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  • Botes, AL, et al. (author)
  • Screening of yeast species for the stereo-selective reduction of bicyclo[2.2.2]octane-2,6-dione
  • 2002
  • In: Journal of the Chemical Society - Perkin Transactions 1. - : Royal Society of Chemistry (RSC). - 1472-7781 .- 1364-5463. ; :8, s. 1111-1114
  • Journal article (peer-reviewed)abstract
    • Yeast strains from more than 31 different genera were screened for the enantioselective reduction of bicyclo[2.2.2]-octane-2,6-dione (1). Reducing activity was found in 80% of the screened yeasts. Bicyclo[2.2.2]octane-2,6-dione was enantioselectively reduced (> 98% ee) to (1R, 4S, 6S)-6-hydroxybicyclo[2.2.2]octane-2-one (-)-2 by 69% of the strains. Enantioselective reduction of the diketone to (1S, 4R, 6S)-6-hydroxybicyclo[2.2.2]octane-2-one ((+)-3, >98% ee) as a major product is reported for the first time. Candida tropicalis UOFS Y-0534 and Candida wickerhamii UOFS Y-0652 displayed this unusual diastereoselectivity.
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Type of publication
journal article (1)
Type of content
peer-reviewed (1)
Author/Editor
Gorwa-Grauslund, Mar ... (1)
Frejd, Torbjörn (1)
Katz, M (1)
Botes, AL (1)
Harvig, D (1)
van Dyk, MS (1)
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Sarvary, Ian (1)
Hahn-Hagerdal, B (1)
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University
Lund University (1)
Language
English (1)
Research subject (UKÄ/SCB)
Natural sciences (1)
Engineering and Technology (1)
Year
2002 (1)

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