| 1. |
- Bose, Swayoma, et al.
(author)
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Zircon U Pb and Hf isotope insights into the Mesoproterozoic breakup of supercontinent Columbia from the Sausar Belt, Central Indian Tectonic Zone
- 2023
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In: Chemie der Erde. - : Elsevier. - 0009-2819 .- 1611-5864. ; , s. 126054-126054
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Journal article (peer-reviewed)abstract
- Credible records of rifting and associated sedimentation and granitoid magmatism coinciding with the Columbia breakup event are not common in the Precambrian Indian continent. We report a 1322 ± 3 Ma concordia age for magmatic zircons from the granitoid rocks of the Sausar mobile belt, Central Indian Tectonic Zone (CITZ). The rocks exhibit geochemical characteristics of A-type granitoid rocks and were generated by the dehydration melting of shallow crust in an extensional tectonic setting. The predominantly negative εHf(t) values and partial melting modelling imply their origin by the reworking of pre-existing granitoid crust. TDM2 (Hf) model ages for these rocks range from 2856 Ma to 1885 Ma suggesting a prolonged period of crustal evolution and reworking of Archean to Paleoproterozoic basement rocks. The temperature for magma generation, determined from the calculated zircon saturation temperature of 874.2 °C is suggestive of melting of a thinned crust that was heated by the upwelling asthenosphere in an extensional tectonic setting. The obtained ages provide evidence for the existence of an extensional event during mid-Mesoproterozoic coinciding with the Columbia breakup event. The extension could also be argued as a local event related to far-field stresses generated due to the ca. 1.6 to 1.5 Ga subduction-collision event at the plate margin farther to the north of the studied region of the CITZ. The recrystallized margins of zircon grains yield 207Pb/206Pb ages between 0.95 Ga and 1.0 Ga implying their alteration during a metamorphic event that can be identified with the final amalgamation and stabilization of the northern and southern Indian blocks along the CITZ, coinciding with the Rodinia assembly, during which the regional structural fabric developed.
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| 2. |
- Callegari, Riccardo, et al.
(author)
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Early Neoproterozoic magmatism and Caledonian metamorphism recorded by the Mårma terrane, Seve Nappe Complex, northern Swedish Caledonides
- 2023
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In: Journal of the Geological Society. - : Geological Society of London. - 0016-7649 .- 2041-479X. ; 180:5
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Journal article (peer-reviewed)abstract
- Petrology, geochronology and bulk-rock chemistry are combined to investigate the early Neoproterozoic magmatismand Cambrian–Ordovician metamorphism in the northern Swedish Caledonides. This work includes several lithologies of theMårma terrane in the Seve Nappe Complex exposed in the Kebnekaise region. U–Pb zircon geochronology yielded crystallizationages of 835 ± 8 Ma for a mylonitic orthogneiss, 864 ± 3 Ma for the Vistas Granite and 840 ± 7 Ma for an intruded granitic dyke,whereas a gabbro and a granodiorite intrusion gave U–Pb zircon crystallization ages of 856 ± 3 Ma and 850 ± 1 Ma, respectively.U–Pb monazite dating of the mylonitic orthogneiss gave an upper intercept age of 841 ± 7 Ma and a lower intercept age of443 ± 20 Ma. Pressure–temperature estimates derived for the mylonitic orthogneiss reveal metamorphic peak-pressure and peaktemperatureof 10.5–11.75 kbar and 550–610°C and 7.4–8.1 kbar at 615–675°C, respectively.Metamorphic pressure–temperatureestimates for the Vistas Granite yield 6.5–7.5 kbar at 600–625°C. Whole-rock chemistry coupled with U–Pb geochronologyindicates that bimodal magmatism was related to attempted rifting of Rodinia between 870 and 840 Ma.
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| 3. |
- Carter, Isabel S. M., et al.
(author)
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Cambrian ages for metavolcanic rocks in the Lower Köli Nappes, Swedish Caledonides: implications for the status of the Virisen arc terrane
- 2023
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In: Journal of the Geological Society. - : Geological Society of London. - 0016-7649 .- 2041-479X. ; 180:6
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Journal article (peer-reviewed)abstract
- The Köli Nappe Complex (KNC) of the Scandinavian Caledonide orogen originated as oceanic terranes within the Iapetus Ocean. These terranes have characteristics of magmatic arcs and associated forearc or back-arc basins and underwent several periods of rifting and magmatism prior to their accretion to the Baltican margin. We present new U–Pb zircon ages from the Lower Köli Ankarede Volcanite Formation in Västerbotten, Sweden. U–Pb ages of magmatic zircon grains from metamorphosed dacitic to andesitic rocks show ages of 512 ± 3.5, 497 ± 2, 491 ± 1 and 488 ± 4 Ma. The three younger ages fit with previous ages for Lower Köli volcanic rocks, but the 512 Ma age is older than any previous age for this unit. These dates constrain the age of magmatism in an ensimatic arc system within Iapetus. We compare this evolution with published information from the other Köli nappes. Magmatic ages within the KNC overlap with ages for an early episode of ultrahigh-pressure (UHP) metamorphism within the underlying Seve Nappe Complex (SNC), supporting the hypothesis that attributes UHP metamorphism within the SNC to subduction beneath the island arc now preserved within the Lower Köli Nappes.
