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  • Olsson, Roger, et al. (author)
  • Is a hydrogen bonded carbene an intermediate in the organoaluminum-induced ring opening of pyranosides?
  • 1997
  • In: Tetrahedron Letters. - 0040-4039. ; 38:32, s. 5701-5704
  • Journal article (peer-reviewed)abstract
    • Semiempirical and ab initio quantum chemical computations indicate that the intermediate formed prior to the selectivity-determining methyl transfer step in the reaction between glycosides and trimethylaluminum is a strongly hydrogen-bended equilibrium OH...C = O-H...C, which is proposed to be an important selectivity promoting factor in the alkyl transfer reaction.
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Type of publication
journal article (1)
Type of content
peer-reviewed (1)
Author/Editor
Olsson, Roger (1)
Frejd, Torbjörn (1)
Berg, Ulf (1)
University
Lund University (1)
Language
English (1)
Year
1997 (1)

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