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Träfflista för sökning "WFRF:(Yoshida A) srt2:(2000-2004)"

Search: WFRF:(Yoshida A) > (2000-2004)

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  • Ueda, K, et al. (author)
  • Anisotropic ultrafast dissociation probed by the Doppler effect in resonant photoemission from CF4
  • 2003
  • In: Physical Review Letters. - 1079-7114. ; 90:23: 233006
  • Journal article (peer-reviewed)abstract
    • The resonant Auger spectrum from the decay of F 1s-excited CF4 is measured. Several lines exhibit a nondispersive kinetic energy as the exciting photon energy is tuned through the resonance region. The F 1s(-1) atomiclike Auger line is split into two components due to the emission of Auger electrons by a fragment in motion, when electron emission is observed along the polarization vector of the light. This Doppler splitting is direct evidence that the core excitation leads to T-d-->C-3v symmetry lowering, by elongation of a specific C-F bond preferentially aligned along the polarization vector of the incident photon.
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