| 1. |
- Dhungel, Omkar, et al.
(author)
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Near-zero-field microwave-free magnetometry with nitrogen-vacancy centers in nanodiamonds
- 2024
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In: Optics Express. - : Optica Publishing Group. - 1094-4087. ; 32:12, s. 21936-21945
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Journal article (peer-reviewed)abstract
- We study the fluorescence of nanodiamond ensembles as a function of static external magnetic field and observe characteristic dip features close to the zero field with potential for magnetometry applications. We analyze the dependence of the feature's width and the contrast of the feature on the size of the diamond (in the range 30 nm-3000 nm) and on the strength of a bias magnetic field applied transversely to the field being scanned. We also perform optically detected magnetic resonance (ODMR) measurements to quantify the strain splitting of the zero-field ODMR resonance across various nanodiamond sizes and compare it with the width and contrast measurements of the zero-field fluorescence features for both nanodiamonds and bulk samples. The observed properties provide compelling evidence of cross-relaxation effects in the NV system occurring close to zero magnetic fields. Finally, the potential of this technique for use in practical magnetometry is discussed.
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| 2. |
- Babar, Rohit, et al.
(author)
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Low-symmetry vacancy-related spin qubit in hexagonal boron nitride
- 2024
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In: npj Computational Materials. - : NATURE PORTFOLIO. - 2057-3960. ; 10:1
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Journal article (peer-reviewed)abstract
- Point defect qubits in semiconductors have demonstrated their outstanding capabilities for high spatial resolution sensing generating broad multidisciplinary interest. Hexagonal boron nitride (hBN) hosting point defect qubits have recently opened up new horizons for quantum sensing by implementing sensing foils. The sensitivity of point defect sensors in hBN is currently limited by the linewidth of the magnetic resonance signal, which is broadened due to strong hyperfine couplings. Here, we report on a vacancy-related spin qubit with an inherently low symmetry configuration, the VB2 center, giving rise to a reduced magnetic resonance linewidth at zero magnetic fields. The VB2 center is also equipped with a classical memory that can be utilized for storing population information. Using scanning transmission electron microscopy imaging, we confirm the existence of the VB2 configuration in free-standing monolayer hBN.
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| 3. |
- Barcza, Gergely, et al.
(author)
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DMRG on Top of Plane-Wave Kohn-Sham Orbitals: A Case Study of Defected Boron Nitride
- 2021
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In: Journal of Chemical Theory and Computation. - : AMER CHEMICAL SOC. - 1549-9618 .- 1549-9626. ; 17:2, s. 1143-1154
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Journal article (peer-reviewed)abstract
- In this paper, we analyze the numerical aspects of the inherent multireference density matrix renormalization group (DMRG) calculations on top of the periodic Kohn-Sham density functional theory using the complete active space approach. The potential of the framework is illustrated by studying hexagonal boron nitride nanoflakes embedding a charged single boron vacancy point defect by revealing a vertical energy spectrum with a prominent multireference character. We investigate the consistency of the DMRG energy spectrum from the perspective of sample size, basis size, and active space selection protocol. Results obtained from standard quantum chemical atom-centered basis calculations and plane-wave based counterparts show excellent agreement. Furthermore, we also discuss the spectrum of the periodic sheet which is in good agreement with extrapolated data of finite clusters. These results pave the way toward applying the DMRG method in extended correlated solid-state systems, such as point defect qubit in wide band gap semiconductors.
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| 4. |
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| 5. |
- Dhungel, Omkar, et al.
(author)
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Near zero-field microwave-free magnetometry with ensembles of nitrogen-vacancy centers in diamond
- 2024
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In: Physical Review B. - : AMER PHYSICAL SOC. - 2469-9950 .- 2469-9969. ; 109:22
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Journal article (peer-reviewed)abstract
- We study cross -relaxation features near zero magnetic field with ensembles of nitrogen -vacancy (NV) centers in diamond and examine their properties in samples with a range of 0.9-16.0 ppm of NV concentrations. The observed NV -NV cross -relaxation features between differently oriented NV centers in high (>= 0.9 ppm)NV-density samples hold promise for a variety of magnetometry applications where microwave fields (or any bias field) disturb the system under study. We theoretically determine the values of the bias magnetic fields corresponding to cross relaxations between different axes and experimentally validate them. The behavior of zero -field cross -relaxation features as a function of temperature is also investigated.
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| 6. |
- Gulka, Michal, et al.
(author)
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Room-temperature control and electrical readout of individual nitrogen-vacancy nuclear spins
- 2021
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In: Nature Communications. - : NATURE RESEARCH. - 2041-1723. ; 12:1
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Journal article (peer-reviewed)abstract
- Nuclear spins in semiconductors are leading candidates for future quantum technologies, including quantum computation, communication, and sensing. Nuclear spins in diamond are particularly attractive due to their long coherence time. With the nitrogen-vacancy (NV) centre, such nuclear qubits benefit from an auxiliary electronic qubit, which, at cryogenic temperatures, enables probabilistic entanglement mediated optically by photonic links. Here, we demonstrate a concept of a microelectronic quantum device at ambient conditions using diamond as wide bandgap semiconductor. The basic quantum processor unit - a single N-14 nuclear spin coupled to the NV electron - is read photoelectrically and thus operates in a manner compatible with nanoscale electronics. The underlying theory provides the key ingredients for photoelectric quantum gate operations and readout of nuclear qubit registers. This demonstration is, therefore, a step towards diamond quantum devices with a readout area limited by inter-electrode distance rather than by the diffraction limit. Such scalability could enable the development of electronic quantum processors based on the dipolar interaction of spin-qubits placed at nanoscopic proximity. Nuclear spins in diamond are promising for applications in quantum technologies due to their long coherence times. Here, the authors demonstrate a scalable electrical readout of individual intrinsic N-14 nuclear spins in diamond, mediated by hyperfine coupling to electron spin of the NV center, as a step towards room-temperature nanoscale diamond quantum devices.