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| 4. |
- Chatterjee, Sukalpa, et al.
(author)
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The Singhbhum Craton (India) records a billion year of continental crust formation and modification
- 2023
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In: Chemical Geology. - : Elsevier. - 0009-2541 .- 1872-6836. ; 641, s. 121772-121772
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Journal article (peer-reviewed)abstract
- The petrogenesis of continental crust from its ultimate mantle source can be reconstructed from the element abundances and radiogenic isotope compositions of ideally pristine igneous rocks. The initial isotope compositions of igneous rocks provide geochemical constraints on the age, composition and evolution of their source(s). Determining initial isotope ratios for rock samples can be challenging, especially in rocks with a long and protracted thermal history. The Rb-Sr system is highly sensitive to parent-daughter element fractionation during magma differentiation. This makes the Rb-Sr isotope systematics ideal to trace the precursor composition of Archean felsic crust and constrain the time of element fractionation during the formation and subsequent modification of continental crust. Initial isotope compositions can be obtained directly from minerals that strongly prefer the daughter element and effectively exclude the parent element of the radio-isotope system of interest. Apatite, having a near zero Rb/Sr ratio, is ideal for preserving its initial 87Sr/86Sr and zircon records initial 176Hf/177Hf compositions. Combined modelling of Sr and Hf isotope data from granitoids of the Archean Singhbhum Craton, indicates that the older Paleoarchean granitoids, emplaced between 3.53 Ga and 3.44 Ga, were derived from a mafic precursor (∼52–54 wt% SiO2) sourced from a depleted mantle at ∼3.71 Ga. Initial 87Sr/86Sr isotope signatures of matrix apatite and apatite inclusions in zircon from the younger Paleoarchean granitoids (3.4–3.2 Ga) of the Singhbhum Craton indicate these younger granitoids were produced by mixing of magma generated from an older mafic source and partial melts derived from the older granitoids. The combined Sr-Hf isotope modelling links the timing of mantle extraction of the precursor material for Paleoarchean Singhbhum granitoids with a known mafic crust extraction event at ∼3.71 Ga. In combination, the new Sr isotope data from apatite combined with whole rock and zircon Hf isotope data from the literature reveal a ∼1 Ga protracted crustal growth and differentiation history of the nucleus of the Singhbhum Craton. By combining radio-isotope systems like 87Rb-87Sr and 176Lu-176Hf, the petrogenesis of Archean felsic crust from the extraction of mafic material from the mantle to reworking in an orogenic cycle to emplacement can be reconstructed. This approach can be applied to other greenstone-gneiss terranes to quantify the spatio-temporal and compositional evolution of voluminous felsic crust and the formation of cratons in the Archean.
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| 5. |
- Drake, Henrik, Docent, 1979-, et al.
(author)
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In Situ Rb/Sr Geochronology and Stable Isotope Geochemistry Evidence for Neoproterozoic and Paleozoic Fracture-Hosted Fluid Flow and Microbial Activity in Paleoproterozoic Basement, SW Sweden
- 2023
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In: Geochemistry Geophysics Geosystems. - : American Geophysical Union (AGU). - 1525-2027. ; 24:5
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Journal article (peer-reviewed)abstract
- Recent studies have shown that biosignatures of ancient microbial life exist in mineral coatings in deep bedrock fractures of Precambrian cratons, but such surveys have been few and far between. Here, we report results from southwestern Sweden in an area of 1.6-1.5 Ga Paleoproterozoic rocks heavily reworked by the 1.14-0.96 Ga Sveconorwegian orogeny, a terrane previously scarcely explored for ancient microbial biosignatures. Calcite-pyrite-adularia-illite-coated fractures were analyzed for stable isotopes via Secondary Ion Mass Spectrometry (delta C-13, delta O-18, delta S-34) and in situ Rb/Sr geochronology via Laser-ablation inductively coupled plasma mass spectrometry. The Rb/Sr ages for calcite-adularia and calcite-illite show that several fluid flow events can be discerned (797 +/- 18-769 +/- 7, 391 +/- 5-387 +/- 6, 356 +/- 5-347 +/- 4, and 301 +/- 7 Ma). The delta C-13, delta O-18 and Sr-87/Sr-86 values of different calcite growth zones further confirmed episodic fluid flow. Pyrite delta S-34 values down to -49.9% V-CDT, together with systematically increased delta S-34 from crystal core to rim, suggest formation following microbial sulfate reduction under semi-closed conditions. Assemblages involving MSR-related pyrite generally have Devonian to Permian Rb/Sr ages, indicating an association to extension-related fracturing and fluid mixing during foreland-basin formation linked to Caledonian orogeny in the northwest. An assemblage with an age of 301 +/- 7 Ma is potentially related to Oslo Rift extension, whereas the Neo-Proterozoic ages relate to post-Sveconorwegian extensional tectonics. Remnants of short-chained fatty acids in the youngest