1. |
- Chen, Zhe, et al.
(author)
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Nano-scale characterization of white layer in broached Inconel 718
- 2017
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In: Materials Science & Engineering A: Structural Materials: Properties, Microstructure and Processing. - Amsterdam : Elsevier BV. - 0921-5093 .- 1873-4936. ; 684, s. 373-384
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Journal article (peer-reviewed)abstract
- The formation mechanism of white layers during broaching and their mechanical properties are not well investigated and understood to date. In the present study, multiple advanced characterization techniques with nano-scale resolution, including transmission electron microscopy (TEM), transmission Kikuchi diffraction (TKD), atom probe tomography (APT) as well as nano-indentation, have been used to systematically examine the microstructural evolution and corresponding mechanical properties of a surface white layer formed when broaching the nickel-based superalloy Inconel 718.TEM observations showed that the broached white layer consists of nano-sized grains, mostly in the range of 20–50 nm. The crystallographic texture detected by TKD further revealed that the refined microstructure is primarily caused by strong shear deformation. Co-located Al-rich and Nb-rich fine clusters have been identified by APT, which are most likely to be γ′ and γ′′ clusters in a form of co-precipitates, where the clusters showed elongated and aligned appearance associated with the severe shearing history. The microstructural characteristics and crystallography of the broached white layer suggest that it was essentially formed by adiabatic shear localization in which the dominant metallurgical process is rotational dynamic recrystallization based on mechanically-driven subgrain rotations. The grain refinement within the white layer led to an increase of the surface nano-hardness by 14% and a reduction in elastic modulus by nearly 10% compared to that of the bulk material. This is primarily due to the greatly increased volume fraction of grain boundaries, when the grain size was reduced down to the nanoscale.
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2. |
- Ekener, Elisabeth, 1963-, et al.
(author)
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Developing Life Cycle Sustainability Assessment methodology by applying values-based sustainability weighting - Tested on biomass based and fossil transportation fuels
- 2018
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In: Journal of Cleaner Production. - : Elsevier BV. - 0959-6526 .- 1879-1786. ; 181, s. 337-351
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Journal article (peer-reviewed)abstract
- The production and use of transportation fuels can lead to sustainability impacts. Assessing them simultaneously in a holistic way is a challenge. This paper examines methodology for assessing the sustainability performance of products in a more integrated way, including a broad range of social impacts. Life Cycle Sustainability Assessment (LCSA) methodology is applied for this assessment. LSCA often constitutes of the integration of results from social LCA (S-LCA), environmental life cycle assessment (E-LCA) and life cycle costing (LCC). In this study, an S-LCA from an earlier project is extended with a positive social aspect, as well as refined and detailed. E-LCA and LCC results are built from LCA database and literature. Multi Criteria Decision Analysis (MCDA) methodology is applied to integrate the results from the three different assessments into an LCSA. The weighting of key sustainability dimensions in the MCDA is performed in different ways, where the sustainability dimensions are prioritized differently priority based on the assumed values of different stakeholder profiles (Egalitarian, Hierarchist, and Individualist). The developed methodology is tested on selected biomass based and fossil transportation fuels - ethanol produced from Brazilian sugarcane and US corn/maize, and petrol produced from Russian and Nigerian crude oils, where it delineates differences in sustainability performance between products assessed. The outcome in terms of relative ranking of the transportation fuel chains based on sustain ability performance differs when applying different decision-maker profiles. This result highlights and supports views that there is no one single answer regarding which of the alternatives that is most sustainable. Rather, it depends strongly upon the worldview and values held by the decision maker. A key conclusion is that sustainability assessments should pay more attention to potential differences in underlying values held by key stakeholders in relevant societal contexts. The LCSA methodology still faces challenges regarding results integration but MCDA in combination with stakeholder profiles appears to be a useful approach to build on further.
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3. |
- Punzi, Marisa, et al.
