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1.	Devasthale, Abhay, et al. (author) The vertical distribution of thin features over the Arctic analysed from CALIPSO observations : Part 2: Aerosols 2011 In: Tellus. Series B, Chemical and physical meteorology. - : Stockholm University Press. - 0280-6509 .- 1600-0889. ; 63:1, s. 86-95 Journal article (peer-reviewed)
2.	Lundén, Jenny, et al. (author) The vertical distribution of atmospheric DMS in the high Arctic summer 2010 In: Tellus. Series B, Chemical and physical meteorology. - : Stockholm University Press. - 0280-6509 .- 1600-0889. ; 62:3, s. 160-171 Journal article (peer-reviewed)abstract The vertical structure of gas-phase dimethyl sulfide, DMS(g), in the high Arctic atmosphere is investigated during a summer season. The model results show that the near-surface DMS(g) concentration over open ocean is very variable both in time and space, depending on the local atmospheric conditions. Profiles over ocean have typically highest concentration near the surface and decrease exponentially with height. Over the pack-ice, the concentrations are typically lower and the vertical structure changes as the air is advected northward. Modeled DMS(g) maxima above the local boundary layer were present in about 3\% of the profiles found over the pack-ice. These maxima were found in association to frontal zones. Our results also show that DMS(g) can be mixed downward by turbulence into the local boundary layer and act as a local near--surface DMS(g) source over the pack-ice and may hence influence the growth of cloud condensation nuclei and cloud formation in the boundary layer. Profile observations are presented in support to the model results. They show that significant DMS(g) concentrations exist in the Arctic atmosphere at altitudes not to be expected when only considering vertical mixing in the boundary layer.
3.	Devasthale, Abhay, et al. (author) The vertical distribution of thin features over the Arctic analysed from CALIPSO observations : Part 1: Optically thin clouds 2011 In: Tellus. Series B, Chemical and physical meteorology. - : Stockholm University Press. - 0280-6509 .- 1600-0889. ; 63:1, s. 77-85 Journal article (peer-reviewed)abstract Clouds play a crucial role in the Arctic climate system. Therefore, it is essential to accurately and reliably quantify and understand cloud properties over the Arctic. It is also important to monitor and attribute changes in Arctic clouds. Here, we exploit the capability of the CALIPSO-CALIOP instrument and provide comprehensive statistics of tropospheric thin clouds, otherwise extremely difficult to monitor from passive satellite sensors. We use 4 yr of data (June 2006-May 2010) over the circumpolar Arctic, here defined as 67-82 degrees N, and characterize probability density functions of cloud base and top heights, geometrical thickness and zonal distribution of such cloud layers, separately for water and ice phases, and discuss seasonal variability of these properties. When computed for the entire study area, probability density functions of cloud base and top heights and geometrical thickness peak at 200-400, 1000-2000 and 400-800 m, respectively, for thin water clouds, while for ice clouds they peak at 6-8, 7-9 and 400-1000 m, respectively. In general, liquid clouds were often identified below 2 km during all seasons, whereas ice clouds were sensed throughout the majority of the upper troposphere and also, but to a smaller extent, below 2 km for all seasons.
4.	Hegg, Dean A., et al. (author) Measurements of black carbon aerosol washout ratio on Svalbard 2011 In: Tellus. Series B, Chemical and physical meteorology. - : Stockholm University Press. - 0280-6509 .- 1600-0889. ; 63:5, s. 891-900 Journal article (peer-reviewed)abstract Simultaneous measurements of aerosol black carbon (BC) in both fresh snow and in air on Svalbard are presented. From these, washout ratios for BC are calculated and compared to sparse previous measurements of this metric in the arctic. The current ratios are significantly higher than previously found measured values. We argue that the degree of snow riming within the accretion zone can explain most of this difference. Using an analytical model of the scavenging process, BC scavenging efficiencies are estimated to lie in the range 0.25-0.5, comparable to measured values.
