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  • Stödeman, Magnus, et al. (author)
  • Thermodynamics of binding of alpha-cyclodextrin to straight-chain alkyl derivatives in aqueous solution
  • 2003
  • In: Journal of Inclusion Phenomena and Molecular Recognition in Chemistry. - 0923-0750. ; 46:3-4, s. 125-132
  • Journal article (peer-reviewed)abstract
    • Apparent standard Gibbs energy, enthalpy, entropy, and heat capacity data of the interactions of alpha-cyclodextrin (alphaCD) to some n-carboxylates H(CH2)(n)COO- (n = 4 - 6), are determined by isothermal titration microcalorimetry at different temperatures in phosphate buffer, pH 9.0, assuming a 1 : 1 model in dilute solution. Modelling of contributions of the thermodynamic properties of the solution indicates that aCD undergoes conformational change upon binding to homologous series of n-carboxylates, n-alcohols, alpha,omega-alkane dicarboxylates and alpha,omega-alkane diols.
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Type of publication
journal article (1)
Type of content
peer-reviewed (1)
Author/Editor
Hallen, D (1)
Stödeman, Magnus (1)
Gomez-Orellana, I (1)
University
Lund University (1)
Language
English (1)
Research subject (UKÄ/SCB)
Natural sciences (1)
Year
2003 (1)

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