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Catalytic decomposi...
Catalytic decomposition of 2% methanol in methane over metallic catalyst by fixed-bed catalytic reactor
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- Awad, A. (author)
- University of Faisalabad, PAK ; Universiti Teknologi PETRONAS, MYS
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- Ahmed, I. (author)
- National University of Science and Technology, PAK
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- Qadir, D. (author)
- Universiti Teknologi PETRONAS, MYS
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- Khan, M. S. (author)
- Texas A&M University at Qatar, QAT
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- Idris, Alamin (author)
- Karlstads universitet,Institutionen för ingenjörs- och kemivetenskaper (from 2013)
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(creator_code:org_t)
- 2021-04-16
- 2021
- English.
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In: Energies. - : MDPI. - 1996-1073. ; 14:8
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https://doi.org/10.3...
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Abstract
Subject headings
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- The structure and performance of promoted Ni/Al2O3 with Cu via thermocatalytic decomposition (TCD) of CH4 mixture (2% CH3OH) were studied. Mesoporous Cat-1 and Cat-2 were synthesized by the impregnation method. The corresponding peaks of nickel oxide and copper oxide in the XRD showed the presence of nickel and copper oxides as a mixed alloy in the calcined catalyst. Temperature program reduction (TPR) showed that Cu enhanced the reducibility of the catalyst as the peak of nickel oxide shifted toward a lower temperature due to the interaction strength of the metal particles and support. The impregnation of 10% Cu on Cat-1 drastically improved the catalytic performance and exhibited 68% CH4 conversion, and endured its activity for 6 h compared with Cat-1, which deactivated after 4 h. The investigation of the spent carbon showed that various forms of carbon were obtained as a by-product of TCD, including graphene fiber (GF), carbon nanofiber (CNF), and multi-wall carbon nanofibers (MWCNFs) on the active sites of Cat-2 and Cat-1, following various kinds of growth mechanisms. The presence of the D and G bands in the Raman spectroscopy confirmed the mixture of amorphous and crystalline morphology of the deposited carbon.
Subject headings
- TEKNIK OCH TEKNOLOGIER -- Kemiteknik -- Kemiska processer (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Chemical Engineering -- Chemical Process Engineering (hsv//eng)
Keyword
- Alloys
- Carbon nanofiber
- Catalyst
- Clean energy
- Premixed gas
- Carbon nanofibers
- Catalysts
- Copper metallography
- Impregnation
- Mixtures
- Nickel metallography
- Nickel oxide
- Catalytic decomposition
- Catalytic performance
- Crystalline morphologies
- Fixed-bed catalytic reactors
- Impregnation methods
- Interaction strength
- Structure and performance
- Thermocatalytic decomposition
- Copper oxides
- Kemiteknik
- Chemical Engineering
Publication and Content Type
- ref (subject category)
- art (subject category)
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