5.	Karl, Matthias, et al. (author) A new flexible multicomponent model for the study of aerosol dynamics in the marine boundary layer 2011 In: Tellus. Series B, Chemical and physical meteorology. - : Stockholm University Press. - 0280-6509 .- 1600-0889. ; 63:5, s. 1001-1025 Journal article (peer-reviewed)abstract A new sectional aerosol dynamics model, MAFOR, was developed with the focus to study nucleation in the marine boundary layer. Novel aspects of the model are (1) flexibility in the treatment of gas phase chemistry, (2) treatment of liquid phase chemistry, which can be extended according to needs and (3) simultaneous calculation of number and mass concentration distributions of a multicomponent aerosol as functions of time. Comparison with well-documented aerosol models (MONO32 and AEROFOR), a comprehensive data set on gas phase compounds, aerosol size distribution and chemical composition obtained during the AOE-96 (Arctic Ocean Expedition, 1996) was used to evaluate the model. Dimethyl sulphide decay during advection of an air parcel over the Arctic pack ice was well captured by the applied models and predicted concentrations of gaseous sulphuric acid and methane sulphonic acid range up to 1.0 x 10(6) cm(-3) and 1.8 x 10(6) cm(-3), respectively. Different nucleation schemes were implemented in MAFOR which allow the simulation of new particle formation. Modelled nucleation rates from sulphuric acid nucleation via cluster activation were up to 0.21 cm(-3) s(-1) while those from ion-mediated nucleation were below 10(-2) cm(-3) s(-1). Classical homogeneous binary and ternary nucleation theories failed to predict nucleation over the central Arctic Ocean in summer.
6.	Tesche, Matthias, et al. (author) Optical and microphysical properties of smoke over Cape Verde inferred from multiwavelength lidar measurements 2011 In: Tellus. Series B, Chemical and physical meteorology. - : Stockholm University Press. - 0280-6509 .- 1600-0889. ; 63:4, s. 677-694 Journal article (peer-reviewed)abstract Lidar measurements of mixed dust/smoke plumes over the tropical Atlantic ocean were carried out during the winter campaign of SAMUM-2 at Cape Verde. Profiles of backscatter and extinction coefficients, lidar ratios, and Angstrom exponents related to pure biomass-burning aerosol from southern West Africa were extracted from these observations. Furthermore, these findings were used as input for an inversion algorithm to retrieve microphysical properties of pure smoke. Seven measurement days were found suitable for the procedure of aerosol-type separation and successive inversion of optical data that describe biomass-burning smoke. We inferred high smoke lidar ratios of 87 +/- 17 sr at 355 nm and 79 +/- 17 sr at 532 nm. Smoke lidar ratios and Angstrom exponents are higher compared to the ones for the dust/smoke mixture. These numbers indicate higher absorption and smaller sizes for pure smoke particles compared to the dust/smoke mixture. Inversion of the smoke data set results in mean effective radii of 0.22 +/- 0.08 mu m with individual results varying between 0.10 and 0.36 mu m. The single-scattering albedo for pure biomass-burning smoke was found to vary between 0.63 and 0.89 with a very low mean value of 0.75 +/- 0.07. This is in good agreement with findings of airborne in situ measurements which showed values of 0.77 +/- 0.03. Effective radii from the inversion were similar to the ones found for the fine mode of the in situ size distributions.
7.	Tesche, Matthias, et al. (author) Profiling of Saharan dust and biomass-burning smoke with multiwavelength polarization Raman lidar at Cape Verde 2011 In: Tellus. Series B, Chemical and physical meteorology. - : Stockholm University Press. - 0280-6509 .- 1600-0889. ; 63:4, s. 649-676 Journal article (peer-reviewed)abstract Extensive lidar measurements of Saharan dust and biomass-burning smoke were performed with one airborne and three ground-based instruments in the framework of the second part of the SAharan Mineral dUst experiMent (SAMUM-2a) during January and February of 2008 at Cape Verde. Further lidar observations with one system only were conducted during May and June of 2008 (SAMUM-2b). The active measurements were supported by Sun photometer observations. During winter, layers of mineral dust from the Sahara and biomass-burning smoke from southern West Africa pass Cape Verde on their way to South America while pure dust layers cross the Atlantic on their way to the Caribbean during summer. The mean 500-nm aerosol optical thickness (AOT) observed during SAMUM-2a was 0.35 +/- 0.18. SAMUM-2a observations showed transport of pure dust within the lowermost 1.5 km of the atmospheric column. In the height range from 1.5 to 5.0 km, mixed dust/smoke layers with mean lidar ratios of 67 +/- 14 sr at 355 and 532 nm, respectively, prevailed. Within these layers, wavelength-independent linear particle depolarization ratios of 0.12-0.18 at 355, 532, and 710 nm indicate a large contribution (30-70%) of mineral dust to the measured optical properties. Angstrom exponents for backscatter and extinction of around 0.7 support this finding. Mean extinction coefficients in the height range between 2 and 4 km were 66 +/- 6 Mm(-1) at 355 nm and 48 +/- 5 Mm(-1) at 532 nm. Comparisons with airborne high-spectral-resolution lidar observations show good agreement within the elevated layers. 3-5 km deep dust layers where observed during SAMUM-2b. These layers showed optical properties similar to the ones of SAMUM-1 in Morocco with a mean 500-nm AOT of 0.4 +/- 0.2. Dust extinction coefficients were about 80 +/- 6 Mm(-1) at 355 and 532 nm. Dust lidar ratios were 53 +/- 10 sr at 355 and 532 nm, respectively. Dust depolarization ratios showed an increase with wavelength from 0.31 +/- 0.10 at 532 nm to 0.37 +/- 0.07 at 710 nm.
