1. |
- Chubarova, Elena V., et al.
(author)
-
Self-assembly of a heteropolyoxopalladate nanocube : [PdII 13AsV 8O34(OH)6] 8-
- 2008
-
In: Angewandte Chemie International Edition. - : Wiley. - 1433-7851 .- 1521-3773. ; 47:49, s. 9542-9546
-
Journal article (peer-reviewed)abstract
- (Chemical Equation Presented) Not like the others: A molecular palladium oxide cluster was formed by self-assembly of palladium(II) and arsenic(V) using mild reaction conditions. The resulting heteropolypalladate [Pd II 13AsV 8O34(OH) 6]8- has a distorted cubic shape and edge lengths of about 1 nm. The thirteen PdII ions retain four-coordinate square-planar geometry, in marked contrast to all other known discrete polyoxometalates.
|
|