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  • Arkhypchuk, Anna I., et al. (author)
  • Cascade Reactions Forming Highly Substituted, Conjugated Phospholes and 1,2-Oxaphospholes
  • 2012
  • In: Angewandte Chemie International Edition. - : Wiley. - 1433-7851 .- 1521-3773. ; 51:31, s. 7776-7780
  • Journal article (peer-reviewed)abstract
    • The reaction of a phospha-Wittig–Horner reagent with diacetylenic ketones (see scheme) results in a cascade of reactions that can lead to both an oxaphosphole-terminated cumulene system and an alkene-bridged bis-phosphole. The reaction outcome is determined by the nature of the acetylene termini, with phenyl groups stabilizing a carbene intermediate that dimerizes to give the bis-phosphole product.
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Type of publication
journal article (1)
Type of content
peer-reviewed (1)
Author/Editor
Ott, Sascha (1)
Arkhypchuk, Anna I. (1)
Santoni, Marie-Pierr ... (1)
University
Uppsala University (1)
Language
English (1)
Research subject (UKÄ/SCB)
Natural sciences (1)
Year
2012 (1)

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