8.	Vogt, Matthias, et al. (author) Seasonal and diurnal cycles of 0.25–2.5 μm aerosol fluxes over urban Stockholm, Sweden 2011 In: Tellus. Series B, Chemical and physical meteorology. - : Stockholm University Press. - 0280-6509 .- 1600-0889. ; 63:5, s. 935-951 Journal article (peer-reviewed)abstract Size resolved aerosol and gas fluxes were measured in Stockholm from 1 April 2008 to 15 April 2009 over both urban and green sectors. CO2 and H2O fluxes peaked in daytime for all seasons. CO2 concentrations peaked in winter. Due to vegetation influence the CO2 fluxes had different diurnal cycles and magnitude in the two sectors. In the urban sector, CO2 fluxes indicated a net source. The sector dominated by residential areas and green spaces had its highest aerosol fluxes in winter. In spring, super micrometer concentrations for both sectors were significantly higher, as were the urban sector rush hour fluxes. The submicrometer aerosol fluxes had a similar diurnal pattern with daytime maxima for all seasons. This suggests that only the super micrometer aerosol emissions are dependent on season. During spring there was a clear difference in super micrometer fluxes between wet and dry streets. Our direct flux measurements have improved the understanding of the processes behind these aerosol emissions. They support the hypothesis that the spring peak in aerosol emissions are due to road dust, produced during the winter, but not released in large quantities until the roads dry up during spring, and explain why Stockholm has problems meeting the EU directive for aerosol mass (PM10).
9.	Aamaas, Borgar, et al. (author) Elemental carbon deposition to Svalbard snow from Norwegian settlements and long-range transport 2011 In: Tellus. Series B, Chemical and physical meteorology. - : Stockholm University Press. - 0280-6509 .- 1600-0889. ; 63:3, s. 340-351 Journal article (peer-reviewed)abstract The impact on snow pack albedo from local elemental carbon (EC) sources in Svalbard has been investigated for the winter of 2008. Highly elevated EC concentrations in the snow are observed around the settlements of Longyearbyen and Svea (locally > 1000 ng g(-1), about 200 times over the background level), while EC concentrations similar to the background level are seen around Ny-Alesund. Near Longyearbyen and Svea, darkened snow influenced by wind transported coal dust from open coal stockpiles is clearly visible from satellite images and by eye at the ground. As a first estimate, the reduction in snow albedo caused by local EC pollution from the Norwegian settlements has been compared to the estimated reduction caused by long-range transported EC for entire Svalbard. The effect of local EC from Longyearbyen, Svea and all Norwegian settlements are estimated to 2.1%, 7.9% and 10% of the total impact of EC, respectively. The EC particles tend to stay on the surface during melting, and elevated EC concentrations due to the spring melt was observed. This accumulation of EC enhances the positive albedo feedbacks. The EC concentrations were observed to be larger in metamorphosed snow than in fresh snow, and especially around ice lenses.
10.	Coz Diego, Esther, et al. (author) Morphology and state of mixture of atmospheric soot aggregates during the winter season over Southern Asia-a quantitative approach 2011 In: Tellus. Series B, Chemical and physical meteorology. - : Stockholm University Press. - 0280-6509 .- 1600-0889. ; 63:1, s. 107-116 Journal article (peer-reviewed)abstract The atmospheric brown cloud phenomena characterized by a high content of soot and a large impact on the solar radiative heating especially affects the tropical Indian Ocean during the winter season. The present study focuses on morphological characteristics and state of mixture of soot aggregates during the winter season over India. Given are quantitative measures of size, morphology and texture on aggregates collected in air at two different sites: Sinhagad near Pune in India and Hanimaadhoo in Maldives. For the latter site two different synoptic patterns prevailed: advection of air from the Arabian region and from the Indian subcontinent, respectively. Aggregates collected at Sinhagad, were associated with open branched structures, characteristic of fresh emission and diameters between 220 and 460 nm. The Hanimaadhoo aggregates were associated with aged closed structures, smaller sizes (130-360 nm) and frequently contained inorganic inclusions. Those arriving from the Indian subcontinent were characterized by the presence of an additional organic layer that covered the aggregate structure. These organic coatings might be a reasonable explanation of the low average wash-out ratios of soot two to seven times lower than that of nss-SO(4)2- that have been reported for air flow arriving at Hanimaadhoo from the Indian subcontinent in winter.
