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- Almqvist, Bjarne, et al.
(author)
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Seismic anisotropy in the Morcles nappe shear zone : Implications for seismic imaging of crustal scale shear zones
- 2013
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In: Tectonophysics. - : Elsevier BV. - 0040-1951 .- 1879-3266. ; 603, s. 162-178
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Journal article (peer-reviewed)abstract
- Microstructures and textures of calcite mylonites from the Morcles nappe large-scale shearzone in southwestern Switzerland develop principally as a function of 1) extrinsic physical parameters including temperature, stress, strain, strain rate and 2) intrinsic parameters, such as mineral composition. We collected rock samples at a single location from this shear zone, on which laboratory ultrasonic velocities, texture and microstructures were investigated and quantified. The samples had different concentration of secondary mineral phases (<5 up to 40 vol.%). Measured seismic P waveanisotropy ranges from 6.5% for polyphase mylonites (similar to 40 vol.%) to 18.4% in mylonites with <5 vol.% secondary phases. Texture strength of calcite is the main factor governing the seismic P wave anisotropy. Measured S wave splitting is generally highest in the foliation plane, but its origin is more difficult to explain solely by calcite texture. Additional texture measurements were made on calcite mylonites with low concentration of secondary phases (<= 10 vol.%) along the metamorphic gradient of the shear zone (15 km distance). A systematic increase in texture strength is observed moving from the frontal part of the shear zone (anchimetamorphism: 280 degrees C) to the higher temperature, basal part (greenschist facies: 350-400 degrees C). Calculated P wave velocities become increasingly anisotropic towards the high-strain part of the nappe, from an average of 5.8%in the frontal part to 13.2% in the root of the basal part. Secondary phases raise an additional complexity, and may act either to increase or decrease seismic anisotropy of shear zone mylonites. Inlight of our findings we reinterpret the origin of some seismically reflective layers in the Grone-Zweisimmen line in southwestern Switzerland (PNR20 Swiss National Research Program). We hypothesize that reflections originate in part from the lateral variation in textural and microstructural arrangement of calcite mylonites in shear zones.
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| 3. |
- Sotiriou, Georgios A., et al.
(author)
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Thermal Energy Dissipation by SiO2-Coated Plasmonic-Superpararnagnetic Nanoparticles in Alternating Magnetic Fields
- 2013
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In: Chemistry of Materials. - : American Chemical Society (ACS). - 0897-4756 .- 1520-5002. ; 25:22, s. 4603-4612
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Journal article (peer-reviewed)abstract
- Multifunctional nanoparticles show great potential in the biomedical field and may help the diagnosis and therapy of diseases. Superparamagnetic nanoparticles are especially attractive because of their ability to dissipate thermal energy in an alternating magnetic field. Furthermore, plasmonic nanoparticles can be effectively used in non- or minimally invasive therapy of tumors exploiting their plasmonic photothermal effect. Here, hybrid plasmonicmagnetic Ag/Fe2O3 nanoparticles are made by flame aerosol technology. These nanoparticles can be in situ encapsulated with an amorphous nanothin SiO2 film to facilitate their dispersion and block any toxicity from Ag/Fe2O3. Detailed physicochemical characterization, including electron microscopy, electron dispersive X-ray spectroscopy, and X-ray diffraction, is performed. Furthermore, their magnetic properties are characterized in detail by monitoring their hysteresis, first-order-reversal-curves, and isothermal remanent magnetization. Finally, the effect of SiO2 and Agcontent on the specific absorption rate (SAR) of the hybrid Ag/Fe2O3 nanoparticles is investigated. The obtained understanding will help the rational design and engineering of multifunctional hybrid nanoprobes targeting specific biomedical applications.
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