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Cellulose nanofibril reinforced composite electrolytes for lithium ion battery applications

Willgert, Markus (author)
KTH,Ytbehandlingsteknik,KTH Royal Institute of Technology, Sweden
Leijonmarck, Simon (author)
RISE,KTH,Tillämpad elektrokemi,Swerea SICOMP AB, Sweden,SICOMP,KTH Royal Institute of Technology, Sweden
Lindbergh, Göran (author)
KTH,Tillämpad elektrokemi,KTH Royal Institute of Technology, Sweden
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Malmström Jonsson, Eva (author)
KTH,Ytbehandlingsteknik
Johansson, Mats K. G. (author)
KTH,Ytbehandlingsteknik,KTH Royal Institute of Technology, Sweden
Malmström, Eva E. (author)
KTH Royal Institute of Technology, Sweden
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 (creator_code:org_t)
2014-06-17
2014
English.
In: Journal of Materials Chemistry A. - : Royal Society of Chemistry (RSC). - 2050-7488 .- 2050-7496. ; 2:33, s. 13556-13564
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • The present study describes the synthesis and characterization of a series of four composite electrolytes for lithium ion battery applications. The two-phase electrolytes are composed of a soft, ionic conductive poly(ethylene glycol) (PEG) matrix having stiff nanofibrillated cellulose (CNF) paper as reinforcement to provide mechanical integrity. The reinforcing CNF is modified in order to create covalent bonds between the phases which is particularly beneficial when swelling the composite with a liquid electrolyte to enhance the ionic conductivity. After swelling the composite polymer electrolyte, forming a gelled structure, values of ionic conductivity at 5 x 10(-5) S cm(-1) and an elastic modulus around 400 MPa at 25 degrees C are obtained.

Subject headings

TEKNIK OCH TEKNOLOGIER  -- Kemiteknik -- Annan kemiteknik (hsv//swe)
ENGINEERING AND TECHNOLOGY  -- Chemical Engineering -- Other Chemical Engineering (hsv//eng)
TEKNIK OCH TEKNOLOGIER  -- Materialteknik (hsv//swe)
ENGINEERING AND TECHNOLOGY  -- Materials Engineering (hsv//eng)

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art (subject category)

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