calcite coatings further indicate a biogenic origin, while the absence of organic molecules in older calcite is in line with thermal degradation, potentially related to heating during Caledonian foreland basin burial. Plain Language Summary This study investigates mineral coatings in Proterozoic basement fractures of Southwestern Sweden, within the Precambrian Fennoscandian shield, to gain insights into ancient microbial life and paleo-fluid flow. Isotopic signatures of these mineral coatings suggest that microbial sulfate reducers have been present in the system as also indicated by preserved organic molecules. Microanalytical geochronology determinations reveal that the fracture system has been activated several times in the Neoproterozoic, Devonian-Early Carboniferous, and Late Carboniferous/Early Permian. These activations are associated with extension events following the Sveconorwegian and Caledonian orogenies as well as formation of the Oslo Rift. The signs of microbial activity are related to the youngest of these events, post-dating burial in the Caledonian foreland basin, when bedrock temperatures became habitable.
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| 6. |
- Henriksson, Jens, et al.
(author)
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Fe-O isotope systematics and magnetite chemistry of the Malmberget iron-oxide apatite deposit, Sweden
- 2023
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In: Proceedings of the 17th SGA Biennial Meeting. - : The Society for Geology Applied to Mineral Deposits (SGA). - 9782839940443 ; , s. 354-357
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Conference paper (peer-reviewed)abstract
- Fe-O isotopes from drill core samples and whole rock chemistry from massive magnetite in LKAB's geochemical database have been used to unravel the origin, affinity, and stratigraphic position of the ore bodies in the Malmberget iron-oxide apatite deposit. Fe-O isotopes suggest a magmatic to magmatic-hydrothermal origin of the Malmberget deposit. Seven distinct magnetite populations have been identified using a novel Fe/V versus V/Ti magnetite discrimination diagram. Six of the magnetite populations form distinct spatio-geochemical clusters, whereas the massive magnetite data from the Fabian-Kapten ore body are scattered. Aggregated, this can be explained by a system where separate events form chemically distinct sill-type apatite-iron oxide intrusions within the volcano-sedimentary package, and repeated eruptions form a chemically scattered ore package on top.
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| 7. |
- Hirst, Catherine, 1989-, et al.
(author)
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Iron isotopes reveal seasonal variations in the mechanisms for iron-bearing particle and colloid formation in the Lena River catchment, NE Siberia
- 2023
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In: Geochimica et Cosmochimica Acta. - 0016-7037 .- 1872-9533. ; 363, s. 77-93
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Journal article (peer-reviewed)abstract
- Large Arctic rivers are an important source of iron (Fe) to the Arctic Ocean, though seasonal variations in the terrestrial source and supply of Fe to the ocean are unknown. To constrain the seasonal variability, we present Fe concentrations and isotopic compositions (δ56Fe) for particulate (>0.22 µm) and colloidal (<0.22 µm–1 kDa) Fe from the Lena River, NE Russia. Samples were collected every month during winter baseflow (September 2012–March 2013) and every 2–3 days before, during and after river ice break-up (May 2015).Iron in particles have isotope ratios lower than crustal values during winter (e.g., δ56FePart = −0.37 ± 0.16‰), and crustal-like values during river ice break-up and spring flood (e.g., δ56FePart = 0.07 ± 0.08‰), indicating a change in the source of particulate Fe between winter and spring flood. Low isotope values are indicative of mineral dissolution, transport of reduced Fe in sub-oxic, ice-covered sub-permafrost groundwaters and near-quantitative precipitation of Fe as particles. Crustal-like isotopic compositions result from the increased supply of detrital particles from riverbank and soil erosion during river ice break-up and flooding. Iron colloids (<0.22 μm) have δ56Fe values that are comparable to or lower than crustal values during winter (e.g., δ56FeCol = −0.08 ± 0.05‰) but similar to or higher than crustal values during spring flood (e.g., δ56FeCol = +0.24 ± 0.11‰). Low δ56Fe ratios for colloidal Fe during winter are consistent with precipitation from isotopically light Fe(II)aq transported in sub-permafrost groundwaters. Higher colloidal δ56Fe ratios during the spring flood indicate that these colloids are supplied from surface soils, where Fe is fractionated via oxidation or organic carbon complexation, similar to during summer. Approximately half of the annual colloidal Fe flux occurs during spring flood while most of the remaining colloidal Fe is supplied during summer months. The total amount of colloidal Fe transported during winter was relatively low. The seasonal variation in colloidal Fe isotope values may be a useful tool to trace the source of colloidal Fe to the Arctic Ocean and monitor future changes in the sources and supply of Fe from the permafrost landscape to the Lena River basin.
