1. |
- Tchaplyguine, Maxim, et al.
(author)
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Absolute core-level binding energy shifts between atom and solid: The Born-Haber cycle revisited for free nanoscale metal clusters
- 2008
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In: Journal of Electron Spectroscopy and Related Phenomena. - : Elsevier BV. - 0368-2048 .- 1873-2526. ; 166, s. 38-44
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Journal article (peer-reviewed)abstract
- Core-level binding energy shifts between the free atom and corresponding large clusters, the latter closely approximating the infinite solid, have been experimentally derived for several elemental metals. The cluster core-level binding energies in question have been determined relative to the vacuum level using synchrotron-based photoelectron spectroscopy. As expected, the experimental shift values show reasonable agreement with those calculated using the thermochemical Born–Haber cycle approach. The largest uncertainty factors defining the discrepancies between the experiment and the model, such as the difference in the multiplet structure of free atoms and the solid, the in some cases indirectly established cluster work functions, and the metal solvation energy, are discussed.
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2. |
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3. |
- Andersson, Svante, 1962-, et al.
(author)
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A Glocal marketing model
- 2009. - 1
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In: Glocal Marketing. - Lund. - 9789144055558 ; , s. 391-396
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Book chapter (peer-reviewed)
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4. |
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5. |
- Andersson, Svante, 1962-, et al.
(author)
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Early Internationalizing Firms
- 2009. - 1
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In: Glocal marketing. - Lund. - 9789144055558 ; , s. 45-64
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Book chapter (peer-reviewed)
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6. |
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7. |
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8. |
- Andersson, Svante, 1962-, et al.
(author)
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The International Entrepreneur
- 2009. - 1
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In: Glocal Marketing. - Lund : Studentlitteratur. - 9789144055558 ; , s. 257-276
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Book chapter (peer-reviewed)
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9. |
- Andersson, Svante, 1962-, et al.
(author)
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Think Globally and Act Locally
- 2009. - 1
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In: Glocal Marketing. - Lund : Studentlitteratur. - 9789144055558 ; , s. 13-26
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Book chapter (peer-reviewed)
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10. |
- Bao, Zhuo, et al.
(author)
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Detailed Theoretical and Experimental Description of Normal Auger Decay in O2
- 2008
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In: Journal of Physics B. - : IOP Publishing. - 0953-4075 .- 1361-6455. ; 41:12, s. 125101-
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Journal article (peer-reviewed)abstract
- The normal Auger electron spectrum of the O-2 molecule is assigned in detail on the basis of ab initio valence configuration interaction (CI) wavefunctions. Potential energy curves of the ground state, the core-ionized states and the doubly charged final states are calculated and Auger decay rates are obtained with the one-centre approximation. Using the lifetime vibrational interference method, band shapes are obtained for all contributions to the Auger spectrum. The calculated Auger electron spectrum allows us to identify all features observed experimentally. Significant differences to previous assignments are reported. A quantitative simulation of the spectrum is given on the basis of a curve-fitting procedure, in which the energetic positions and intensities of the theoretical bands were optimized. Besides providing a basis for a refined analysis of the spectrum, the fit allows us to assess the accuracy of the calculation. As expected for this level of theory, the absolute accuracy of the valence CI energies is found to be about 0.3 eV. The inherent error of the one-centre transition rates is less than 5% of the most intense transition in the spectrum. The frequently questioned one-centre Auger transition rates are shown to be rather appropriate if applied with reasonable wavefunctions and if the vibrational band structure of the molecular spectrum is properly taken into account.
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