SwePub
Sök i LIBRIS databas

  Extended search

onr:"swepub:oai:DiVA.org:kth-12851"
 

Search: onr:"swepub:oai:DiVA.org:kth-12851" > Self-adaptable Cata...

  • 1 of 1
  • Previous record
  • Next record
  •    To hitlist
  • Zalubovskis, RaivisKTH,Organisk kemi,Christina Moberg (author)

Self-adaptable Catalysts : Substrate-Dependent Ligand Configuration

  • Article/chapterEnglish2008

Publisher, publication year, extent ...

  • 2008-01-17
  • Washington DC :American Chemical Society,2008
  • printrdacarrier

Numbers

  • LIBRIS-ID:oai:DiVA.org:kth-12851
  • https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-12851URI
  • https://doi.org/10.1021/ja074044kDOI

Supplementary language notes

  • Language:English
  • Summary in:English

Part of subdatabase

Classification

  • Subject category:ref swepub-contenttype
  • Subject category:art swepub-publicationtype

Notes

  • QC20100524
  • Pd(II) allyl and Pd(0) olefin complexes containing the configurationally labile ligand 1,2-bis-[4,5dihydro-3H-dibenzo[c-e]azepino]ethane were studied as models for intermediates in Pd-catalyzed allylic alkylations. According to NMR and DFT studies, the ligand prefers C-s conformation in both eta(3)-1,3-diphenylpropenyl and eta(3)-cyclohexenyl Pd(II) complexes, whereas in Pd(0) olefin complexes it adopts different conformations in complexes derived from the two types of allyl systems in both solution and, as verified by X-ray crystallography, in the solid state. These results demonstrate that the Pd complex is capable of adapting its structure to the reacting substrate. The different structural preferences also provide an explanation for the behavior of 1,3-diphenyl-2-propenyl acetate and 2-cyclohexenyl acetate in Pd-catalyzed allylic alkylations using pseudo-C-2 and pseudo-C-s symmetric ligands.

Subject headings and genre

Added entries (persons, corporate bodies, meetings, titles ...)

  • Bouet, AlexisKTH,Organisk kemi,Christina Moberg(Swepub:kth)u18uqdec (author)
  • Fjellander, Ester,1982-KTH,Organisk kemi,Christina Moberg(Swepub:kth)u114h0lr (author)
  • Constant, SamuelUniversity of Geneva,Jérôme Lacour (author)
  • Linder, DavidUniversity of Geneva,Jérôme Lacour (author)
  • Andreas, FischerKTH,Oorganisk kemi,Andreas Fischer(Swepub:kth)u1mpcad5 (author)
  • Lacour, JérômeUniversity of Geneva,Jérôme Lacour (author)
  • Privalov, TimofeiKTH,Organisk kemi,Timofei Privalov(Swepub:kth)u1p555lx (author)
  • Moberg, ChristinaKTH,Organisk kemi,Christina Moberg(Swepub:kth)u1dmzdbd (author)
  • KTHOrganisk kemi (creator_code:org_t)

Related titles

  • In:Journal of the American Chemical SocietyWashington DC : American Chemical Society130:6, s. 1845-18550002-78631520-5126

Internet link

Find in a library

To the university's database

  • 1 of 1
  • Previous record
  • Next record
  •    To hitlist

Kungliga biblioteket hanterar dina personuppgifter i enlighet med EU:s dataskyddsförordning (2018), GDPR. Läs mer om hur det funkar här.
Så här hanterar KB dina uppgifter vid användning av denna tjänst.

 
pil uppåt Close

Copy and save the link in order to return to this view