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Spin-orbit interaction mediated molecular dissociation
- Kokkonen, E. (author)
-
- Löytynoja, Tuomas (author)
- KTH,Teoretisk kemi och biologi
- Jankala, K. (author)
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- Kettunen, J. A. (author)
- Heinasmaki, S. (author)
- Karpenko, A. (author)
- Huttula, M. (author)
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- (creator_code:org_t)
- AIP Publishing, 2014
- 2014
- English.
- In: Journal of Chemical Physics. - : AIP Publishing. - 0021-9606 .- 1089-7690. ; 140:18, s. 184304-
- Journal article (peer-reviewed)
Abstract
Subject headings
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- The effect of the spin-orbit interaction to photofragmentation is investigated in the mercury(II) bromide (HgBr2) molecule. Changes in the fragmentation between the two spin-orbit components of Hg 5d photoionization, as well as within the molecular-field-splitted levels of these components are observed. Dissociation subsequent to photoionization is studied with synchrotron radiation and photoelectron-photoion coincidence spectroscopy. The experimental results are accompanied by relativistic ab initio analysis of the photoelectron spectrum.
Subject headings
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
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- art (subject category)
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- Kettunen, J. A.
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- Karpenko, A.
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- Huttula, M.
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