(author)
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Combined anaerobic-ozonation process for treatment of textile wastewater : Removal of acute toxicity and mutagenicity
- 2015
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In: Journal of Hazardous Materials. - : Elsevier BV. - 0304-3894 .- 1873-3336. ; 292, s. 52-60
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Journal article (peer-reviewed)abstract
- A novel set up composed of an anaerobic biofilm reactor followed by ozonation was used for treatment of artificial and real textile effluents containing azo dyes. The biological treatment efficiently removed chemical oxygen demand and color. Ozonation further reduced the organic content of the effluents and was very important for the degradation of aromatic compounds, as shown by the reduction of UV absorbance. The acute toxicity toward Vibrio fischeri and the shrimp Artemia salina increased after the biological treatment. No toxicity was detected after ozonation with the exception of the synthetic effluent containing the highest concentration, 1. g/l, of the azo dye Remazol Red. Both untreated and biologically treated textile effluents were found to have mutagenic effects. The mutagenicity increased even further after 1. min of ozonation. No mutagenicity was however detected in the effluents subjected to longer exposure to ozone. The results of this study suggest that the use of ozonation as short post-treatment after a biological process can be beneficial for the degradation of recalcitrant compounds and the removal of toxicity of textile wastewater. However, monitoring of toxicity and especially mutagenicity is crucial and should always be used to assess the success of a treatment strategy. © 2015 Elsevier B.V.
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4. |
- Zambrano, Jesús, et al.
(author)
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Optimal steady-state design of zone volumes of bioreactors with Monod growth kinetics
- 2015
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In: Biochemical Engineering Journal. - : Elsevier BV. - 1369-703X .- 1873-295X. ; 100, s. 59-66
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Journal article (peer-reviewed)abstract
- This paper deals with steady-state analysis and design of bioreactors consisting of a number of completely stirred tank reactors (CSTRs) in series. The study is confined to one consumed (substrate) and one consuming constituent (biomass). The specific microbial growth rate is assumed to be described by Monod kinetics. The death of biomass is assumed to be negligible. Two optimal design problems for a large number of CSTRs in series are studied: to minimize the effluent substrate concentration for a given total volume, and to minimize the total volume for a given effluent substrate concentration. As an appealing alternative to solve these problems numerically, it is proposed to consider the asymptotic case where the number of CSTRs tends to infinity. This is shown to correspond to one CSTR in series with a plug flow reactor (PFR). A CSTR with a sufficient large volume is needed to avoid wash-out of the biomass. The main result is that both design problems for the CSTR + PFR configuration have the same solution with respect to the optimal volume of the CSTR, which is given as an explicit function of the incoming substrate concentration, the volumetric flow rate and the coefficients of the Monod growth rate function. Numerical results indicate that the plug flow approach may be used as a feasible design procedure even for a reasonably low number of CSTRs in series.
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5. |
- Fhager, Andreas, 1976, et al.
(author)
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Image Reconstruction in Microwave Tomography Using a Dielectric Debye Model
- 2012
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In: IEEE Transactions on Biomedical Engineering. - 0018-9294 .- 1558-2531. ; 59:1, s. 156 - 166
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Journal article (peer-reviewed)abstract
- In this paper, quantitative dielectric image reconstruction based on broadband microwave measurements is investigated. A time-domain-based algorithm is derived where Debye model parameters are reconstructed in order to take into account the strong dispersive behavior found in biological tissue. The algorithm is tested with experimental and numerical data in order to verify the algorithm and to investigate improvements in the reconstructed image resulting from the improved description of the dielectric properties of the tissue when using broadband data. The comparison is made in relation to the more commonly used conductivity model. For the evaluation, two examples were considered, the first was a lossy saline solution and the second was less lossy tap water. Both liquids are strongly dispersive and used as a background medium in the imaging examples. The results show that the Debye model algorithm is of most importance in the tap water for a bandwidth of more than 1.5 GHz. Also the saline solution exhibits a dispersive behavior but since the losses restrict the useful bandwidth, the Debye model is of less significance even if somewhat larger and stronger artifacts can be seen in the conductivity model reconstructions.
