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  • Merritt, Eleanor A., et al. (author)
  • Facile synthesis of Koser's reagent and derivatives from iodine or aryl iodides
  • 2010
  • In: Journal of Organic Chemistry. - : American Chemical Society (ACS). - 0022-3263 .- 1520-6904. ; 75:21, s. 7416-7419
  • Journal article (peer-reviewed)abstract
    • The first one-pot synthesis of neutral and electron-rich [hydroxy(tosyloxy)iodo]arenes (HTIBs) from iodine and arenes is presented, thereby avoiding the need for expensive iodine(III) precursors. A large set of HTIBs, including a polyfluorinated analogue, can be obtained from the corresponding aryl iodide under the same conditions. The reaction proceeds under mild conditions, without excess reagents, and is fast and high-yielding. Together, the two presented routes give access to a wide range of HTIBs, which are useful reagents in a variety of synthetic transformations.
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Type of publication
journal article (1)
Type of content
peer-reviewed (1)
Author/Editor
Olofsson, Berit (1)
Silva Jr., Luiz F. (1)
Merritt, Eleanor A. (1)
Carneiro, Vania M.T. (1)
University
Stockholm University (1)
Language
English (1)
Research subject (UKÄ/SCB)
Natural sciences (1)
Year
2010 (1)

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