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- Larhed, M, et al.
(author)
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Rapid fluorous Stille coupling reactions conducted under microwave irradiation
- 1997
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In: Journal of Organic Chemistry. - UNIV PITTSBURGH,DEPT CHEM,PITTSBURGH,PA 15260. UNIV UPPSALA,CTR BIOMED,DEPT ORGAN PHARMACEUT CHEM,S-75123 UPPSALA,SWEDEN. : American Chemical Society (ACS). - 0022-3263 .- 1520-6904. ; 62:16, s. 5583-5587
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Journal article (peer-reviewed)abstract
- Palladium-catalyzed fluorous Stille cross-coupling reactions with organic halides or triflates require only 90-120 s for completion when conducted under microwave irradiation. Comparable thermal reactions require about 1 day. Fourteen different coupling products were synthesized and isolated in good yields after three-phase extraction (FC-84, dichloromethane, water) and chromatography. The examples extend the scope of the fluorous Stille coupling with respect to both the tin and halide/triflate components. Applications in parallel synthesis are suggested.
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- Olofsson, K, et al.
(author)
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High-speed, highly fluorous organic reactions
- 1999
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In: Journal of Organic Chemistry. - Uppsala Univ, BMC, Dept Organ Pharmaceut Chem, SE-75123 Uppsala, Sweden. Univ Pittsburgh, Dept Chem, Pittsburgh, PA 15260 USA. : American Chemical Society (ACS). - 0022-3263 .- 1520-6904. ; 64, s. 4539-
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Journal article (peer-reviewed)
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