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The protonation sta...
The protonation state and binding mode in a metal coordination complex from the charge measured in solution by electrophoretic NMR
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- Giesecke, Marianne (författare)
- KTH,Tillämpad fysikalisk kemi
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- Szabo, Zoltan (författare)
- KTH,Organisk kemi
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- Furo, Istvan (författare)
- KTH,Tillämpad fysikalisk kemi
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(creator_code:org_t)
- Royal Society of Chemistry (RSC), 2013
- 2013
- Engelska.
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Ingår i: Analytical Methods. - : Royal Society of Chemistry (RSC). - 1759-9660 .- 1759-9679. ; 5:7, s. 1648-1651
- Relaterad länk:
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https://doi.org/10.1...
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https://pubs.rsc.org...
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- We measured with high accuracy the effective charge of a uranium (VI)-AMP complex by electrophoretic NMR (eNMR). Using the same method, the degree of counterion association is also assessed which leads to a quantitative determination of the nominal charge which then provides the degree of ligand deprotonation in the complex. This demonstrates a new application of eNMR for resolving structural details of supramolecular complexes.
Ämnesord
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Nyckelord
- Multinuclear Nmr
- Stability-Constants
- Uranyl Acetate
- Ions
- Polyelectrolytes
- Nucleotides
- Uranium
- Cells
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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