1. |
- Bielawski, Marcin, et al.
(author)
-
Efficient and General One-Pot Synthesis of Diaryliodonium Triflates : Optimization, Scope and Limitations
- 2007
-
In: Advanced Synthesis and Catalysis. - : Wiley. - 1615-4150 .- 1615-4169. ; 349:17-18, s. 2610-2618
-
Journal article (peer-reviewed)abstract
- Symmetrical and unsymmetrical diaryliodonium triflates have been synthesized from both electron-deficient and electron-rich arenes and aryl iodides with mCPBA and triflic acid. A thorough investigation of the optimization, scope and limitations has resulted in an improved one-pot protocol that is fast, high-yielding, and operationally simple. The reaction has been extended to the direct synthesis of symmetrical iodonium salts from iodine and arenes, conveniently circumventing the need for aryl iodides.
|
|
2. |
|
|
3. |
|
|