| 1. |
- Andersson, August, et al.
(author)
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(14)C-Based source assessment of soot aerosols in Stockholm and the Swedish EMEP-Aspvreten regional background site
- 2011
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In: Atmospheric Environment. - : Elsevier BV. - 1352-2310 .- 1873-2844. ; 45:1, s. 215-222
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Journal article (peer-reviewed)abstract
- Combustion-derived soot or black carbon (BC) in the atmosphere has a strong influence on both climate and human health. In order to propose effective mitigation strategies for BC emissions it is of importance to investigate geographical distributions and seasonal variations of BC emission sources. Here, a radiocarbon methodology is used to distinguish between fossil fuel and biomass burning sources of soot carbon (SC). SC is isolated for subsequent off-line (14)C quantification with the chemothermal oxidation method at 375 degrees C (CTO-375 method), which reflects a recalcitrant portion of the BC continuum known to minimize inadvertent inclusion of any non-pyrogenic organic matter. Monitored wind directions largely excluded impact from the Stockholm metropolitan region at the EMEP-Aspvreten rural station 70 km to the south-west. Nevertheless, the Stockholm city and the rural stations yielded similar relative source contributions with fraction biomass (f(biomass)) for fall and winter periods in the range of one-third to half. Large temporal variations in (14)C-based source apportionment was noted for both the 6 week fall and the 4 month winter observations. The f(biomass) appeared to be related to the SC concentration suggesting that periods of elevated BC levels may be caused by increased wood fuel combustion. These results for the largest metropolitan area in Scandinavia combine with other recent (14)C-based studies of combustion-derived aerosol fractions to suggest that biofuel combustion is contributing a large portion of the BC load to the northern European atmosphere.
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| 2. |
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| 3. |
- Mills, Gina, 1959, et al.
(author)
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New stomatal flux-based critical levels for ozone effects on vegetation
- 2011
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In: Atmospheric Environment. - : Elsevier BV. - 1873-2844 .- 1352-2310. ; 45:28, s. 5064-5068
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Journal article (peer-reviewed)abstract
- The critical levels for ozone effects on vegetation have been reviewed and revised by the LRTAP Convention. Eight new or revised critical levels based on the accumulated stomatal flux of ozone (POD gamma, the Phytotoxic Ozone Dose above a threshold flux of Y nmol m(-2) PLA s(-1), where PLA is the projected leaf area) have been agreed. For each receptor, data were combined from experiments conducted under naturally fluctuating environmental conditions in 2-4 countries, resulting in linear dose response relationships with response variables specific to each receptor (r(2) = 0.49-0.87, p
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| 4. |
- Sheesley, Rebecca J., et al.
(author)
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Source characterization of organic aerosols using Monte Carlo source apportionment of PAHs at two South Asian receptor sites
- 2011
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In: Atmospheric Environment. - : Elsevier BV. - 1352-2310 .- 1873-2844. ; 45:23, s. 3874-3881
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Journal article (peer-reviewed)abstract
- The quantification of source contributions is of key importance for proposing environmental mitigation strategies for particulate organic matter. Organic molecular tracer analysis of polycyclic aromatic hydrocarbons (PAHs) and n-alkanes was conducted on a set of winter samples from two regional receptor sites in South Asia: the Island of Hanimaadhoo (the Republic of Maldives) and a mountain top near Sinhagad (W. India). Monte Carlo source apportionment (MCSA) techniques were applied to the observed PAH ratios using profiles of a representative range of regional combustion sources from the literature to estimate the relative source contributions from petroleum combustion, coal combustion and biomass burning. One advantage of this methodology is the combined use of the mean and standard deviation of the diagnostic ratios to calculate probability distribution functions for the fractional contributions from petroleum, coal and biomass combustion. The results of this strategy indicate a higher input from coal combustion at the Hanimaadhoo site (32-43 +/- 21%) than the Sinhagad site (24-25 +/- 18%). The estimated biomass contribution for Sinhagad (53 +/- 22%) parallels previous radiocarbon-based source apportionment of elemental carbon at this location (54 +/- 3%). In Hanimaadhoo, the MCSA results indicate 34 +/- 20% biomass burning contribution compared to 41 +/- 5% by radiocarbon apportionment of EC. While the MCSA based on PAH ratio diagnostic distributions are less precise than the radiocarbon-based apportionment, it provides additional information of the relative contribution of two subgroups, coal and petroleum combustion, within the overall contribution from fossil fuel combustion.
