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How Graphene is Cut upon Oxidation?
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- Li, Zhenyu (author)
- KTH,Teoretisk kemi
-
- Zhang, Wenhua (author)
- KTH,Teoretisk kemi
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- Luo, Yi (author)
- KTH,Skolan för bioteknologi (BIO)
- show more...
- Yang, Jinlong (author)
- Hou, Jian Guo (author)
- show less...
- (creator_code:org_t)
- 2009-04-17
- 2009
- English.
- In: Journal of the American Chemical Society. - : American Chemical Society (ACS). - 0002-7863 .- 1520-5126. ; 131:18, s. 6320-6321
- Journal article (peer-reviewed)
Abstract
Subject headings
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- Our first principles calculations reveal that an oxidative cut of graphene is realized by forming epoxy and then carbonyl pairs. Direct formation of a carbonyl pair to tear graphene up from an edge position is not favorable in energy. This atomic picture is valuable for developing effective means of graphene manipulation. The proposed epoxy pairs may be related to some long puzzling experimental observations on graphene oxide.
Subject headings
- MEDICIN OCH HÄLSOVETENSKAP -- Medicinska och farmaceutiska grundvetenskaper -- Andra medicinska och farmaceutiska grundvetenskaper (hsv//swe)
- MEDICAL AND HEALTH SCIENCES -- Basic Medicine -- Other Basic Medicine (hsv//eng)
Keyword
- graphite oxides; films
- Chemistry
- Kemi
Publication and Content Type
- ref (subject category)
- art (subject category)
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- Royal Institute of Technology
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