11.	Mårtensson, E. Monica, et al. (author) The role of sea-salt emissions in controlling the marine Aitken and accumulation mode aerosol : a model study 2010 In: Tellus. Series B, Chemical and physical meteorology. - : Stockholm University Press. - 0280-6509 .- 1600-0889. ; 62:4, s. 259-279 Journal article (peer-reviewed)abstract The remote marine aerosol and the cloud droplet number concentration (CDNC) are examined with an aerosol microphysics box model in an attempt to better understand the processes involved in the formation and transformation of the marine aerosol. Emission of submicrometre sea-salt and dimethylsulfide (DMS) have been included together with aerosol dynamics, gas and liquid phase chemistry and cloud processing representative for the marine boundary layer atmosphere. Our simulations are able to reproduce a bimodal submicrometre size distribution with realistic number concentrations even when new particle formation by nucleation is neglected. This indicates that ultrafine primary sea-salt flux is an important source of Aitken mode particles and CDNC. However, sulphate still constitutes 20-80% of the Aitken and accumulation mode masses. The temperature dependence of the sea-salt source function leads to a 23% decrease in total number concentration when the temperature increases from 12 to 20 degrees C. The influence of DMS emission on the aerosol and CDNC is minimal but the size distribution and mass concentration of sulphate is changed, mostly due to in-cloud processes. The wind speed is the dominant factor determining the CDNC, although entrainment of aerosols from free troposphere can have a substantial effect.
12.	Omstedt, Anders, 1949, et al. (author) Factors influencing the acid–base (pH) balance in the Baltic Sea: a sensitivity analysis 2010 In: Tellus B. - : Stockholm University Press. - 0280-6509 .- 1600-0889. ; 62:4, s. 280-295 Journal article (peer-reviewed)abstract Using calculations based on the marine carbon system and on modelling, the sensitivity of Baltic Sea surface pH was examined. Transient long-term calculations demonstrated that the marine carbon system adjusts to lateral boundary conditions within some decades, as does salinity. Climate changes in temperature or salinity will only marginally affect the acid–base (pH) balance. Wetter or dryer climate will also play a minor role in the pH balance. The direct effect on seawater pH of acid precipitation over the Baltic Sea surface was demonstrated to be small. Acidification due to river transport of dissolved organic carbon (DOC) into the marine system seems marginal although mineralization of terrestrial DOC may cause extra marine acidification, but the effect has yet to be quantified. Increased nutrient load may increase the amplitude in the pH seasonal cycle and increase the acidification during winter time. Fossil fuel burning is likely to have both a direct and indirect effect through increased CO2 levels, altering seawater pH as well as changing the river chemistry. This may severely threaten some species in the Baltic Sea, particularly in the Northern Baltic.
13.	Björkman, Mats P., et al. (author) Nitrate dry deposition in svalbard 2013 In: Tellus. Series B, Chemical and physical meteorology. - : Stockholm University Press. - 0280-6509 .- 1600-0889. ; 65, s. 19071- Journal article (peer-reviewed)abstract Arctic regions are generally nutrient limited, receiving an extensive part of their bio-available nitrogen from the deposition of atmospheric reactive nitrogen. Reactive nitrogen oxides, as nitric acid (HNO3) and nitrate aerosols (p-NO3), can either be washed out from the atmosphere by precipitation or dry deposited, dissolving to nitrate (NO3-). During winter, NO3- is accumulated in the snowpack and released as a pulse during spring melt. Quantification of NO3- deposition is essential to assess impacts on Arctic terrestrial ecology and for ice core interpretations. However, the individual importance of wet and dry deposition is poorly quantified in the high Arctic regions where in-situ measurements are demanding. In this study, three different methods are employed to quantify NO3- dry deposition around the atmospheric and ecosystem monitoring site, Ny-Alesund, Svalbard, for the winter season (September 2009 to May 2010): (1) A snow tray sampling approach indicates a dry deposition of -10.27 +/- 3.84 mg m(-2) (+/- S.E.); (2) A glacial sampling approach yielded somewhat higher values -30.68 +/- 12.00 mg m(-2); and (3) Dry deposition was also modelled for HNO3 and p-NO3 using atmospheric concentrations and stability observations, resulting in a total combined nitrate dry deposition of -10.76 +/- 1.26 mg m(-2). The model indicates that deposition primarily occurs via HNO3 with only a minor contribution by p-NO3. Modelled median deposition velocities largely explain this difference: 0.63 cm s(-1) for HNO3 while p-NO3 was 0.0025 and 0.16 cm s(-1) for particle sizes 0.7 and 7 mm, respectively. Overall, the three methods are within two standard errors agreement, attributing an average 14% (total range of 2-44%) of the total nitrate deposition to dry deposition. Dry deposition events were identified in association with elevated atmospheric concentrations, corroborating recent studies that identified episodes of rapid pollution transport and deposition to the Arctic.
