholm University (1)
Language
English (1)
Research subject (UKÄ/SCB)
Natural sciences (1)
Year
2023 (1)Undo refine

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