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| 8. |
- Mulder, Jacob, et al.
(author)
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New Reference Materials, Analytical Procedures and Data Reduction Strategies for Sr Isotope Measurements in Geological Materials by LA‐MC‐ICP‐MS
- 2023
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In: Geostandards and Geoanalytical Research. - : Wiley. - 1639-4488 .- 1751-908X. ; 47:2, s. 311-336
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Journal article (peer-reviewed)abstract
- Laser ablation multi-collector mass spectrometry (LA-MC-ICP-MS) has emerged as the technique of choice for in situ measurements of Sr isotopes in geological minerals. However, the method poses analytical challenges and there is no widely adopted standardised approach to collecting these data or correcting the numerous potential isobaric inferences. Here, we outline practical analytical procedures and data reduction strategies to help establish a consistent framework for collecting and correcting Sr isotope measurements in geological materials by LA-MC-ICP-MS. We characterise a new set of plagioclase reference materials, which are available for distribution to the community, and present a new data reduction scheme for the Iolite software package to correct isobaric interferences for different materials and analytical conditions. Our tests show that a combination of Kr-baseline subtraction, Rb-peak-stripping using βRb derived from a bracketing glass reference material, and a CaCa or CaAr correction for plagioclase and CaCa or CaAr + REE2+ correction for rock glasses, yields the most accurate and precise 87Sr/86Sr measurements for these materials. Using the analytical and correction procedures outlined herein, spot analyses using a beam diameter of 100 μm or rastering with a 50–65 μm diameter beam can readily achieve < 100 ppm 2SE repeatability ("internal") precision for 87Sr/86Sr measurements for materials with < 1000 μg g-1 Sr.
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| 9. |
- Nisson, D.M., et al.
(author)
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Hydrogeochemical and isotopic signatures elucidate deep subsurface hypersaline brine formation through radiolysis driven water-rock interaction
- 2023
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In: Geochimica et Cosmochimica Acta. - : Elsevier. - 0016-7037 .- 1872-9533. ; 340, s. 65-84
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Journal article (peer-reviewed)abstract
- Geochemical and isotopic fluid signatures from a 2.9–3.2 km deep, 45–55 °C temperature, hypersaline brine from Moab Khotsong gold and uranium mine in the Witwatersrand Basin of South Africa were combined with radiolytic and water–rock isotopic exchange models to delineate brine evolution over geologic time, and to explore brine conditions for habitability. The Moab Khotsong brines were hypersaline (Ca-Na-Cl) with 215–246 g/L TDS, and Cl− concentrations up to 4 mol/L suggesting their position as a hypersaline end-member significantly more saline than any previously sampled Witwatersrand Basin fluids. The brines revealed low DIC (∼0.266–∼1.07 mmol/L) with high (∼8.49–∼23.6 mmol/L) DOC pools, and several reduced gaseous species (up to 46 % by volume H2) despite microoxic conditions (Eh = 135–161 mV). Alpha particle radiolysis of water to H2, H2O2, and O2 along with anhydrous-silicate-to-clay alteration reactions predicted 4 mol/L Cl− brine concentration and deuterium enrichment in the fracture waters over a period > 1.00 Ga, consistent with previously reported 40Ar noble gas-derived residence times of 1.20 Ga for this system. In addition, radiolytic production of 7–26 nmol/(L × yr) H2, 3–11 nmol/(L × yr) O2, and 1–8 nmol/(L × yr) H2O2 was predicted for 1–100 g/g 238U dosage scenarios, supporting radiolysis as a significant source of H2 and oxidant species to deep brines over time that are available to a low biomass system (102–103 cells/mL). The host rock lithology was predominately Archaean quartzite, with minerals exposed on fracture surfaces that included calcite, pyrite, and chlorite. Signatures of 18Ocalcite, 13Ccalcite, Δ33Spyrite, 34Spyrite and 87Sr/86Sr obtained from secondary ion mass spectrometry (SIMS) microanalyses suggest several discrete fluid events as the basin cooled from peak greenschist conditions to equilibrium with present-day brine temperatures. The brine physiochemistry, geochemistry, and cellular abundances were significantly different from those of a younger, shallower, low salinity dolomitic fluid in the same mine, and both were different from the mine service water. These results indicate the discovery of one of few long-isolated systems that supports subsurface brine formation via extended water–rock interaction, and an example of a subsurface brine system where abiotic geochemistry may support a low biomass microbial community.
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