SwePub
Sök i SwePub databas

  Extended search

Träfflista för sökning "id:"swepub:oai:DiVA.org:kth-21279" "

Search: id:"swepub:oai:DiVA.org:kth-21279"

  • Result 1-1 of 1
Sort/group result
   
EnumerationReferenceCoverFind
1.
  • Belyaev, A. N., et al. (author)
  • Redox properties of rhodium(III) oxo-bridged carboxylate complexes
  • 2001
  • In: Russian journal of general chemistry. - 1070-3632 .- 1608-3350. ; 71:8, s. 1186-1193
  • Journal article (peer-reviewed)abstract
    • Chemical and electrochemical oxidation of rhodium (III) oxo-bridged carboxylate complexes was studied. The chemical [with O-3 and Ce(IV) salts] or electrochemical (at potentials of 1.00-1.20 V) oxidations of the binuclear complexes [Rh-2(mu-O)(mu-O2CCH3)(2)(H2O)(6)](2+) and [Rh-2(mu-O)(mu-O2CCF3)(2)(H2O)(6)](2+) leads to the superoxo complexes [Rh-2(mu-O)(O-2(-))(mu-O2CCH3)(2)(H2O)(5)]+ and [Rh-2(mu-O)(O-2(-))(mu-O2CCF3)(2)(H2O)(5)](+) with terminal coordination of O-2(-). The trinuclcar acetate [Rh-3(mu(3)-O)(mu-O2CCH3)(6)(H2O)(3)](+), unlike its trifluoroacetate analog [Rh-3(mu(3)-O)(mu-O2CCF3)(6)(H2O)(3)](+), is oxidized only electrochemically at a potential of 1.38 V. The oxidation of [Rh-3(mu(3)-O)(mu-O2CCH3)(6)(H2O)(3)](+) is reversible and involves formation of an unstable superoxo group O-2(-) between two Rh-3(III)(mu(3)-O) cores.
  •  
Skapa referenser, mejla, bekava och länka
  • Result 1-1 of 1
Type of publication
journal article (1)
Type of content
peer-reviewed (1)
Author/Editor
Belyaev, A. N. (1)
Simanova, S. A. (1)
Gorlov, Mikhail (1)
Bashmakov, V. I. (1)
Panina, N. S. (1)
Vyatkin, V. E. (1)
University
Royal Institute of Technology (1)
Language
English (1)
Year
2001 (1)

Kungliga biblioteket hanterar dina personuppgifter i enlighet med EU:s dataskyddsförordning (2018), GDPR. Läs mer om hur det funkar här.
Så här hanterar KB dina uppgifter vid användning av denna tjänst.

 
pil uppåt Close

Copy and save the link in order to return to this view