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  • Cherkasov, A. R., et al. (author)
  • Correlation analysis in the chemistry of free radicals
  • 2001
  • In: Uspehi himii. - 0042-1308 .- 1817-5651. ; 70:1, s. 3-27
  • Research review (peer-reviewed)abstract
    • Published data available by now on the use of correlation analysis in the free-radical chemistry are discussed systematically. The scales of <> sigma -constants of substituents proposed previously are analysed. It is shown that none of them is suitable as a general scale because almost in all cases, it is impossible to separate correctly the proper radical and polar contributions to the overall effect of substituents. A new approach to the quantitative estimation of the relationship between the structure and reactivity of molecules in free-radical processes is proposed and called r(-2)-analysis.
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Type of publication
research review (1)
Type of content
peer-reviewed (1)
Author/Editor
Jonsson, Mats (1)
Cherkasov, A. R. (1)
Galkin, V. I. (1)
Cherkasov, R. A. (1)
University
Royal Institute of Technology (1)
Language
Russian (1)
Year
2001 (1)

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