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  • Tian, Yupeng, et al. (author)
  • Two novel two-photon polymerization initiators with extensive application prospects
  • 2004
  • In: Chemical Physics Letters. - : Elsevier. - 0009-2614 .- 1873-4448. ; 388:4-6, s. 325-329
  • Journal article (peer-reviewed)abstract
    • Two novel two-photon polymerization initiators, 10-ethyl-3-E-(4-(N,N′-di-n-butylamino)styryl)phenothiazine 5 and 10-ethyl-3,7-E,E-bis(4-(N,N′-di-n-butyl amino)styryl)phenothiazine 6, have been efficiently synthesized with room temperature solid phase Wittig reaction. Two initiators were found to exhibit good single-photon fluorescence emission and their quantum yields, lifetimes and solvent effects have been studied in detail. Two-photon fluorescence spectra were investigated under 800 nm fs laser pulse and two-photon absorption (TPA) cross-sections of the initiators have been evaluated by theoretical calculation.Two-photon initiating polymerization microfabrication experiments have been carried out and artificial defects were made and polymerization mechanism was also discussed.
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