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- 2019
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Journal article (peer-reviewed)
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- Abolfathi, Bela, et al.
(author)
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The Fourteenth Data Release of the Sloan Digital Sky Survey : First Spectroscopic Data from the Extended Baryon Oscillation Spectroscopic Survey and from the Second Phase of the Apache Point Observatory Galactic Evolution Experiment
- 2018
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In: Astrophysical Journal Supplement Series. - : IOP Publishing Ltd. - 0067-0049 .- 1538-4365. ; 235:2
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Journal article (peer-reviewed)abstract
- The fourth generation of the Sloan Digital Sky Survey (SDSS-IV) has been in operation since 2014 July. This paper describes the second data release from this phase, and the 14th from SDSS overall (making this Data Release Fourteen or DR14). This release makes the data taken by SDSS-IV in its first two years of operation (2014-2016 July) public. Like all previous SDSS releases, DR14 is cumulative, including the most recent reductions and calibrations of all data taken by SDSS since the first phase began operations in 2000. New in DR14 is the first public release of data from the extended Baryon Oscillation Spectroscopic Survey; the first data from the second phase of the Apache Point Observatory (APO) Galactic Evolution Experiment (APOGEE-2), including stellar parameter estimates from an innovative data-driven machine-learning algorithm known as "The Cannon"; and almost twice as many data cubes from the Mapping Nearby Galaxies at APO (MaNGA) survey as were in the previous release (N = 2812 in total). This paper describes the location and format of the publicly available data from the SDSS-IV surveys. We provide references to the important technical papers describing how these data have been taken (both targeting and observation details) and processed for scientific use. The SDSS web site (www.sdss.org) has been updated for this release and provides links to data downloads, as well as tutorials and examples of data use. SDSS-IV is planning to continue to collect astronomical data until 2020 and will be followed by SDSS-V.
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- Blanton, Michael R., et al.
(author)
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Sloan Digital Sky Survey IV : Mapping the Milky Way, Nearby Galaxies, and the Distant Universe
- 2017
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In: Astronomical Journal. - : IOP Publishing Ltd. - 0004-6256 .- 1538-3881. ; 154:1
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Journal article (peer-reviewed)abstract
- We describe the Sloan Digital Sky Survey IV (SDSS-IV), a project encompassing three major spectroscopic programs. The Apache Point Observatory Galactic Evolution Experiment 2 (APOGEE-2) is observing hundreds of thousands of Milky Way stars at high resolution and. high signal-to-noise ratios in the near-infrared. The Mapping Nearby Galaxies at Apache Point Observatory (MaNGA) survey is obtaining spatially resolved spectroscopy for thousands of nearby galaxies (median z similar to 0.03). The extended Baryon Oscillation Spectroscopic Survey (eBOSS) is mapping the galaxy, quasar, and neutral gas distributions between z similar to 0.6 and 3.5 to constrain cosmology using baryon acoustic oscillations, redshift space distortions, and the shape of the power spectrum. Within eBOSS, we are conducting two major subprograms: the SPectroscopic IDentification of eROSITA Sources (SPIDERS), investigating X-ray AGNs. and galaxies in X-ray clusters, and the Time Domain Spectroscopic Survey (TDSS), obtaining spectra of variable sources. All programs use the 2.5 m Sloan Foundation Telescope at the. Apache Point Observatory; observations there began in Summer 2014. APOGEE-2 also operates a second near-infrared spectrograph at the 2.5 m du Pont Telescope at Las Campanas Observatory, with observations beginning in early 2017. Observations at both facilities are scheduled to continue through 2020. In keeping with previous SDSS policy, SDSS-IV provides regularly scheduled public data releases; the first one, Data Release 13, was made available in 2016 July.
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- Chuang, Yi-De, et al.
(author)
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Modular soft x-ray spectrometer for applications in energy sciences and quantum materials
- 2017
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In: Review of Scientific Instruments. - : AIP Publishing. - 1089-7623 .- 0034-6748. ; 88:1
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Journal article (peer-reviewed)abstract
- Over the past decade, the advances in grating-based soft X-ray spectrometers have revolutionizedthe soft X-ray spectroscopies in materials research. However, these novel spectrometers are mostlydedicated designs, which cannot be easily adopted for applications with diverging demands. Here wepresent a versatile spectrometer design concept based on the Hettrick-Underwood optical scheme thatuses modular mechanical components. The spectrometer’s optics chamber can be used with gratingsoperated in either inside or outside orders, and the detector assembly can be reconfigured accordingly.The spectrometer can be designed to have high spectral resolution, exceeding 10 000 resolvingpower when using small source (∼1 µm) and detector pixels (∼5 µm) with high line density gratings(∼3000 lines/mm), or high throughput at moderate resolution. We report two such spectrometers withslightly different design goals and optical parameters in this paper. We show that the spectrometer withhigh throughput and large energy window is particularly useful for studying the sustainable energymaterials. We demonstrate that the extensive resonant inelastic X-ray scattering (RIXS) map of batterycathode material LiNi1/3Co1/3Mn1/3O2 can be produced in few hours using such a spectrometer.Unlike analyzing only a handful of RIXS spectra taken at selected excitation photon energies across theelemental absorption edges to determine various spectral features like the localized dd excitations andnon-resonant fluorescence emissions, these features can be easily identified in the RIXS maps. Studyingsuch RIXS maps could reveal novel transition metal redox in battery compounds that are sometimeshard to be unambiguously identified in X-ray absorption and emission spectra. We propose that thismodular spectrometer design can serve as the platform for further customization to meet specificscientific demands.
