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Synthesis and chara...
Synthesis and characterization of two novel high valent dinuclear complexes with a triphenolate ligand bearing functional groups
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Shi, F. (author)
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Li, H. Y. (author)
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Peng, X. J. (author)
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Zhang, R. (author)
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Chen, X. Q. (author)
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Fan, J. L. (author)
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Cui, J. N. (author)
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Akermark, B. (author)
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Sun, Licheng C. (author)
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- 2005
- 2005
- English.
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In: Chinese Chemical Letters. - 1001-8417 .- 1878-5964. ; 16:1, s. 89-92
- Related links:
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https://urn.kb.se/re...
Abstract
Subject headings
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- Two novel high valent complexes [M-2(III, III)L(mu-OAc)(2)](PF6)-P-. (M=Mn, Fe; 9) were prepared, where L was the tri-anion of 2,6-bis{[(2-hydroxy-3-(morpholin-4-yl methyl)-5-tertbutyl benzyl)(pyridyl-2-methyl)amino]methyl}-4-methyl phenol which contained additional phenolic, tert-butyl and morpholin-4-yl methyl groups compared to its parent [Mn-2(II, II)(bpmp) (mu-OAc)(2)](CIO4)-C-. (10). These improvements decreased the difference between the new model and (Mn)(4) cluster (OEC in nature).
Keyword
- dinuclear complex
- OEC
- artificial photosynthesis
- phenols
Publication and Content Type
- ref (subject category)
- art (subject category)
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