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C1s and O1s gas pha...
C1s and O1s gas phase shake-up spectra from Mo(CO)6
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- Bustad, Johnny (author)
- Högskolan i Gävle,Ämnesavdelningen för naturvetenskap
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Enkvist, C (author)
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Lunell, S (author)
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Tillborg, H (author)
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Nilsson, A (author)
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Osborne, S (author)
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Sandell, A (author)
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Martensson, N (author)
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Svensson, S (author)
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(creator_code:org_t)
- Elsevier BV, 1994
- 1994
- English.
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In: Chemical Physics. - : Elsevier BV. - 0301-0104 .- 1873-4421. ; 179:3, s. 303-312
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
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- Experimental high-resolution core photoelectron C1s and O1s shake-up spectra of molybdenum hexacarbonyl, Mo(CO)(6), are reported and compared with results of semiempirical INDO/CI calculations. Several hitherto unobserved peaks are identified and assigned. It is found that an intra- and inter-group classification can be used to describe the transitions. The transitions of lowest energy have Mo-CO inter-group character. Dynamical effects on the line widths of the experimental shake-up peaks are discussed. A discussion of the relevance of experimental results obtained for the Mo(CO)(6)e for CO adsorption on metal surfaces is presented.
Publication and Content Type
- ref (subject category)
- art (subject category)
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