14.	Fleischer, Siegfried, 1938-, et al. (author) Dark oxidation of water in soils 2013 In: Tellus. Series B, Chemical and physical meteorology. - Hoboken, NJ : Wiley-Blackwell. - 0280-6509 .- 1600-0889. ; 65:1 Journal article (peer-reviewed)abstract We report the release of oxygen (O2) under dark conditions in aerobic soils. This unexpected process is hidden by respiration which constitutes the dominating reversal O2 flux. By using H218O in different soils, we confirmed that 16O18O and 18O2 released under dark soil conditions originated from added H218O. Water is the only large-scale source of electrons for reduction of CO2 in soils, but it has not been considered as an electron donor because of the very strong oxidation system needed. A high share of soil inorganic material seems to favor the release of O2. © 2013 S. Fleischer et al.
15.	Friberg, Johan, et al. (author) Sources of increase in lowermost stratospheric sulphurous and carbonaceous aerosol background concentrations during 1999-2008 derived from CARIBIC flights 2014 In: Tellus. Series B: Chemical and Physical Meteorology. - : Stockholm University Press. - 0280-6509 .- 1600-0889. Journal article (peer-reviewed)abstract This study focuses on sulphurous and carbonaceous aerosol, the major constituents of particulate matter in the lowermost stratosphere (LMS), based on in situ measurements from 1999 to 2008. Aerosol particles in the size range of 0.082 mm were collected monthly during intercontinental flights with the CARIBIC passenger aircraft, presenting the first long-term study on carbonaceous aerosol in the LMS. Elemental concentrations were derived via subsequent laboratory-based ion beam analysis. The stoichiometry indicates that the sulphurous fraction is sulphate, while an O/C ratio of 0.2 indicates that the carbonaceous aerosol is organic. The concentration of the carbonaceous component corresponded on average to approximately 25% of that of the sulphurous, and could not be explained by forest fires or biomass burning, since the average mass ratio of Fe to K was 16 times higher than typical ratios in effluents from biomass burning. The data reveal increasing concentrations of particulate sulphur and carbon with a doubling of particulate sulphur from 1999 to 2008 in the northern hemisphere LMS. Periods of elevated concentrations of particulate sulphur in the LMS are linked to downward transport of aerosol from higher altitudes, using ozone as a tracer for stratospheric air. Tropical volcanic eruptions penetrating the tropical tropopause are identified as the likely cause of the particulate sulphur and carbon increase in the LMS, where entrainment of lower tropospheric air into volcanic jets and plumes could be the cause of the carbon increase.
16.	Hieronymus, Jenny, 1981-, et al. (author) Unravelling the land source : an investigation of the processes contributing to the oceanic input of DIC and alkalinity 2013 In: Tellus. Series B, Chemical and physical meteorology. - : Stockholm University Press. - 0280-6509 .- 1600-0889. ; 65, s. 19683- Journal article (peer-reviewed)abstract In models of the marine carbon system, it is important to correctly represent riverine and aerial inputs of dissolved inorganic carbon (DIC) and alkalinity. We have examined the different processes contributing to this exchange. In terms of DIC, we have divided the fluxes into their internal component, constituting the carbon ultimately derived from the atmosphere, and their external component originating from rocks. We find that the only process contributing to external DIC input is carbonate and fossil carbon weathering and that erosion of organic matter ultimately constitutes a DIC sink. A number of both riverine and aerial inputs affect the alkalinity. Beside carbonate and silicate weathering, we examine processes of pyrite weathering, aerial input of sulphuric acid, and riverine and aerial inputs of various nitrogen species. Using the observation that, in the ocean, the nitrate concentration follows that of phosphate, we assume a steady state in nitrate. This leads to the surprising result that the only processes affecting the alkalinity is riverine input of nitrate, constituting an alkalinity source and input of ammonia, constituting an alkalinity sink. Furthermore, we compare the flux sizes. As expected, carbonate and silicate weathering has the largest effect on alkalinity, though we note that burial of pyrite might be of importance during periods of large-scale anoxia.