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- Shao, Yu-Cheng, et al.
(author)
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The key energy scales of Gd-based metallofullerene determined by resonant inelastic X-ray scattering spectroscopy
- 2017
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In: Scientific Reports. - : Springer Science and Business Media LLC. - 2045-2322. ; 7:1
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Journal article (peer-reviewed)abstract
- Endohedral metallofullerenes, formed by encaging Gd inside fullerenes like C80, can exhibit enhanced proton relaxitivities compared with other Gd-chelates, making them the promising contrast agents for magnetic resonance imaging (MRI). However, the underlying key energy scales of Gd x Sc3-x N@C80 (x = 1-3) remain unclear. Here, we carry out resonant inelastic X-ray scattering (RIXS) experiments on Gd x Sc3-x N@C80 at Gd N 4,5-edges to directly study the electronic structure and spin flip excitations of Gd 4f electrons. Compared with reference Gd2O3 and contrast agent Gadodiamide, the features in the RIXS spectra of all metallofullerenes exhibit broader spectral lineshape and noticeable energy shift. Using atomic multiplet calculations, we have estimated the key energy scales such as the inter-site spin exchange field, intra-atomic 4f-4f Coulomb interactions, and spin-orbit coupling. The implications of these parameters to the 4f states of encapsulated Gd atoms are discussed.
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- Xu, Shuang Feng, et al.
(author)
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Lactoferrin ameliorates dopaminergic neurodegeneration and motor deficits in MPTP-treated mice
- 2019
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In: Redox Biology. - : Elsevier BV. - 2213-2317. ; 21
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Journal article (peer-reviewed)abstract
- Brain iron accumulation is common in patients with Parkinson's disease (PD). Iron chelators have been investigated for their ability to prevent neurodegenerative diseases with features of iron overload. Given the non-trivial side effects of classical iron chelators, lactoferrin (Lf), a multifunctional iron-binding globular glycoprotein, was screened to identify novel neuroprotective pathways against dopaminergic neuronal impairment. We found that Lf substantially ameliorated PD-like motor dysfunction in the subacute 1-methyl-4-phenyl-1,2,3,6-tetrahydropyridine (MPTP)-induced mouse model of PD. We further showed that Lf could alleviate MPTP-triggered apoptosis of DA neurons, neuroinflammation, and histological alterations. As expected, we also found that Lf suppressed MPTP-induced excessive iron accumulation and the upregulation of divalent metal transporter (DMT1) and transferrin receptor (TFR), which is the main intracellular iron regulation protein, and subsequently improved the activity of several antioxidant enzymes. We probed further and determined that the neuroprotection provided by Lf was involved in the upregulated levels of brain-derived neurotrophic factor (BDNF), hypoxia-inducible factor 1α (HIF-1α) and its downstream protein, accompanied by the activation of extracellular regulated protein kinases (ERK) and cAMP response element binding protein (CREB), as well as decreased phosphorylation of c-Jun N-terminal kinase (JNK) and mitogen activated protein kinase (MAPK)/P38 kinase in vitro and in vivo. Our findings suggest that Lf may be an alternative safe drug in ameliorating MPTP-induced brain abnormalities and movement disorder.
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- Xue, Chuang, et al.
(author)
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Bridging chemical- and bio-catalysis : high-value liquid transportation fuel production from renewable agricultural residues
- 2017
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In: Green Chemistry. - : Royal Society of Chemistry. - 1463-9262 .- 1463-9270. ; 19:3, s. 660-669
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Journal article (peer-reviewed)abstract
- Catalytic conversion of lignocellulosic biomass to high-value transportation petrol, jet and diesel fuels is of great importance to develop versatile renewable energy and boost the rural economy, thus it is receiving worldwide attention. However, the state-of-the-art processes still suffer from a low efficiency in yield and productivity, which hinders the progress of its commercialization. Thus, it is essential to explore the consolidated catalytic reaction and refinery process. Here we report an advanced approach/process that could continuously produce long-chain (C-5-C-15) ketones from lignocellulosic biomass in a cascade mode by integrating several bio- and chemical catalysis reactions/processes, which exhibits a high efficiency and stable conversion rate. This technology consolidated the acetone-butanol-ethanol (ABE) fermentation, palladium catalyzed alkylation and in situ product recovery, allowing the catalytic reaction to proceed consistently and smoothly. The remarkable conversion properties are mainly attributed to the excellent compatible linkage of chemical catalysis with biosynthesis and process design to stabilize the Pd catalytic reaction. This validated strategy for the rational process design and integration of chemical-and bio-catalysis offers great demonstration in producing high-value transportation biofuels derived from agricultural residues.
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