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- K. Wiesner, R. F. Fink, S. L. Sorensen, M. Andersson, R. Feifel, I. Hjelte, C. Miron, A. Naves de Brito, L. Rosenqvist, H. Wang, S. Svensson, O. Björneholm
(author)
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Valence Photoionization and Resonant Core Excitation of Ozone - Experimental and Theoretical Study of the C-State of O3
- 2003
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In: Chem Phys. Lett.. ; :375, s. 76-
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Journal article (peer-reviewed)
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- Rosenqvist, L, et al.
(author)
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Femtosecond dissociation of ozone studied by the Auger Doppler effect
- 2001
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In: JOURNAL OF CHEMICAL PHYSICS. - : AMER INST PHYSICS. - 0021-9606. ; 115:8, s. 3614-3620 Language: English
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Journal article (peer-reviewed)abstract
- A Doppler-type shift in the kinetic energy of atomic Auger electrons emitted after fast dissociation of O-3 molecules is observed. The resonant Auger spectrum from the decay of repulsive core-excited states reflects both the early molecular ozone decay an
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3. |
- Rosenqvist, L., et al.
(author)
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Femtosecond dissociation of ozone studied by the Auger Doppler effect
- 2001
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In: Journal of Chemical Physics. - : AIP Publishing. - 0021-9606 .- 1089-7690. ; 115:8, s. 3614-3620
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Journal article (peer-reviewed)abstract
- The peaks arising from the decay of the excited oxygen atom were studied. Fast dissociation of core-excited ozone was confirmed by the presence of Auger emission from atomic oxygen in the decay spectrum from the ozone OT 1s-σ*(7a1) state. No such emission was observed after excitation of the corresponding state on the central oxygen atom. An angle-dependent energy shift of the atomic lines was observed. Analysis of the energy shift revealed that the kinetic energy released in the dissociation process is approximately 3.3 ± 0.3eV. An energy release of 8.45 was found by application of a Born-Haber cycle.
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- Wiesner, K, et al.
(author)
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Valence photoionization and resonant core excitation of ozone - experimental and theoretical study of the (C)over-tilde-state of O-3(+)
- 2003
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In: Chemical Physics Letters. - 0009-2614. ; 375:1-2, s. 76-83
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Journal article (peer-reviewed)abstract
- Resonant Auger electron spectra of core excited O-3 (O(F)1s(-1) 2b(1)(1)) are presented for the first time. The photoionization valence spectrum with sample purity and resolution superior to those published is presented. The first direct experimental evidence for the (C) over tilde (2) B-1 state of O-3(+) is found. Ab initio calculations of the resonant Auger electron (RAE) spectrum have been performed supporting the assignment of the (C) over tilde -state. (C) 2003 Elsevier Science B.V. All rights reserved.
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