17.	Horst, Axel, et al. (author) Stable bromine isotopic composition of atmospheric CH3Br 2013 In: Tellus. Series B, Chemical and physical meteorology. - : Stockholm University Press. - 0280-6509 .- 1600-0889. ; 65, s. 21040- Journal article (peer-reviewed)abstract Tropospheric methyl bromide (CH3Br) is the largest source of bromine to the stratosphere and plays an important role in ozone depletion. Here, the first stable bromine isotope composition (delta Br-81) of atmospheric CH3Br is presented. The delta Br-81 of higher concentration Stockholm samples and free air subarctic Abisko samples suggest a source/background value of -0.04 +/- 0.28 parts per thousand ranging up to +1.75 +/- 0.12 parts per thousand. The Stockholm delta Br-81 versus concentration relationship corresponds to an apparent isotope enrichment factor of -4.7 +/- 3.7 parts per thousand, representing the combined reaction sink. This study demonstrates the scientific potential of atmospheric delta Br-81 measurements, which in the future may be combined with other isotope systems in a top-down inverse approach to further understand key source and sink processes of methyl bromide.
18.	Iizuka, Yoshinori, et al. (author) Sulphate and chloride aerosols during Holocene and last glacial periods preserved in the Talos Dome Ice Core, a peripheral region of Antarctica 2013 In: Tellus. Series B, Chemical and physical meteorology. - Stokcholm : Stockholm University Press. - 0280-6509 .- 1600-0889. ; 65, s. 20197- Journal article (peer-reviewed)abstract Antarctic ice cores preserve the record of past aerosols, an important proxy of past atmospheric chemistry. Here we present the aerosol compositions of sulphate and chloride particles in the Talos Dome (TD) ice core from the Holocene and Last Glacial Period. We find that the main salt types of both periods are NaCl, Na2SO4 and CaSO4, indicating that TD ice contains relatively abundant sea salt (NaCl) from marine primary particles. By evaluating the molar ratio of NaCl to Na2SO4, we show that about half of the sea salt does not undergo sulphatisation during late Holocene. Compared to in inland Antarctica, the lower sulphatisation rate at TD is probably due to relatively little contact between sea salt and sulphuric acid. This low contact rate can be related to a reduced time of reaction for marine-sourced aerosol before reaching TD and/or to a reduced post-depositional effect from the higher accumulation rate at TD. Many sulphate and chloride salts are adhered to silicate minerals. The ratio of sulphate-adhered mineral to particle mass and the corresponding ratio of chloride-adhered mineral both increase with increasing dust concentration. Also, the TD ice appears to contain Ca(NO3)(2) or CaCO3 particles, thus differing from aerosol compositions in inland Antarctica, and indicating the proximity of peripheral regions to marine aerosols.
19.	Karl, Matthias, et al. (author) A study of new particle formation in the marine boundary layer over the central Arctic Ocean using a flexible multicomponent aerosol dynamic model 2012 In: Tellus. Series B, Chemical and physical meteorology. - : Stockholm University Press. - 0280-6509 .- 1600-0889. ; 64, s. 17158- Journal article (peer-reviewed)abstract Enhancement of number concentrations of particles with sizes less than 25 nm diameter has been frequently observed in the boundary layer over the central Arctic Ocean during summer. The sectional aerosol dynamics model for Marine Aerosol Formation (MAFOR) was applied to evaluate the capability of different nucleation mechanisms to reproduce nucleation events observed during three expeditions (1996, 2001 and 2008) onboard the Swedish icebreaker Oden. Model calculations suggest that a source rate of a condensable organic vapour (OV) of about 2 x 10(5) cm(-3) s(-1) is required to reproduce observed growth of nucleation mode particles. Nucleation rates predicted by the newly proposed combined sulphuric acid nucleation mechanism, which best described new particle formation in the Arctic, ranged from 0.04 to 0.1 cm(-3) s(-1). This mechanism additively combines ion-mediated nucleation and cluster activation, and treats condensation of OV without correction of the Kelvin effect. In several events, the simultaneous number enhancement of particles in the 20-50 nm size range remained unexplained by the nucleation mechanisms. This lends support to alternative theories such as the fragmentation of marine gels (approximate to 200-500 nm diameter in size) by physical or chemical processes.
