2. |
- Zhou, Xiao-Ping, et al.
(author)
-
Anion-p-Interaction-Directed Self-Assembly of Ag(I) Coordination Networks
- 2007
-
In: Crystal Growth & Design. - : American Chemical Society (ACS). - 1528-7483 .- 1528-7505. ; 7:3, s. 485-487
-
Journal article (peer-reviewed)abstract
- Reactions of AgX with 2,4,6-tri(2-pyridyl)-1,3,5-trazine (tpt) yielded three 3D highly symmetric isostructural coordination polymers (X = ClO4-, BF4-, and PF6-) and a dimer (X = CF3COO-), respectively. In the coordination polymers, anion−π interactions are found between the multiatomic anions and tpt ligands. Systematic variation including synthetic methods, ratios of reactants, and solvents provides synthetic evidence proving that anion−π interactions play a decisive role in assembly of the coordination polymers.
|
|