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6. |
- Kuktaite, Ramune, et al.
(author)
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Monitoring Nanostructure Dynamics and Polymerization in Glycerol Plasticized Wheat Gliadin and Glutenin Films : Relation to Mechanical Properties
- 2016
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In: ACS Sustainable Chemistry and Engineering. - : American Chemical Society (ACS). - 2168-0485. ; 4:6, s. 2998-3007
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Journal article (peer-reviewed)abstract
- Gliadin and glutenin proteins with 10, 20, 30 and 40% of glycerol were compression molded into films (130 °C) and evaluated for protein polymerization, β-sheet structure and nano-structural morphology. Here, for the first time we show how different amounts of glycerol impact the nano-structure and functional properties of the gliadin and glutenin films. Most polymerized protein was found in the gliadin films with 20 and 30% glycerol, and in all the glutenin films (except 10%), by RP-HPLC. A β-sheet-rich protein structure was found to be high in the 10 and 20% glycerol gliadin films, and in the 20 and 30% glycerol glutenin films by FT-IR. Glycerol content of 20, 30 and 40% impacted the nano-structural morphology of the gliadin glycerol films observed by SAXS, and to a limited extent for 10 and 20% glycerol gliadin films revealed by WAXS. No ordered nano-structure was found for the glutenin glycerol films. The 20%, 30% and 40% glycerol films were the most tunable for specific mechanical properties. For the highest stiffness and strength, the 10% glycerol protein films were the best choice.
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7. |
- Nakeva von Mentzer, Cecilia, 1968-, et al.
(author)
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Computer-assisted training of phoneme-grapheme correspondence for children who are deaf and hard of hearing : Effects on phonological processing skills
- 2013
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In: International Journal of Pediatric Otorhinolaryngology. - Amsterdam, Netherlands : Elsevier. - 0165-5876 .- 1872-8464. ; 77:12, s. 2049-2057
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Journal article (peer-reviewed)abstract
- Objective: Examine deaf and hard of hearing (DHH) children's phonological processing skills in relation to a reference group of children with normal hearing (NH) at two baselines pre intervention. Study the effects of computer-assisted phoneme-grapheme correspondence training in the children. Specifically analyze possible effects on DHH children's phonological processing skills.Methods: The study included 48 children who participated in a computer-assisted intervention study, which focuses on phoneme-grapheme correspondence. Children were 5, 6, and 7 years of age. There were 32 DHH children using cochlear implants (CI) or hearing aids (HA), or both in combination, and 16 children with NH. The study had a quasi-experimental design with three test occasions separated in time by four weeks; baseline 1 and 2 pre intervention, and 3 post intervention. Children performed tasks measuring lexical access, phonological processing, and letter knowledge. All children were asked to practice ten minutes per day at home supported by their parents.Results: NH children outperformed DHH children on the majority of tasks. All children improved their accuracy in phoneme-grapheme correspondence and output phonology as a function of the computer-assisted intervention. For the whole group of children, and specifically for children with CI, a lower initial phonological composite score was associated with a larger phonological change between baseline 2 and post intervention. Finally, 18 DHH children, whereof 11 children with CI, showed specific intervention effects on their phonological processing skills, and strong effect sizes for their improved accuracy of phoneme-grapheme correspondence.Conclusion: For some DHH children phonological processing skills are boosted relatively more by phoneme-grapheme correspondence training. This reflects the reciprocal relationship between phonological change and exposure to and manipulations of letters.
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8. |
- Blomfors, Mattias, 1990, et al.