20.	Krecl, Patricia, et al. (author) A feasibility study of mapping light-absorbing carbon using a taxi fleet as a mobile platform 2014 In: Tellus. Series B, Chemical and physical meteorology. - : Stockholm University Press. - 0280-6509 .- 1600-0889. ; 66, s. 23533- Journal article (peer-reviewed)abstract Carbon-containing particles are associated with adverse health effects, and their light-absorbing fractions were recently estimated to be the second largest contributor to global warming after carbon dioxide. Knowledge on the spatiotemporal variability of light-absorbing carbon (LAC) particles in urban areas is relevant for air quality management and to better diagnose the population exposure to these particles. This work reports on the first mobile LAC mass concentrations (M-LAC) measured on-board four taxis in the Stockholm metropolitan area in November 2011. On average, concentrations were higher and more variable during daytime (median of 1.9 mu g m(-3) and median absolute deviation of 2.3 mu g m(-3)). Night-time (21:00-05:00) measurements were very similar for all road types and also compared to levels monitored at an urban background fixed site (median of 0.9 mu g m(-3)). We observed a large intra-urban variability in concentrations, with maxima levels inside road tunnels (median and 95th percentile of 7.5 and 40.1 mu g m(-3), respectively). Highways presented the second ranked concentrations (median and 95th percentile of 3.2 and 9.7 mu g m(-3), respectively) associated with highest vehicle speed (median of 65 km h(-1)), traffic rates (median of 62 000 vehicles day(-1) and 1500 vehicles h(-1)) and diesel vehicles share (7-10%) when compared to main roads, canyon streets, and local roads. Multiple regression modelling identified hourly traffic rate and M-LAC concentration measured at an urban background site as the best predictors of on-road concentrations, but explained only 25% of the observed variability. This feasibility study proved to be a time-and cost-effective approach to map out ambient M-LAC concentrations in Stockholm and more research is required to represent the distribution in other periods of the year. Simultaneous monitoring of other pollutants, closely correlated to M-LAC levels in traffic-polluted environments, and including video recording of road and traffic changes would be an asset.
21.	Li, Xin, et al. (author) Cloud droplet activation mechanisms of amino acid aerosol particles : insight from molecular dynamics simulations 2013 In: Tellus. Series B, Chemical and physical meteorology. - : Stockholm University Press. - 0280-6509 .- 1600-0889. ; 65, s. 65- Journal article (peer-reviewed)abstract Atmospheric amino acids constitute a large fraction of water-soluble organic nitrogen compounds in aerosol particles, and have been confirmed as effective cloud condensation nuclei (CCN) materials in laboratory experiments. We present a molecular dynamics (MD) study of six amino acids with different structures and chemical properties that are relevant to the remote marine atmospheric aerosol-cloud system, with the aim of investigating the detailed mechanism of their induced changes in surface activity and surface tension, which are important properties for cloud drop activation. Distributions and orientations of the amino acid molecules are studied; these L-amino acids are serine (SER), glycine (GLY), alanine (ALA), valine (VAL), methionine (MET) and phenylalanine (PHE) and are categorised as hydrophilic and amphiphilic according to their affinities to water. The results suggest that the presence of surface-concentrated amphiphilic amino acid molecules give rise to enhanced Lennard-Jones repulsion, which in turn results in decreased surface tension of a planar interface and an increased surface tension of the spherical interface of droplets with diameters below 10 nm. The observed surface tension perturbation for the different amino acids under study not only serves as benchmark for future studies of more complex systems, but also shows that amphiphilic amino acids are surface active. The MD simulations used in this study reproduce experimental results of surface tension measurements for planar interfaces and the method is therefore applicable for spherical interfaces of nano-size for which experimental measurements are not possible to conduct.
22.	Lund, Magnus, et al. (author) Characteristics of summer-time energy exchange in a high Arctic tundra heath 2000-2010 2014 In: Tellus. Series B: Chemical and Physical Meteorology. - : Stockholm University Press. - 0280-6509 .- 1600-0889. ; 66 Journal article (peer-reviewed)abstract Global warming will bring about changes in surface energy balance of Arctic ecosystems, which will have implications for ecosystem structure and functioning, as well as for climate system feedback mechanisms. In this study, we present a unique, long-term (2000-2010) record of summer-time energy balance components (net radiation, R-n; sensible heat flux, H; latent heat flux, LE; and soil heat flux, G) from a high Arctic tundra heath in Zackenberg, Northeast Greenland. This area has been subjected to strong summer-time warming with increasing active layer depths (ALD) during the last decades. We observe high energy partitioning into H, low partitioning into LE and high Bowen ratio (beta = H/LE) compared with other Arctic sites, associated with local climatic conditions dominated by onshore winds, slender vegetation with low transpiration activity and relatively dry soils. Surface saturation vapour pressure deficit (D-s) was found to be an important variable controlling within-year surface energy partitioning. Throughout the study period, we observe increasing H/R-n and LE/R-n and decreasing G/R-n and beta, related to increasing ALD and decreasing soil wetness. Thus, changes in summer-time surface energy balance partitioning in Arctic ecosystems may be of importance for the climate system.
