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  • Dunås, Petter, 1990, et al. (author)
  • Selective Iron-Mediated C- and O-Addition of Phenolic Nucleophiles to a Cyclohexadiene Scaffold Using Renewable Precursors
  • 2019
  • In: ACS Sustainable Chemistry & Engineering. - : American Chemical Society (ACS). - 2168-0485. ; 7:7, s. 7155-7162
  • Journal article (peer-reviewed)abstract
    • Renewable phenols have been investigated as nucleophiles for the addition to a cationic cyclohexadienyl iron carbonyl scaffold. Benign conditions compatible with solvents such as ethanol and water were developed, and for the first time, selective C- or O-addition could be achieved. In addition, a novel atom-economic approach to forming the C-addition products directly from the neutral precursor complex in a single step using a catalytic acid is described. The formed C-addition product could then be selectively demetalated to form one of two different product classes, a functionalized arene or a cyclohexadiene.
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Type of publication
journal article (1)
Type of content
peer-reviewed (1)
Author/Editor
Lewis, Simon E. (1)
Kann, Nina, 1964 (1)
Dunås, Petter, 1990 (1)
Paterson, Andrew, 19 ... (1)
Kociok-Köhn, G. (1)
University
Chalmers University of Technology (1)
Language
English (1)
Research subject (UKÄ/SCB)
Natural sciences (1)
Engineering and Technology (1)
Year
2019 (1)

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