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Search: WFRF:(Stich M) > (2010-2014)

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  • Stich, Troy A., et al. (author)
  • Structural insights into [Co4O4(C5H5N)(4)(CH3CO2)(4)](+), a rare Co(IV)-containing cuboidal complex
  • 2013
  • In: Polyhedron. - : Elsevier BV. - 0277-5387 .- 1873-3719. ; 64:SI, s. 304-307
  • Journal article (peer-reviewed)abstract
    • We report high-frequency (up to 219 GHz) and correspondingly high-field electron paramagnetic resonance spectra and X-ray crystal structure of [Co4O4(pyridine)(4)(acetate)(4)](+) ([Co4O4(py)(4)(OAc)(4)](+)) that serves as a structural and spectroscopic model of cobalt-oxide films that are capable of oxidizing water. These results are, in large part, consistent with those from our earlier, lower-frequency study and serve to benchmark future high-field studies on paramagnetic states of the catalyst film. (C) 2013 Published by Elsevier Ltd.
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