| 1. |
- Tian, Yu-peng, et al.
(author)
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Synthesis, crystal structure and NLO properties of a novel ruthenium(II) complex with unusual coordination mode
- 2005
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In: Transition metal chemistry (Weinheim). - : Kluwer Academic Publishers. - 0340-4285 .- 1572-901X. ; 30:7, s. 778-785
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Journal article (peer-reviewed)abstract
- A new Schiff base 4-[N-hydroxyethyl-N-(methyl)amino]benzaldehyde S-methyl dithiocarbazate (HL, where H is a dissociable proton) and the ruthenium complex [Ru(bpy)2L]PF6 (bpy = 2,2′-bipyridine) have been synthesized. The structural determinations of the ligand and its ruthenium complex, by X-ray crystallography, show that the ligand is coordinated as a monoanionic bidentate N, S-donor, forming a four-member chelate ring with a bite angle of 65.91°. The complex shows intense MLCT transitions in the visible region. Fluorescent and electrochemical properties have been also studied. The complex in DMF solution exhibited a strong two-photon absorption (t.p.a.) at 532 nm nanosecond laser pulses. The t.p.a. coefficient β, t.p.a. cross-section σ and the third-order optical nonlinearity χ(3) of the complex and the ligand have been determined by the Z-scan technique.
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| 2. |
- Zhang, Xuanjun, et al.
(author)
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Two strong emitting coordination polymers with chain and ladder structures
- 2003
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In: Transition metal chemistry (Weinheim). - Netherlands : Kluwer Academic Publishers. - 0340-4285 .- 1572-901X. ; 28:6, s. 707-711
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Journal article (peer-reviewed)abstract
- Two coordination polymers [Zn(Cabo)2(EtOH)2(4,4′-Bipy)]n(1), and [Zn2(Cabo)2(NO3)2(4,4′-Bipy)2]n(2) (Cabo = carbazolylacetate, 4,4′-Bipy = 4,4′-bipyridine) with chain and ladder structures, respectively, were prepared and characterized by X-ray single-crystal structural analysis. The results showed that the different anions of metal salts have a large effect on the construction of coordination frameworks. Both complexes show strong emissions in the solid state as well as high thermal stability.
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| 3. |
- Zhang, Xuanjun, et al.
(author)
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Zn(II) and Cd(II) N-carbazolylacetates with strong fluorescence
- 2003
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In: Polyhedron. - : Elsevier. - 0277-5387 .- 1873-3719. ; 22:3, s. 397-402
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Journal article (peer-reviewed)abstract
- N-carbazolylacetic acid was synthesized using a new method in a high yield and two carbazolylacetato complexes [Zn(Cabo)-(phen)2ClO4]·0.5C2H5OH and [Cd(Cabo)(phen)2-ClO4] (Cabo=N-carbazolylacetate, phen=1,10-phenanthroline) were synthesized and characterized by elemental analysis, IR, UV–Vis spectra, thermal analyses, photoluminescence measurement and X-ray diffraction studies. Both of the complexes exhibit strong blue emission in solid state as well as high thermal stability and solvent-resistant properties.
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