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| 5. |
- Vogt, Matthias, et al.
(author)
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Traffic Aerosol emission velocity derived from direct flux measurements over urban Stockholm, Sweden
- 2011
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In: Atmospheric Environment. - : Elsevier BV. - 1352-2310 .- 1873-2844. ; 45:32, s. 5725-5731
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Journal article (peer-reviewed)abstract
- Size-resolved aerosol vertical number fluxes were measured using the eddy covariance method, 105 meters above the ground over the city of Stockholm, Sweden, between 1st April 2008 and 15th April 2009. The size range of the measurements cover particles from 0.25 to 2.5 μm diameter (Dp). Emission velocities (ve) were calculated for the same size range and were found to be well correlated with friction velocity (u*) and CO2 fluxes (FCO2). These variables were used to parameterize the emission velocity aswhere ve and u* are given in [m s−1], Dp in [μm], and FCO2 in [mmol m−2s−1]. The parameterization reproduces the average diurnal cycle from the observations well for particles sizes up to 0.6 μm Dp. For larger particles the parameterization tends to over predict the emission velocity. These larger particles are not believed to be produced by combustion and therefore not well represented by FCO2, which represents the traffic source through its fossil fuel consumption and the related CO2 emissions.
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| 6. |
- Dutcher, Dabrina D., et al.
(author)
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Emissions from soy biodiesel blends: A single particle perspective
- 2011
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In: Atmospheric Environment. - : Elsevier BV. - 1352-2310. ; 45:20, s. 3406-3413
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Journal article (peer-reviewed)abstract
- Biodiesel has recently reemerged as a common fuel. However, emissions from biodiesel combustion have been studied in much less detail than those from traditional petroleum-based diesel. In this experiment, emissions from the combustion of different fuel blends (BOO, B02, B20, B99, where the number after B indicates the percentage, by volume, of biodiesel in the fuel) in a VW TDi engine were analyzed by aerosol time-of-flight mass spectrometers (ATOFMS) for single-particle composition and vacuum aerodynamic size. The ATOFMS results show that the PAH molecular weight distribution is not significantly affected by the fuel composition, and that sulfates are reduced by increased biodiesel content. Octanedioic acid (a carbonyl species) is increased with increased biodiesel concentration. Clustering results from the single-particle spectra show that the particles fall in five main types by chemical composition. The aerodynamic size distribution of these individual clusters was also determined. These results also show that methods used to identify diesel particle emissions for source apportionment are not applicable when significant concentrations of biodiesel are used in fuels. (C) 2011 Elsevier Ltd. All rights reserved.
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| 7. |
- Grundström, Maria, 1979, et al.
(author)
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Urban NO2 and NO pollution in relation to the North Atlantic Oscillation NAO
- 2011
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In: Atmospheric Environment. - : Elsevier BV. - 1352-2310. ; 45:4, s. 883-888
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Journal article (peer-reviewed)abstract
- The North Atlantic Oscillation (NAO), a measure of the strength of the zonal wind across the North Atlantic Ocean, strongly influences weather conditions in NW Europe, e.g. temperature, precipitation and wind, especially during winter. It was hypothesised that elevated concentrations of nitrogen oxides in Gothenburg would be enhanced during negative NAO index (NAOI) conditions, representing more anticyclonic weather situations and thus leading to limited air mixing in the urban atmosphere, than situations with NAOI > 0. Hourly wintertime (DecembereFebruary) concentrations (1997e2006) of NO2, NO, air pressure, temperature and wind direction from an urban rooftop (30mabove street level) in the centre of the City of Gothenburg were analysed in relation to NAOI. Air pressure, the average concentration of nitrogen oxides (NOx ¼ NO2 þ NO), as well as the fraction of hourly NO2 and NO concentrations exceeding 90 mg m_3 and the fraction of daily NO concentrations exceeding 60 mg m_3, were significantly and negatively related to NAOI. Air temperature was positively correlated with NAOI. Southerly and westerly winds were more common in months with positive NAOI, while easterly and northerly winds were overrepresented in months with negative NAOI. High pollution concentrations dominantly occurred in situations with northerly and easterly wind directions. High NO2 and NO concentrations were associated with negative NAOI, especially in the morning when the traffic rush coincided with restricted air mixing. Over the tenyear period there were trends for more negative NAOI and increased time fractions with hourly NO2 concentrations exceeding 90 mgm_3. The conclusion of this study is that a climate shift towards higher or lower NAOI has the potential to significantly influence urban air pollution in North-West Europe, and thus the possibility to reach air quality standards, even if emissions remain constant.