(author)
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Partial safety factors for the anchorage capacity of corroded reinforcement bars in concrete
- 2019
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In: Engineering structures. - : Elsevier BV. - 0141-0296 .- 1873-7323. ; 181, s. 579-588
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Journal article (peer-reviewed)abstract
- Many reinforced concrete bridges in Europe and around the world are damaged by reinforcement corrosion and the annual maintenance costs are enormous. It is therefore important to develop reliable methods to assess the structural capacity of corroded reinforced concrete structures and avoid unnecessary maintenance costs. Although there are advanced models for determining the load carrying capacity of structures, it is not obvious how they should be used to verify the performance of existing structures. To confidently assess the bond of corroded reinforcement in concrete, for example, the calculation model must give a sufficient safety margin. When designing new structures, semi-probabilistic approaches (such as the partial safety factor method) are adopted to achieve the target reliabilities specified in structural design codes. This paper uses probabilistic methods to develop partial factors for application in an existing bond model, to assess the safety of corroded reinforced concrete structures. The response of the bond model was studied using Monte Carlo (MC) simulations for several design cases, with probability distributions fitted to the results. Partial factors were then derived, based on these distributions. Furthermore, an MC-based simulation technique called “importance sampling” was used to study the reliability of several deterministic bond assessments conducted using these partial factors. The results show that deterministic assessments which use the proposed partial factors lead to a safety level at least equal to the target value. The results presented in this paper will support the assessment of reinforced concrete structures with anchorage problems and give a reasonable approximation of the anchorage capacity with sufficient safety margin. When generalised to cover other failure modes and structural configurations, this will enable better utilisation of damaged structures and lead to major environmental and economical savings for society.
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9. |
- Jägerbrand, Annika K., et al.
(author)
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Speed reduction effects over distance of animal-vehicle collision countermeasures – a driving simulator study
- 2018
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In: European Transport Research Review. - : Springer Publishing Company. - 1867-0717 .- 1866-8887. ; 10:2
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Journal article (peer-reviewed)abstract
- Purpose: This study examined if speed reduction effects from animal-vehicle collision (AVC) countermeasures are merely local or do extend to a wider area, and what implications the results have on road planning practice regarding AVCs.Methods: Twenty-five drivers drove repeatedly on a 9-km long road stretch in a high-fidelity driving simulator. The development of vehicle speed in the surrounding of an automatic speed camera, a wildlife warning sign and a radio message, were investigated in a full factorial within-subject experiment. The factors wildlife fence (with/without) and forest (dense/open landscape) were also included.Results: The radio warning message had the largest influence on vehicle speed with a speed reduction of 8 km/h that lasted beyond 1 km and 2 km after the implementation. Eighty-eight per cent of the drivers reported being made extra aware of AVC due to the radio message, which was also associated with stress, insecurity and unsafety. The warning sign reduced vehicle speed by 1.5 km/h, but speed reductions were not significantly reduced 1 km after the implementation. Only 8 % of the drivers felt insecure/unsafe after passing the wildlife warning sign, explaining its limited impact on speed. There were no main effects of the automatic speed camera on vehicle speed at longer distances after implementation.Conclusions: We recommend that AVC countermeasures should be of various design, occur at various segments along the road, and preferably be adaptive and geo-localized to minimize habituation effects on drivers.
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10. |
- Nordebo, Sven, 1963-, et al.
(author)
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A parametric model for the changes in the complex valued conductivity of a lung during tidal breathing
- 2018
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In: Journal of Physics D. - : IOP Publishing. - 0022-3727 .- 1361-6463. ; 51:20
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Journal article (peer-reviewed)abstract
- Classical homogenization theory based on the Hashin-Shtrikman coated ellipsoids is used to model the changes in the complex valued conductivity (or admittivity) of a lung during tidal breathing. Here, the lung is modeled as a two-phase composite material where the alveolar air-filling corresponds to the inclusion phase. The theory predicts a linear relationship between the real and the imaginary parts of the change in the complex valued conductivity of a lung during tidal breathing, and where the loss cotangent of the change is approximately the same as of the effective background conductivity and hence easy to estimate. The theory is illustrated with numerical examples based on realistic parameter values and frequency ranges used with electrical impedance tomography (EIT). The theory may be potentially useful for imaging and clinical evaluations in connection with lung EIT for respiratory management and control.
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