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  • Zweidinger, S., et al. (author)
  • Reaction mechanism of the oxidation of HCl over RuO2(110)
  • 2008
  • In: Journal of Physical Chemistry C. - : American Chemical Society (ACS). - 1932-7447 .- 1932-7455. ; 112:27, s. 9966-9969
  • Journal article (peer-reviewed)abstract
    • High-resolution core-level shift spectroscopy and temperature-programmed reaction experiments together with density functional theory calculations reveal that the oxidation of HCl with oxygen producing Cl-2 and water proceeds on the chlorine-stabilized RuO2(110)surface via a one-dimensional Langmuir-Hinshelwood mechanism. The recombination of two adjacent chlorine atoms on the catalyst's surface constitutes the rate-determining step in this novel Deacon-like process.
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Type of publication
journal article (1)
Type of content
peer-reviewed (1)
Author/Editor
Lundgren, Edvin (1)
Andersen, Jesper N (1)
Crihan, D (1)
Knapp, M (1)
Over, H (1)
Seitsonen, A P (1)
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Hofmann, J. P. (1)
Weststrate, C. J. (1)
Zweidinger, S. (1)
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University
Lund University (1)
Language
English (1)
Research subject (UKÄ/SCB)
Natural sciences (1)
Year
2008 (1)

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