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| 7. |
- Hamdi, Hanen, et al.
(author)
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Stone-Wales defects in hexagonal boron nitride as ultraviolet emitters
- 2020
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In: npj Computational Materials. - : Nature Research. - 2057-3960. ; 6:1
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Journal article (peer-reviewed)abstract
- Many quantum emitters have been measured close or near the grain boundaries of the two-dimensional hexagonal boron nitride where various Stone-Wales defects appear. We show by means of first principles density functional theory calculations that the pentagon-heptagon Stone-Wales defect is an ultraviolet emitter and its optical properties closely follow the characteristics of a 4.08-eV quantum emitter, often observed in polycrystalline hexagonal boron nitride. We also show that the square-octagon Stone-Wales line defects are optically active in the ultraviolet region with varying gaps depending on their density in hexagonal boron nitride. Our results may introduce a paradigm shift in the identification of fluorescent centres in this material.
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| 8. |
- Ivády, Viktor, et al.
(author)
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Ab initio theory of the negatively charged boron vacancy qubit in hexagonal boron nitride
- 2020
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In: npj Computational Materials. - : Nature Publishing Group. - 2057-3960. ; 6:1
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Journal article (peer-reviewed)abstract
- Highly correlated orbitals coupled with phonons in two-dimension are identified for paramagnetic and optically active boron vacancy in hexagonal boron nitride by first principles methods which are responsible for recently observed optically detected magnetic resonance signal. Here, we report ab initio analysis of the correlated electronic structure of this center by density matrix renormalization group and Kohn-Sham density functional theory methods. By establishing the nature of the bright and dark states as well as the position of the energy levels, we provide a complete description of the magneto-optical properties and corresponding radiative and non-radiative routes which are responsible for the optical spin polarization and spin dependent luminescence of the defect. Our findings pave the way toward advancing the identification and characterization of room temperature quantum bits in two-dimensional solids.
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| 9. |
- Ivády, Viktor, et al.
(author)
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Photoluminescence at the ground-state level anticrossing of the nitrogen-vacancy center in diamond: A comprehensive study
- 2021
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In: Physical Review B. - : AMER PHYSICAL SOC. - 2469-9950 .- 2469-9969. ; 103:3
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Journal article (peer-reviewed)abstract
- The nitrogen-vacancy center (NV center) in diamond at magnetic fields corresponding to the ground-state level anticrossing (GSLAC) region gives rise to rich photoluminescence (PL) signals due to the vanishing energy gap between the electron spin states, which enables for a broad variety of environmental couplings to have an effect on the NV centers luminescence. Previous works have addressed several aspects of the GSLAC photoluminescence, however, a comprehensive analysis of the GSLAC signature of NV ensembles in different spin environments at various external fields is missing. Here we employ a combination of experiments and recently developed numerical methods to investigate in detail the effects of transverse electric and magnetic fields, strain, P1 centers, NV centers, and the C-13 nuclear spins on the GSLAC photoluminescence. Our comprehensive analysis provides a solid ground for advancing various microwave-free applications at the GSLAC, including but not limited to magnetometry, spectroscopy, dynamic nuclear polarization (DNP), and nuclear magnetic resonance (NMR) detection. We demonstrate that not only the most abundant (NV)-N-14 center but the (NV)-N-15 can also be utilized in such applications.
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| 10. |
- Krumrein, Marcel, et al.
(author)
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Precise Characterization of a Waveguide Fiber Interface in Silicon Carbide
- 2024
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In: ACS Photonics. - : AMER CHEMICAL SOC. - 2330-4022.
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Journal article (peer-reviewed)abstract
- Spin-active optical emitters in silicon carbide are excellent candidates toward the development of scalable quantum technologies. However, efficient photon collection is challenged by undirected emission patterns from optical dipoles, as well as low total internal reflection angles due to the high refractive index of silicon carbide. Based on recent advances with emitters in silicon carbide waveguides, we now demonstrate a comprehensive study of nanophotonic waveguide-to-fiber interfaces in silicon carbide. We find that across a large range of fabrication parameters, our experimental collection efficiencies remain above 90%. Further, by integrating silicon vacancy color centers into these waveguides, we demonstrate an overall photon count rate of 181 kilo-counts per second, which is an order of magnitude higher compared to standard setups. We also quantify the shift of the ground state spin states due to strain fields, which can be introduced by waveguide fabrication techniques. Finally, we show coherent electron spin manipulation with waveguide-integrated emitters with state-of-the-art coherence times of T-2 similar to 42 mu s. The robustness of our methods is very promising for quantum networks based on multiple orchestrated emitters.
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