23.	Moberg, Anders, 1961- (author) Comparisons of simulated and observed Northern Hemisphere temperature variations during the past millennium - selected lessons learned and problems encountered 2013 In: Tellus. Series B, Chemical and physical meteorology. - : Stockholm University Press. - 0280-6509 .- 1600-0889. ; 65, s. 19921- Journal article (peer-reviewed)abstract Comparison of simulated and reconstructed past climate variability within the last millennium provides an opportunity to aid the understanding and interpretation of palaeoclimate proxy data and to test hypotheses regarding external forcings, feedback mechanisms and internal climate variability under conditions close to those of the present day. Most such comparisons have been made at the Northern Hemispheric scale, of which a selection of recent results is briefly discussed here. Uncertainties in climate and forcing reconstructions, along with the simplified representations of the true climate system represented by climate models, limit our possibility to draw certain conclusions regarding the nature of forced and unforced climate variability. Additionally, hemispheric-scale temperature variations have been comparatively small, wherefore the last millennium is apparently not a particularly useful period for estimating climate sensitivity. Nevertheless, several investigators have concluded that Northern Hemispheric-scale decadal-mean temperatures in the last millennium show a significant influence from natural external forcing, where volcanic forcing is significantly detectable while solar forcing is less robustly detected. The amplitude of centennial-scale variations in solar forcing has been a subject for much debate, but current understanding of solar physics implies that these variations have been small – similar in magnitude to those within recent sunspot cycles – and thus they have not been a main driver of climate in the last millennium. This interpretation is supported by various comparisons between forced climate model simulations and temperature proxy data. Anthropogenic greenhouse gas and aerosol forcing has been detected by the end of Northern Hemispheric temperature reconstructions.
24.	Norman, Maria, 1973-, et al. (author) Influence of Coastal Upwelling on the Air-Sea Gas Exchange of CO2 in a Baltic Sea Basin 2013 In: Tellus. Series B, Chemical and physical meteorology. - : Stockholm University Press. - 0280-6509 .- 1600-0889. ; 65:21831, s. 1-16 Journal article (peer-reviewed)abstract During coastal upwelling cold water from the ocean interior with high CO2 concentration is brought up to the surface, allowing this water to interact with the atmosphere. This sets the stage for events with potentially altered sea–air CO2 fluxes. Four upwelling events off the east coast of Gotland in the Baltic Sea were analyzed to assess the impact of upwelling on the air–sea exchange of CO2. For each event, the observed pCO2 were found to be a function of sea-surface temperature (SST) in the upwelling area, which allowed satellite observations of SST to form a proxy for surface water pCO2. A bulk formula was then used to estimate the air–sea CO2 flux during the upwelling events. The results show that the CO2 fluxes in the study area are highly influenced by the upwelling. Comparing with idealized cases without upwelling yields relatively large differences, ranging between 19 and 250% in reduced uptake/increased emission of CO2. Upwelling may also influence the CO2 fluxes on larger scales. A rough estimate indicates that it may also be of significant importance for the average annual CO2 flux from the Baltic Sea. Including upwelling possibly decreases the Baltic Sea annual average uptake by up to 25%.
25.	Omstedt, Anders, 1949, et al. (author) Future changes in the Baltic Sea acid-base (pH) and oxygen balances 2012 In: Tellus. Series B, Chemical and physical meteorology. - : Stockholm University Press. - 0280-6509 .- 1600-0889. ; 64 Journal article (peer-reviewed)abstract Possible future changes in Baltic Sea acid–base (pH) and oxygen balances were studied using a catchment–sea coupled model system and numerical experiments based on meteorological and hydrological forcing datasets and scenarios. By using objective statistical methods, climate runs for present climate conditions were examined and evaluated using Baltic Sea modelling. The results indicate that increased nutrient loads will not inhibit future Baltic Sea acidification; instead, the seasonal pH cycle will be amplified by increased biological production and mineralization. All examined scenarios indicate future acidification of the whole Baltic Sea that is insensitive to the chosen global climate model. The main factor controlling the direction and magnitude of future pH changes is atmospheric CO2 concentration (i.e. emissions). Climate change and land-derived changes (e.g. nutrient loads) affect acidification mainly by altering the seasonal cycle and deep-water conditions. Apart from decreasing pH, we also project a decreased saturation state of calcium carbonate, decreased respiration index, and increasing hypoxic area – all factors that will threaten the marine ecosystem. We demonstrate that substantial reductions in fossil-fuel burning are needed to minimize the coming pH decrease and substantial reductions in nutrient loads are needed to reduce the coming increase in hypoxic and anoxic waters.

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