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  • Korzhavyi, Pavel A., 1966-, et al. (author)
  • Exploring monovalent copper compounds with oxygen and hydrogen
  • 2012
  • In: Proceedings of the National Academy of Sciences of the United States of America. - : National Academy of Sciences. - 0027-8424 .- 1091-6490. ; 109:3, s. 686-689
  • Journal article (peer-reviewed)abstract
    • New important applications of copper metal, e.g., in the areas of hydrogen production, fuel cell operation, and spent nuclear fuel disposal, require accurate knowledge of the physical and chemical properties of stable and metastable copper compounds. Among the copper(I) compounds with oxygen and hydrogen, cuprous oxide Cu(2)O is the only one stable and the best studied. Other such compounds are less known (CuH) or totally unknown (CuOH) due to their instability relative to the oxide. Here we combine quantum-mechanical calculations with experimental studies to search for possible compounds of monovalent copper. Cuprous hydride (CuH) and cuprous hydroxide (CuOH) are proved to exist in solid form. We establish the chemical and physical properties of these compounds, thereby filling the existing gaps in our understanding of hydrogen- and oxygen-related phenomena in Cu metal.
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Type of publication
journal article (1)
Type of content
peer-reviewed (1)
Author/Editor
Johansson, Börje (1)
Isaev, Eyvas (1)
Korzhavyi, Pavel A., ... (1)
Soroka, Inna L. (1)
Lilja, Christina (1)
University
Royal Institute of Technology (1)
Uppsala University (1)
Linköping University (1)
Language
English (1)
Research subject (UKÄ/SCB)
Natural sciences (1)
Engineering and Technology (1)
Year
2012 (1)

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