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Sökning: (WFRF:(Seshadri S)) > (2005-2009)

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  • Fecht, H. -J, et al. (författare)
  • Thermophysical properties of liquids : Modelling and non-metallic materials
  • 2005
  • Ingår i: ESA SP. - 0379-6566 .- 1609-0438. ; :1281, s. 24-35
  • Tidskriftsartikel (refereegranskat)abstract
    • The accurate knowledge and high-precision measurements of the thermophysical properties of liquids is necessary for the numerical modeling of industrial processes where the solid-liquid phase transformation plays a crucial role. The reduction of magnetic levitation forces in microgravity leads either to a significant improvement in accuracy or makes the measurement possible in the first place. High-precision measurements on chemically highly reactive melts require containerless processing using non-contact diagnostic tools. Scientific precursor experiments were conducted in the TEMPUS containerless processing facility during the Spacelab IML-2 and MSL-1 missions, also.
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  • Basu, S., et al. (författare)
  • Activity of iron oxide in steelmaking slag
  • 2008
  • Ingår i: Metallurgical and materials transactions. B, process metallurgy and materials processing science. - : Springer Science and Business Media LLC. - 1073-5615 .- 1543-1916. ; 39:3, s. 447-456
  • Tidskriftsartikel (refereegranskat)abstract
    • Most refining reactions in steelmaking involve oxidation of impurity element(s). The product(s) of oxidation either dissolve in the slag or escape as gaseous phase. The activities of oxygen in the metal (h (O)), and that of "FeO" in slag (a (FeO)), are major factors controlling these chemical reactions. The activities of oxygen and "FeO" are thermodynamically related, provided equilibrium distribution of oxygen between the slag and the metal is attained. This enables direct estimation of one parameter from the other. A thorough knowledge of the variation in activity of FeO, and factors affecting the same, is therefore of great importance in the process metallurgy of steelmaking. The present work experimentally measures the activity of FeO in steelmaking slags and attempts to develop a correlation for estimation of gamma(FeO) as a function of temperature and chemical composition of the slag.
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  • Wang, Lijun, 1979-, et al. (författare)
  • High-temperature mass spectrometric study of the vaporization process in the system CaO-MgO-Al2O3-Cr2O3-FeO-SiO2
  • 2009
  • Ingår i: Rapid Communications in Mass Spectrometry. - : Wiley. - 0951-4198 .- 1097-0231. ; 23, s. 2233-2239
  • Tidskriftsartikel (refereegranskat)abstract
    • Knudsen effusion mass spectrometry was used to study vaporization processes and thermodynamic properties of twenty samples of chromium-containing slags in the CaO-MgO-Al2O3-Cr2O3-FeO-SiO 2 system in the temperature range 1850-2750 K. Tungsten cells were used and Cr2O3 solid was used as a reference material. The system was calibrated using liquid gold. As FeO was the first emanating vapor species, monitoring of the chromium-containing species could be carried out only after the complete vaporization of FeO. This, however, was found to have very little impact on the concentration of the slags investigated. During the measurements, the ion current intensities of CrO+ and CrO +2 species in the mass spectra of the vapor over the CaO-MgO-Al2O3-Cr2O3-FeO-SiO 2 samples were monitored and compared with those corresponding to solid Cr2O3. Data on the partial pressures of vapor species as well as the activities of Cr2O3 as a function of temperature were obtained. The results are expected to be valuable in the optimization of slag composition in high alloy steelmaking processes.
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  • Resultat 1-8 av 8

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