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| 8. |
- Lindgren, Magnus, et al.
(author)
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Analysis of unregulated emissions from an off-road diesel engine during realistic work operations
- 2011
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In: Atmospheric Environment. - : Elsevier BV. - 1352-2310. ; 45, s. 5394-5398
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Journal article (peer-reviewed)abstract
- Emissions from vehicle diesel engines constitute a considerable share of anthropogenic emissions of pollutants, including many non-regulated compounds such as aromatic hydrocarbons and alkenes. One way to reduce these emissions might be to use fuels with low concentrations of aromatic hydrocarbons, such as Fischer–Tropsch (F–T) diesels. Therefore this study compared Swedish Environmental Class 1 diesel (EC1) with the F–T diesel fuel Ecopar™ in terms of emissions under varied conditions (steady state, controlled transients and realistic work operations) in order to identify factors influencing emissions in actual operation. Using F–T diesel reduced emissions of aromatic hydrocarbons, but not alkenes. Emissions were equally dependent on work operation character (load, engine speed, occurrence of transients) for both fuels. There were indications that the emissions originated from unburnt fuel, rather than from combustion products
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| 9. |
- Martin Ngwabie, Ngwa, et al.
(author)
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Effects of animal activity and air temperature on methane and ammonia emissions from a naturally ventilated building for dairy cows
- 2011
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In: Atmospheric Environment. - : Elsevier BV. - 1352-2310. ; 45, s. 6760-6768
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Journal article (peer-reviewed)abstract
- Knowledge of how different factors affect gas emissions from animal buildings can be useful for emission prediction purposes and for the improvement of emission abatement techniques. In this study, the effects of dairy cow activity and indoor air temperature on gas emissions were examined. The concentrations of CH(4), NH(3), CO(2) and N(2)O inside and outside a dairy cow building were measured continuously between February and May together with animal activity and air temperature. The building was naturally ventilated and had a solid concrete floor which sloped towards a central urine gutter. Manure was scraped from the floor once every hour in the daytime and once every second hour at night into a partly covered indoor pit which was emptied daily at 6 a.m. and at 5 p.m. Gas emissions were calculated from the measured gas concentrations and ventilation rates estimated by the CO(2) balance method. The animal activity and emission rates of CH(4) and NH(3) showed significant diurnal variations with two peaks which were probably related to the feeding routine. On an average day, CH(4) emissions ranged from 7 to 15 g LU(-1) h(-1) and NH(3) emissions ranged from 0.4 to 1.5 g LU(-1) h(-1) (1 LU = 500 kg animal weight). Mean emissions of CH(4) and NH(3) were 10.8 g LU(-1) h(-1) and 0.81 g LU(-1) h(-1), respectively. The NH(3) emissions were comparable to emissions from tied stall buildings and represented a 4% loss in manure nitrogen. At moderate levels, temperature seems to affect the behaviour of dairy cows and in this study where the daily indoor air temperature ranged from about 5 up to about 20 degrees C, the daily activity of the cows decreased with increasing indoor air temperature (r = -0.78). Results suggest that enteric fermentation is the main source of CH(4) emissions from systems of the type in this study, while NH(3) is mainly emitted from the manure. Daily CH(4) emissions increased significantly with the activity of the cows (r = 0.61) while daily NH(3) emissions increased significantly with the indoor air temperatures (r = 0.66). Daily CH(4) emissions were negatively correlated to the indoor air temperature (r = -0.84). This suggests that increased daily indoor air temperatures due to seasonal changes may bring about decreased animal activity which may decrease the release of CH(4) from dairy cows. Finally, changes in daily NH(3) emissions were influenced more by the indoor air temperature than by the activity of the cows. (C) 2011 Elsevier Ltd. All rights reserved.
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