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- Li, Shengli, et al.
(author)
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Formation of a Novel Polymeric Cadmium(II) Complex Bridged by Sulfur and Thiocyanato Ions
- 2003
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In: Chemistry Letters. - : Chemical Society of Japan. - 0366-7022 .- 1348-0715. ; 32:8, s. 748-749
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Journal article (peer-reviewed)abstract
- The title complex, {[N(CH3)4]2[Cd(SCN)2S]}n, was prepared by self-assembling from the reaction of a methanol/water (volume ratio, 1/1) solution containing cadmium(II) thiocyanate with equivalent amount of tetramethylammonium thiocyanate. The result of single X-ray determination for the complex reveals that a novel polymeric cadmium(II) complex bridged by sulfur and thiocyanato ions was obtained, which formed a two-dimensional (2D) structure.
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2. |
- Zhang, Xuanjun, et al.
(author)
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Zn(II) and Cd(II) N-carbazolylacetates with strong fluorescence
- 2003
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In: Polyhedron. - : Elsevier. - 0277-5387 .- 1873-3719. ; 22:3, s. 397-402
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Journal article (peer-reviewed)abstract
- N-carbazolylacetic acid was synthesized using a new method in a high yield and two carbazolylacetato complexes [Zn(Cabo)-(phen)2ClO4]·0.5C2H5OH and [Cd(Cabo)(phen)2-ClO4] (Cabo=N-carbazolylacetate, phen=1,10-phenanthroline) were synthesized and characterized by elemental analysis, IR, UV–Vis spectra, thermal analyses, photoluminescence measurement and X-ray diffraction studies. Both of the complexes exhibit strong blue emission in solid state as well as high thermal stability and solvent-resistant properties.
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