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Search: WFRF:(Hedberg Mikael) > (2000-2004)

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1.
  • Hedberg, Bo, et al. (author)
  • Learning in imaginary organizations
  • 2001
  • In: Handbook of organizational learning and knowledge. - Oxford : Oxford University Press. - 0198295839 - 0198295820 ; , s. 733-752
  • Book chapter (peer-reviewed)
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  • Hedberg, Linda, et al. (author)
  • Scattered Hammond plots reveal second level of site-specific information in protein folding: ′ (β‡)
  • 2004
  • In: Proceedings of the National Academy of Sciences of the United States of America PNAS. - : Proceedings of the National Academy of Sciences. ; 101:20, s. 7606–11-
  • Journal article (peer-reviewed)abstract
    • Site-specific information about structural heterogeneities of the protein-folding transition-state ensemble is commonly derived from the scatter of the Brønsted plot through the individual values of = Δlogkf/ΔlogKD-N. Here, we provide a second level of site-specific detail in the transition-state analysis by demonstrating that the scatter of the Hammond plot is related to heterogeneities in the -value growth. That is, the extent of transition-state movement (Δβ‡) is proportional to the free-energy gradient of the mutational perturbation across the top of the activation barrier, ′(β‡) ΔlogKD-N. The analysis is applied to the two-state protein L23 where the site-specific free-energy gradients are used to identify the interactions that show the highest degree of consolidation after crossing the barrier top. These interactions are distributed as a shell around the high- initiation point and denote the side-chain contacts that add criticality to the folding nucleus.
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