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- Engström, V., et al.
(author)
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The effect of seed size on the growth of silicalite-1 films on gold surfaces
- 2000
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In: Microporous and Mesoporous Materials. - 1387-1811 .- 1873-3093. ; 38:1, s. 51-60
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Journal article (peer-reviewed)abstract
- Silicalite-1 films grown on gold surfaces seeded with colloidal crystals with a size of 60, 165 and 320 nm were investigated by reflection–absorption infrared spectroscopy, scanning electron microscopy and X-ray diffraction in order to follow up the formation of nano-scale defects and to determine the optimal synthesis conditions for preparation of silicalite-1 films with a low concentration of defects. Using 60-nm-sized colloidal crystals, the seeding method was capable of producing silicalite-1 films with low concentrations of defects and with thicknesses ranging from 100 to 300 nm, which are predominantly oriented with the a-axis perpendicular to the surface. Hydrothermal treatment times of the 60-nm-seeded surfaces longer than 36 h as well as the seeding with 165 or 320 nm colloidal crystals substantially enhanced the formation of defects in the films.
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