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L-lactide macromono...
L-lactide macromonomer synthesis initiated by new cyclic tin alkoxides functionalized for brushlike structures
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Ryner, Maria (author)
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- Finne, Anna (author)
- KTH,Polymerteknologi
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- Albertsson, Ann-Christine (author)
- KTH,Polymerteknologi
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Kricheldorf, Hans R. (author)
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(creator_code:org_t)
- 2001-09-05
- 2001
- English.
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In: Macromolecules. - : American Chemical Society (ACS). - 0024-9297 .- 1520-5835. ; 34:21, s. 7281-7287
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- L-Lactide macromonomers with an incorporated double bond were successfully synthesized by controlled ring-opening polymerization initiated by two new cyclic tin alkoxides (1,1-di-n-butyl-stanna-2,7-dioxacyclo-4-heptene and 9,9,20,20-tetrabutyl-8,10,19,21-tetraoxa-9,20-distanna-dispiro[5.5.5.5]d ocosa-2,14-diene). Initiators and crude reaction mixtures were characterized by NMR. H-1 NMR analysis showed that the initiators were completely reacted in the polymerization and that both tin-oxygen bonds were reactive and participated in propagation. The polymerizations were performed in chloroform at 60 degreesC, and the molecular weight was effectively controlled by adjusting the monomer-to-initiator ratio. The molecular weight distribution was narrow (<1.1) for both high and low molecular weights (3000-72 000 g/mol). A plot of M-n vs conversion was linear up to a conversion of 98%, showing a system propagating in a controlled manner. The kinetic investigation showed that all of the polymerizations were first order in monomer and that no termination reactions occurred during polymerization.
Subject headings
- NATURVETENSKAP -- Kemi -- Polymerkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Polymer Chemistry (hsv//eng)
Keyword
- ring-opening polymerization
- poly(l-lactide) macromonomers
- macrocyclic polymerization
- multiblock copolymers
- aluminum alkoxides
- graft-copolymers
- polylactones
- polyesters
- pentaerythritol
- caprolactone
- Polymer chemistry
- Polymerkemi
Publication and Content Type
- ref (subject category)
- art (subject category)
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