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Search: WFRF:(Langer Thierry) > (2019)

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  • Monticelli, Serena, et al. (author)
  • Sustainable Asymmetric Organolithium Chemistry : Enantio- and Chemoselective Acylations through Recycling of Solvent, Sparteine, and Weinreb "Amine"
  • 2019
  • In: ChemSusChem. - : Wiley. - 1864-5631 .- 1864-564X. ; 12:6, s. 1147-1154
  • Journal article (peer-reviewed)abstract
    • The well-established Hoppe-Beak chemistry, which involves enantioselective generation of organolithium compounds in the presence of (-)-sparteine, was revisited and applied to unprecedented acylations with Weinreb amides to access highly enantioenriched alpha-oxyketones and cyclic alpha-aminoketones. Recycling of the sustainable solvent cyclopentyl methyl ether, sparteine, and the released Weinreb amine [HNMe(OMe)] was possible through a simple work-up procedure that enabled full recovery of these precious materials. The methodology features a robust scope and flexibility, thus allowing the enantioselective preparation of scaffolds amenable of further derivatization.
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3.
  • Troosters, Thierry, et al. (author)
  • Introduction of the harmonised respiratory physiotherapy curriculum
  • 2019
  • In: Breathe. - : European Respiratory Society (ERS). - 1810-6838 .- 2073-4735. ; 15:2, s. 110-115
  • Research review (peer-reviewed)abstract
    • Building on the core syllabus for postgraduate training in respiratory physiotherapy, published in 2014, the European Respiratory Society (ERS) respiratory physiotherapy task force has developed a harmonised and structured postgraduate curriculum for respiratory physiotherapy training. The curriculum outlines the knowledge, skills and attitudes which must be mastered by a respiratory physiotherapist working with adult or paediatric patients, together with guidance for minimal clinical exposures, and forms of learning and assessment. This article presents the rationale, methodology and content of the ERS respiratory physiotherapy curriculum. The full curriculum can be found in the supplementary material.
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